Tea-Acrylates/Acrylonitrogens Copolymer: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: June 30, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Tea-Acrylates/Acrylonitrogens Copolymer?

Tea-Acrylates/Acrylonitrogens Copolymer is a synthetic polymer made by reacting acrylate and acrylonitrile building blocks with triethanolamine (TEA). This reaction creates long chain molecules that can dissolve in water, then dry down to form a clear flexible film on the skin or hair. The official chemical description, 2-Propenenitrile, hydrolyzed, 2,2′,2”-nitrilotrisethanol salts, points to the fact that the original acrylonitrile is partly broken down (hydrolyzed) and neutralized with TEA to keep the final material mild and easy to handle.

Polymers that leave a film have been used in cosmetics since the 1950s when hairsprays first gained popularity. As consumers asked for lighter, less flaky finishes, chemists developed new copolymers like this one that hold style yet stay flexible. Its balanced mix of acrylate units for strength and nitrile units for flexibility made it a useful upgrade over older resins.

Manufacturing starts with acrylic acid, acrylonitrile and other monomers placed in a reactor with water. A small amount of initiator sets off the chain-building process. After the polymer chains reach the right length, the batch is neutralized with triethanolamine to form the water-soluble salt, filtered and dried into a powder or left as a concentrated solution.

In finished products you will mostly find Tea-Acrylates/Acrylonitrogens Copolymer in hair gels, styling creams, setting lotions, mascara, brow gels, peel-off face masks and long-wear makeup. Formulators pick it when they need hold, shine or a smooth film that resists humidity without feeling stiff.

Tea-Acrylates/Acrylonitrogens Copolymer’s Cosmetic Benefits/Uses

This ingredient is prized for one main reason within cosmetic formulas.

Film forming: Once the water in a product evaporates the polymer creates an even invisible layer that locks the style of hair, keeps makeup in place or gives a peel-off mask its easy-to-remove sheet. The film can also help trap moisture, add a light gloss and protect against minor environmental stress like wind or pollution particles.

Who Can Use Tea-Acrylates/Acrylonitrogens Copolymer

The polymer is generally considered friendly to all skin and hair types since it sits on the surface and does not penetrate deeply. Normal, dry and combination skin tend to appreciate the light film that helps seal in hydration. Very oily or acne-prone users might find heavy concentrations feel occlusive or add unwanted shine, so lightweight formulas are best for them.

Because the material is fully synthetic and manufactured without animal by-products, it is suitable for vegans and vegetarians. The ingredient itself is not derived from any animal source.

The large molecular size means it is unlikely to be absorbed into the bloodstream, so products containing it are viewed as low risk for pregnant or breastfeeding women. This is not medical advice; anyone who is expecting or nursing should run any skincare or haircare product past a healthcare professional to be on the safe side.

Tea-Acrylates/Acrylonitrogens Copolymer does not increase photosensitivity, so it will not make skin more prone to sunburn. It also plays well with common actives like niacinamide or vitamin C because it is chemically inert and stays on the surface.

Potential Side Effects/Adverse Reactions

Responses to topical Tea-Acrylates/Acrylonitrogens Copolymer can vary from person to person. The issues listed below are possible but uncommon when the ingredient is used at the levels normally found in finished products.

  • Mild skin irritation such as redness or itching on very sensitive skin
  • Contact dermatitis in individuals allergic to acrylate chemistry
  • Eye stinging or watering if the raw polymer dust or an aerosol formula gets into the eyes
  • Product buildup or flaking on hair when high hold styling items are layered repeatedly
  • Dry-feeling strands if a strong film prevents moisture from entering extremely porous hair

If you notice any persistent irritation or discomfort stop using the product and consult a medical professional.

Comedogenic Rating

Rating: 1/5

Tea-Acrylates/Acrylonitrogens Copolymer earns a low score because its molecules are large and sit on top of the skin rather than slipping into pores where blockages start. The film it leaves is breathable and easily removed with ordinary cleansing so buildup is minimal. As a result this ingredient is generally fine for people prone to acne or breakouts, especially when used in lightweight formulas.

Keep in mind that comedogenicity can rise if a product layers several film formers, heavy oils or waxes alongside this polymer. In that case the full formula, and not the polymer alone, may increase the chance of clogged pores.

Summary

Tea-Acrylates/Acrylonitrogens Copolymer is a synthetic film former that dries into a clear flexible layer to hold hairstyles, keep makeup in place or let peel-off masks lift away cleanly. It mixes strength from its acrylate portions with flexibility from its nitrile portions, giving products lasting hold without a stiff helmet feel.

The polymer is moderately popular in hair styling aids and long-wear cosmetics but less common in everyday skincare, mainly because brands often pick newer marketed resins for buzz value. Still, chemists rely on it when they need dependable humidity resistance and an easy-to-use water-soluble base.

Safety profiles rate it as low risk for irritation or pore clogging, and its large size keeps it on the surface of skin and hair. As with any new product though it is smart to do a quick patch test before full use just to make sure your skin agrees with the complete formula.

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