Polysilicone-6: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: July 1, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Polysilicone-6?

Polysilicone-6 is a man-made silicone polymer created by linking together units of dimethyl and methyl 3-mercaptopropyl siloxanes with small amounts of 2-methylpropyl 2-propenoate. The result is a flexible, water-resistant chain that can spread easily over hair or skin and then set into a thin smooth layer.

Silicone chemistry has been part of cosmetics since the 1950s. As brands searched for longer-lasting makeup and sleeker hair products in the late 1990s specialists developed Polysilicone-6 to deliver a lighter feel than older silicones while still giving strong hold and shine. Today most supplies come from large specialty chemical plants where the raw siloxanes are mixed, heated and catalyzed under controlled conditions until the desired molecular weight is reached. The finished material is then filtered and blended into liquid or powder form for formulators.

You will most often see Polysilicone-6 in hair care lines such as shampoos, rinse-out conditioners, leave-in creams, serums and styling gels. Skin care and makeup brands also use it in foundations, primers, setting sprays, sheet masks and long-wear sunscreens whenever they want a breathable yet durable film that resists water and humidity.

Polysilicone-6’s Cosmetic Benefits/Uses

This ingredient earns its place on labels thanks to two key functions that improve how a product looks, feels and lasts on the body.

  • Film Forming – Once applied Polysilicone-6 lays down an invisible, flexible film that locks in active ingredients, helps makeup stay put and provides a soft focus finish on the skin. On hair the film shields strands from humidity so styles hold longer and frizz is reduced.
  • Hair Conditioning – The slick surface created by the polymer smooths rough cuticles, boosts shine and makes combing easier which cuts down on breakage and split ends.

Who Can Use Polysilicone-6

Because Polysilicone-6 forms a breathable light film it suits most skin types including dry, normal, combination and oily skin. It is non-occlusive so it rarely traps oil yet it still gives surface slip for drier complexions. Very acne-prone users who are sensitive to any silicone buildup may prefer to use it sparingly or choose rinse-off formulas.

The polymer is fully synthetic and contains no animal by-products so it is suitable for vegans and vegetarians.

Current safety reviews show no specific risks for women who are pregnant or breastfeeding when Polysilicone-6 is used topically at the levels found in cosmetics. This is not medical advice and anyone who is expecting or nursing should show the ingredient list to a qualified healthcare provider for personal guidance.

Polysilicone-6 does not absorb UV light and is not known to cause photosensitivity. It is also fragrance-free and chemically stable so it rarely interacts with other common skincare actives.

Potential Side Effects/Adverse Reactions

Reactions to topical Polysilicone-6 differ from person to person. The effects below are possible yet uncommon when the ingredient is used in properly formulated products.

  • Mild skin irritation such as redness or itching in sensitive individuals
  • Transient acne flare-ups if multiple silicone layers are left on very oily skin without proper cleansing
  • Eye stinging if a high-hold hair spray or primer containing the polymer gets into the eyes
  • Flat or greasy-looking hair when heavy leave-in products are overused
  • Rare allergic contact dermatitis due to sensitivity to trace residual monomers

If any discomfort or persistent reaction develops discontinue use and consult a healthcare professional.

Comedogenic Rating

1 out of 5

Polysilicone-6 forms a lightweight breathable film that stays on the surface of skin so it seldom blocks pores. Its large molecules create space for natural oil to flow and it does not harden into a waxy plug. A score of 1 is given rather than 0 because any film former can trap sebum if layered with very heavy products or left on for long periods without proper cleansing.

Most acne-prone users can tolerate Polysilicone-6, though those with extremely oily or easily congested skin may prefer it in rinse-off or lightly formulated leave-ons.

The polymer is typically used at low levels and is often combined with fast-evaporating silicones that further reduce clogging risk.

Summary

Polysilicone-6 is a versatile silicone polymer that delivers two standout benefits: it lays down a flexible water resistant film that keeps makeup and active ingredients in place and it smooths hair cuticles for easier detangling, added shine and longer-lasting style. Its silky chains spread quickly then set to a soft barrier that resists humidity while letting skin and scalp breathe.

Although not as widely talked about as classic dimethicone it appears in a growing number of long wear foundations, primers, sunscreens and next-gen hair stylers where light feel and durability are key selling points.

Safety reviews show the ingredient is non sensitising, non mutagenic and stable, indicating it is generally safe for everyday cosmetic use. Still, patch testing any new product that contains Polysilicone-6 is a wise step to confirm personal compatibility.

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