Propyltrimoniumchloride Acrylamide/Dimethylacrylamide Copolymer: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: July 1, 2025
Share:
Inside this article:

We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Propyltrimoniumchloride Acrylamide/Dimethylacrylamide Copolymer?

Propyltrimoniumchloride Acrylamide/Dimethylacrylamide Copolymer is a man-made ingredient created by linking two small building blocks, dimethylacrylamide and propyltrimonium methacrylamide, into a long chain. This chain forms a lightweight film when it dries, which is why it is popular in hair and skin products. The copolymer is produced through a controlled chemical reaction called polymerization, carried out in water under mild heat. Because the starting materials are easy to source and the process is predictable, manufacturers can make large batches with consistent quality.

The cosmetic industry began using this copolymer in the late 1990s as brands searched for alternatives to older, heavier fixatives. Its positive charge helps it cling to negatively charged hair fibers, allowing for better performance at lower use levels than many legacy resins. Today it appears in shampoos, rinse-out and leave-in conditioners, styling gels, mousses, curl creams, anti-frizz serums, edge-taming pastes, setting sprays and even some facial primers that aim to blur texture while controlling stray hairs around the hairline.

Propyltrimoniumchloride Acrylamide/Dimethylacrylamide Copolymer’s Cosmetic Benefits/Uses

In formulas this versatile copolymer delivers several helpful actions:

  • Antistatic: Its positive charge neutralizes static buildup so hair stays smooth rather than flyaway
  • Film forming: Dries to a flexible, breathable film that helps lock in style and gives a soft touch finish without flaking
  • Hair conditioning: Deposits a thin layer along the cuticle, adding slip for easier comb-through and a silkier feel
  • Hair fixing: Provides light to medium hold that keeps curls, waves and updos in place while allowing natural movement

Who Can Use Propyltrimoniumchloride Acrylamide/Dimethylacrylamide Copolymer

This ingredient works for most skin and hair types. Because it sits on the surface and forms a breathable film without blocking pores, it is generally well tolerated by oily, combination, dry and even sensitive skin. People with extremely reactive or broken skin may still want to proceed carefully since any charged polymer can sometimes feel tight or cause slight tingling on compromised areas.

The copolymer is fully synthetic and contains no animal-derived substances, so it is suitable for both vegans and vegetarians.

No specific warnings exist for pregnant or breastfeeding women. The material is used at very low levels and does not penetrate deeply, but this is not medical advice. Anyone who is expecting or nursing should run the product past a qualified healthcare professional to be sure it fits their personal situation.

The ingredient does not make skin more sensitive to sunlight, so there is no need for extra sun protection beyond the usual daily SPF recommendation.

Potential Side Effects/Adverse Reactions

Reactions to topical Propyltrimoniumchloride Acrylamide/Dimethylacrylamide Copolymer differ from person to person. The effects listed below are possible yet uncommon when the ingredient is used at the concentrations found in finished cosmetic products.

  • Mild skin or scalp irritation such as redness or a stinging sensation
  • Itching caused by sensitivity to the cationic charge
  • Allergic contact dermatitis in individuals already allergic to acrylamide derivatives
  • Product buildup that can make hair feel heavy or dull if not cleansed regularly

If any uncomfortable reaction occurs stop using the product and seek guidance from a medical professional.

Comedogenic Rating

Rating: 0 out of 5

Propyltrimoniumchloride Acrylamide/Dimethylacrylamide Copolymer is a large water-soluble molecule that stays on the surface of skin and hair without sinking into pores or mixing with skin oil. It forms a light, breathable film rather than a greasy layer, so it does not encourage clogged pores or breakouts.

Because of this, the ingredient is suitable for people who tend to get acne or blackheads.

One extra point to note is that the copolymer can bind to excess oil on hair and help rinse it away during cleansing, which may further lower the risk of pore congestion when compared with heavier styling resins.

Summary

Propyltrimoniumchloride Acrylamide/Dimethylacrylamide Copolymer works as an antistatic agent, film former, hair conditioner and light hold fixative. Its positive charge lets it latch onto negatively charged hair strands, then it dries into a thin flexible film that smooths frizz, adds slip and keeps styles in place without crunch or flakes.

The ingredient is moderately popular in modern hair care, often showing up in gels, mousses and leave-in products that aim for a soft natural finish. It is less common in skincare but may appear in primers or light lotions that look to blur texture.

Overall safety is high because the polymer remains on the surface and is used at low levels. Irritation or allergy is rare yet always possible with any cosmetic component. It is smart to patch test a new product containing this copolymer to make sure it suits your own skin or scalp.

Was this article helpful?
More from Glooshi:
ADVERTISEMENT
Get all our top headlines in beauty.
Delivered right to your inbox each week. Zero spam, all goodness, opt-out at anytime.
This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.
Get the latest beauty news, top product recommendations & brand-exclusive discount codes direct to your inbox.
Send good feedback:

All feedback is greatly appreciated, anonymous, and will be used to improve the quality of our articles.

This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.
Send bad feedback:

All feedback is greatly appreciated, anonymous, and will be used to improve the quality of our articles.

This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.
Search