Quaternium-18 Hectorite: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: June 30, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Quaternium-18 Hectorite?

Quaternium-18 Hectorite is a blend of two things: a quaternary ammonium salt made from hydrogenated tallow and a naturally occurring clay called hectorite. When the positively charged quaternium portion is bonded to the negatively charged layers of hectorite, it turns the clay into an “organoclay” that works well in oily or low-water formulas. This ingredient first appeared in cosmetics in the late twentieth century when formulators were looking for a way to thicken non-water products such as lipsticks and sunscreens without leaving a heavy feel. Production starts with purified hectorite that is reacted with the quaternary ammonium compound in water, then dried and milled into a fine powder ready for use. You will commonly spot it in foundations, cream blushes, sunscreens, masks, hair styling pastes, anti-aging serums, moisturizers and other leave-on products where a smooth stable texture is key.

Quaternium-18 Hectorite’s Cosmetic Benefits/Uses

Its main job in a formula is viscosity controlling, which means it helps adjust how thick or thin a product feels. By swelling in the oily parts of a recipe it builds a flexible network that keeps the product from running or separating, suspends pigments or shimmer evenly and gives creams and gels a luxurious cushion that spreads easily on skin or hair.

Who Can Use Quaternium-18 Hectorite

Because it is primarily a texture enhancer that stays on the surface of skin or hair, Quaternium-18 Hectorite is generally well tolerated by most skin types including dry, normal, combination, oily and even sensitive skin. Its lightweight feel makes it unlikely to clog pores, while its ability to stabilize formulas helps prevent separation that could otherwise lead to irritation.

The quaternary ammonium part of this ingredient is made from hydrogenated tallow, which is derived from animal fat. For that reason products containing Quaternium-18 Hectorite are not suitable for vegans or strict vegetarians who avoid animal-derived ingredients.

No specific safety warnings have been issued for pregnant or breastfeeding women. Current data suggest topical use is safe, yet this is not medical advice. Anyone who is pregnant or nursing should discuss any skincare product with a qualified healthcare professional to be sure it fits their individual needs.

Quaternium-18 Hectorite does not increase skin’s sensitivity to sunlight so there is no extra photosensitivity risk. It is also odorless and free of known hormone-disrupting activity, making it a low-concern choice for most users.

Potential Side Effects/Adverse Reactions

Side effects and reactions to the topical application of Quaternium-18 Hectorite can vary from person to person. The points below outline potential issues, but they are uncommon for the average user when the ingredient is used correctly in a finished product.

  • Mild skin irritation
  • Contact dermatitis in individuals allergic to quaternary ammonium compounds
  • Eye irritation if the powder or an improperly emulsified product gets into the eyes
  • Build-up or residue on hair after frequent use of high-hold styling products

If any discomfort, redness or other adverse reaction occurs, discontinue use and seek advice from a healthcare professional.

Comedogenic Rating

Rating: 1 / 5
Quaternium-18 Hectorite sits on the surface without melting into pores and its clay base can even mop up excess oil, making clogged pores unlikely. It lacks the heavy fatty acids or waxes that usually raise comedogenicity concerns, so it earns a low score of 1.
In practical terms this means the ingredient is generally suitable for acne-prone or breakout-prone skin.
Because the quaternary portion is cationic it can bind lightly to skin and hair, yet this film is thin and water-rinseable, keeping pore-blocking risk minimal.

Summary

Quaternium-18 Hectorite is mainly a viscosity controller that swells in the oil phase to thicken, stabilize and suspend pigments, giving creams, sticks and gels a smooth cushiony feel without heaviness. It has found a steady but niche spot in color cosmetics, sunscreens and styling pastes rather than becoming a headline ingredient, yet formulators value its reliability and silky glide.

Current research and decades of use show it to be low risk for irritation, sensitization or pore clogging, with the main caveat being its animal-derived origin for those who avoid such inputs. As with any new product a quick patch test is a smart step to ensure personal compatibility.

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