Ppg-26/Dimer Dilinoleate Copolymer: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: July 1, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Ppg-26/Dimer Dilinoleate Copolymer?

Ppg-26/Dimer Dilinoleate Copolymer is a man-made ingredient created by joining two materials: PPG-26, a small water-loving molecule, and dilinoleic acid, a fatty acid that comes from plant oils such as soybean or safflower. When chemists link these pieces together they form a long, flexible chain called a copolymer. The result acts a bit like a lightweight plastic film that feels smooth yet never heavy on skin.

The copolymer first appeared in cosmetic labs in the late 1990s as brands looked for gentler alternatives to thick waxes and heavy oils. By tweaking the balance of watery and oily parts scientists found Ppg-26/Dimer Dilinoleate Copolymer could lock moisture in while leaving a soft finish. Its popularity grew as makeup formulators noticed it helped color last longer without cracking or flaking.

Manufacturing starts with plant-derived linoleic acid, which is turned into dilinoleic acid through a simple heating step. This fatty acid is then reacted with propylene glycol to create PPG-26. Finally, under controlled heat and pressure, the two pieces bond into the copolymer. The process is well established and produces a stable, high-purity ingredient fit for personal care.

You will most often spot Ppg-26/Dimer Dilinoleate Copolymer in long-wear foundations, liquid lipsticks, waterproof mascaras, primers, sunscreens, lightweight lotions and some hair styling creams where a flexible hold is needed.

Ppg-26/Dimer Dilinoleate Copolymer’s Cosmetic Benefits/Uses

This versatile ingredient offers two key functions that improve how a product feels and performs on skin or hair.

  • Film forming: It creates a thin breathable layer that holds pigments in place helps sunscreen stay put resists smudging and gives hair light control without stiffness.
  • Humectant: Its water-loving parts attract and bind moisture which keeps skin feeling soft prevents makeup from looking dry and supports a smooth even finish.

Who Can Use Ppg-26/Dimer Dilinoleate Copolymer

Ppg-26/Dimer Dilinoleate Copolymer works well for nearly all skin types. Dry and normal skin benefit from its moisture-binding ability while combination and oily skin appreciate that it feels weightless and breathable instead of greasy. Sensitive skin generally tolerates it because the large polymer molecules sit on the surface rather than penetrating deeply, though individual sensitivities are always possible.

The ingredient is produced from plant-derived fatty acids and petroleum-based propylene glycol, with no animal by-products used during manufacture, so it is considered suitable for vegans and vegetarians.

Current safety data show no evidence that topical use poses a risk during pregnancy or breastfeeding. The polymer is too large to pass through skin in meaningful amounts. That said this is not medical advice and anyone who is pregnant or nursing should review any skincare product with a qualified health professional before use.

Ppg-26/Dimer Dilinoleate Copolymer does not increase photosensitivity so it does not make skin more prone to sunburn. It can be safely layered with daily sunscreen for extra protection and staying power.

Potential Side Effects/Adverse Reactions

Reactions to topical Ppg-26/Dimer Dilinoleate Copolymer vary from person to person. The following list covers potential side effects although most users will not experience any of them when the ingredient is used correctly in a finished product.

  • Skin irritation or mild redness in very sensitive individuals
  • Allergic contact dermatitis in those with a specific sensitivity to propylene glycol derivatives
  • Temporary eye stinging if the product is accidentally rubbed into the eyes
  • Minor acne flare-ups in extremely clog-prone skin when used in heavy makeup layers
  • Product buildup or dullness on fine hair if not washed out thoroughly

If any uncomfortable reaction occurs stop using the product and consult a healthcare professional or dermatologist for guidance.

Comedogenic Rating

Rating: 1 out of 5. Ppg-26/Dimer Dilinoleate Copolymer is a large, lightweight polymer that tends to sit on the surface rather than sinking into pores, so it rarely traps oil or dead skin inside follicles. It may contribute to breakouts only if layered heavily with other occlusive ingredients or left on very oily skin for extended periods. Overall it is generally suitable for people who are prone to acne or congestion.

Because this ingredient usually appears in long-wear color cosmetics applied over primer or sunscreen, buildup from multiple layers can occasionally raise the clogging potential. Regular cleansing at the end of the day helps keep pores clear.

Summary

Ppg-26/Dimer Dilinoleate Copolymer acts mainly as a film former and humectant. Its flexible polymer chain creates a thin breathable coat that anchors pigments, boosts water resistance and gives hair or skin a smooth feel. The water-loving portions attract moisture, keeping makeup fresh and preventing dryness.

While not a household name, it is a quiet workhorse in many long-wear foundations, liquid lipsticks, waterproof mascaras and some lightweight lotions. Formulators appreciate its balance of hold and comfort, which keeps it in steady demand even if consumers rarely notice it on the label.

Current research shows it is low risk for irritation, allergies or systemic absorption, making it safe for everyday cosmetic use. As with any new product perform a quick patch test first to be cautious, especially if you have very sensitive or reactive skin.

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