Sodium Acrylates/Ethylhexyl Acrylate Copolymer: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: June 30, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Sodium Acrylates/Ethylhexyl Acrylate Copolymer?

Sodium Acrylates/Ethylhexyl Acrylate Copolymer is a synthetic polymer created by combining acrylic acid, methacrylic acid or their simple esters with 2-ethylhexyl acrylate, then neutralizing part of the chain with sodium. The result is a network of long, flexible molecules that disperse in water yet set into a thin flexible film on the skin. First explored in the late 1970s as a way to improve texture in hair styling products, the material quickly found a place in skin care formulas because it delivered a soft touch and helped active ingredients stay put. Today it is produced in large reactors where the monomers are mixed, initiated with heat or light to start polymerization, and finally purified and spray-dried into a fine white powder or delivered as an aqueous gel.

The copolymer shows up in a wide range of leave-on and rinse-off items. You may spot it in sheet mask essences, lightweight moisturizers, anti-aging serums, tinted sunscreens, hair gels, styling creams, liquid eyeliners and peel-off masks. Its versatility lies in the way it forms an invisible layer that improves product wear without a heavy feel.

Sodium Acrylates/Ethylhexyl Acrylate Copolymer’s Cosmetic Benefits/Uses

This ingredient is prized for one main function that affects both how a product feels and how it performs on the skin.

Film forming: Once applied it dries into a uniform, flexible film that locks moisture in, helps pigments or actives stay in place and boosts resistance to water or sweat. That film also gives products a smooth glide during application and a soft finish afterward which can make skin look more refined and hair styles hold longer.

Who Can Use Sodium Acrylates/Ethylhexyl Acrylate Copolymer

This film-forming polymer is considered gentle enough for all main skin types including dry, normal, combination and oily skin because it is non-sensitizing and has no known effect on sebum production. People with very acne-prone or congested skin who react poorly to occlusive layers may want to monitor how their skin feels, as any film former can sometimes trap sweat and oil under hot or humid conditions.

The ingredient is fully synthetic and contains no animal-derived substances, so it is suitable for vegans and vegetarians. Most commercial grades are produced without animal testing, but shoppers who avoid animal testing should still look for cruelty-free certification from the finished brand.

Current safety assessments have not identified reproductive or developmental risks, which means products containing this copolymer are generally regarded as safe for people who are pregnant or breastfeeding. However this article is not medical advice and anyone expecting or nursing should run their routine past a qualified physician to be extra sure.

The polymer does not absorb UV light or make skin more reactive to sunlight, so it is not considered photosensitizing. It is odorless, colorless and chemically stable, with no special storage or daylight precautions needed.

Potential Side Effects/Adverse Reactions

Individual responses to topical ingredients differ, so the effects listed below are only potential issues. In properly formulated products most users experience none of them.

  • Mild skin irritation such as redness or itching, usually transient
  • Allergic contact dermatitis in users already sensitized to acrylic copolymers
  • Eye irritation if the raw powder or an aerosolized mist reaches the eyes
  • Clogged pores or small breakouts in rare cases where heavy layers are left on very oily skin
  • Pilling or flaking when layered with high-silicone or high-oil formulas, which is a product performance issue rather than a safety concern

If you notice any discomfort, rash or persistent irritation stop using the product and seek advice from a healthcare professional or dermatologist.

Comedogenic Rating

Sodium Acrylates/Ethylhexyl Acrylate Copolymer has a comedogenic rating of 1 out of 5. The polymer molecules are large, water loving and non greasy so they remain on the surface rather than lodging inside pores. While the light film can theoretically trap oil and sweat if applied in very thick layers that risk is low compared with heavier waxes or oils.

Most people who are prone to acne or breakouts tolerate this ingredient well.

If a formula couples the copolymer with rich butters, oils or high levels of silicones the overall clogging potential may rise so the full ingredient list matters more than this single component.

Summary

Sodium Acrylates/Ethylhexyl Acrylate Copolymer is a synthetic film former that lays down a thin flexible layer on skin or hair. This layer locks in moisture, stabilizes pigments and actives, boosts water and sweat resistance and gives products a smooth glide with a soft finish.

You can find it in sheet masks, serums, tinted sunscreens, eyeliners and hair gels which shows how popular it has become for formulators who want lightweight staying power.

Safety reviews rate it as low risk, non sensitizing and non toxic at cosmetic use levels. Still, it is wise to patch test any new product containing this ingredient to be sure your skin is happy with the complete formula.

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