Quaternium-24: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: June 30, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Quaternium-24?

Quaternium-24 is the cosmetic name for decyldimethyloctylammonium chloride, a quaternary ammonium salt formed by combining a fatty alcohol chain with ammonium and chloride. The fatty alcohol part is usually sourced from coconut or palm oils then refined in a lab. Chemists first explored this class of compounds in the mid-20th century while searching for better fabric softeners and household cleaners. Their mild yet effective surface action quickly caught the eye of personal care formulators who adapted them for skin and hair products.

To make Quaternium-24, manufacturers start with a natural fatty alcohol that is reacted with dimethylamine, then quaternized with methyl chloride to lock in a permanent positive charge. This positive charge is the key to its performance because it helps the ingredient bond to negatively charged surfaces like skin proteins, hair strands and microbial cell walls.

Today you will most often find Quaternium-24 in rinse-off and leave-on hair conditioners, anti-frizz sprays, scalp treatments, micellar cleansers, facial masks and some gentle body washes. Its smooth feel, cleansing help and germ control make it a versatile pick for both hair care and skin care formulas.

Quaternium-24’s Cosmetic Benefits/Uses

Below are the main ways Quaternium-24 improves everyday beauty products

  • Antimicrobial: The ingredient’s positive charge breaks down the outer layers of bacteria and some fungi which helps keep formulas fresh and can support a cleaner scalp or skin surface
  • Antistatic: By neutralizing electrical buildup on hair strands it reduces flyaways, improves combability and leaves hair looking smoother and more controlled
  • Cleansing: Its surfactant character lifts away oils and dirt allowing rinse-off products to clean effectively without harshness making it helpful in mild shampoos or micellar waters

Who Can Use Quaternium-24

Most skin types tolerate Quaternium-24 well because it is mild and non-sensitizing. Normal, dry and oily skin can all benefit from its cleansing and antimicrobial help, while its antistatic effect makes it especially useful for anyone struggling with frizz or flyaways. Very sensitive or eczema-prone skin may want to proceed with caution, as any cationic surfactant can occasionally trigger irritation when the skin barrier is already compromised.

The fatty alcohol used to create Quaternium-24 is typically sourced from coconut or palm so the final material is considered plant derived and suitable for vegetarians and vegans. Those avoiding palm should look for brands that confirm coconut sourcing.

No data indicate that Quaternium-24 poses a risk to pregnant or breastfeeding women when used topically in cosmetic concentrations. Because every pregnancy is unique this is not medical advice and anyone expecting or nursing should show their chosen products to a qualified doctor just to be safe.

The ingredient does not produce photosensitivity, so it will not make skin more prone to sunburn. It is also color safe for treated hair and rinses clean without stripping.

Potential Side Effects/Adverse Reactions

Responses to topical Quaternium-24 differ from person to person. The effects listed below are only potential outcomes and are uncommon when the ingredient is used correctly in a professionally formulated product.

  • Skin irritation mild redness stinging or itching can occur on very sensitive skin or when applied to broken skin
  • Allergic contact dermatitis rare but possible with repeated exposure in individuals who develop a specific allergy
  • Eye irritation may cause burning or watering if a cleanser or conditioner accidentally gets into the eyes
  • Scalp buildup frequent leave-on use can leave hair feeling heavy or greasy in fine hair types
  • Exacerbation of existing dermatitis damaged or inflamed skin may react more strongly than healthy skin

If any of these effects appear stop using the product and seek advice from a healthcare professional.

Comedogenic Rating

Rating: 1 / 5 – Quaternium-24 is a lightweight cationic surfactant that generally rinses away cleanly and does not leave an oily film on skin. Its molecular size and water-dispersible nature make it very unlikely to block pores, so breakouts are not commonly linked to this ingredient.

Because of the low rating, products containing Quaternium-24 are usually fine for people who get acne or clogged pores. The only exception might be heavy leave-on creams layered thickly on already oily skin, but that situation is rare with this ingredient.

One extra point worth noting is that Quaternium-24 often shows up in hair care. Residue from a leave-in conditioner that touches the forehead or hairline can sometimes mix with sweat and other styling products and contribute to pimples in that area, so rinse well if you are breakout-prone.

Summary

Quaternium-24 works as an antimicrobial, an antistatic agent and a mild cleanser. Its permanent positive charge lets it stick to negatively charged surfaces like hair cuticles and microbial cell walls which helps smooth strands, reduce static and curb bacterial growth. At the same time its surfactant tail lifts dirt and oil so skin and hair feel fresh without harsh stripping.

While not as famous as big-name conditioning agents like behentrimonium chloride or quaternium-91, Quaternium-24 still appears in a steady stream of shampoos conditioners and micellar waters thanks to its balanced performance and plant-derived origin.

Safety reviews show a low irritation profile and virtually no comedogenic risk when used at normal cosmetic levels. As with any new personal care product, patch testing on a small area first is a smart habit to catch any individual sensitivities early.

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