Va/Crotonates/Methacryloxybenzophenone-1 Copolymer: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: June 30, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Va/Crotonates/Methacryloxybenzophenone-1 Copolymer?

Va/Crotonates/Methacryloxybenzophenone-1 Copolymer is a synthetic ingredient made by combining three main building blocks: vinyl acetate, crotonic acid and methacryloxybenzophenone-1. When these small molecules are linked together in a controlled reaction they form a flexible film-forming polymer. The process happens in large reactors where heat, pressure and special initiators help the molecules join into long chains. Once the reaction is complete the material is purified, dried and milled into a fine powder or delivered as a ready-to-use liquid dispersion.

The beauty industry adopted this copolymer in the late 1980s as chemists searched for lightweight fixatives that could also guard hair and skin from sunlight. By blending traditional vinyl acetate with a UV-absorbing unit (methacryloxybenzophenone-1) they created a versatile polymer that set quickly yet stayed clear and flexible. Today the ingredient can be found in hair sprays, styling gels, mousses, mascara, brow setters, sunscreens and some long-wear makeup products.

Va/Crotonates/Methacryloxybenzophenone-1 Copolymer’s Cosmetic Benefits/Uses

This multitasking polymer adds several useful properties to modern formulas

  • Film forming – Dries down to a thin transparent layer that helps makeup or skincare stay put, resist smudging and endure humidity or sweat
  • Hair fixing – Provides flexible hold in styling products so hairstyles keep their shape without feeling stiff or flaky
  • UV absorber – Soaks up part of the sun’s UVA and UVB rays reinforcing the overall sun protection offered by a product and helping slow color fade in hair dyes

Who Can Use Va/Crotonates/Methacryloxybenzophenone-1 Copolymer

This polymer is generally considered suitable for all skin and hair types. It forms a breathable film that is lightweight so even oily or combination skin tends to tolerate it without feeling greasy, while its non occlusive nature makes it comfortable for dry or sensitive skin. People with very reactive or allergy-prone skin should still keep an eye on ingredient lists since any synthetic resin can occasionally trigger irritation in this group.

The copolymer is manufactured entirely from petrochemical starting materials and contains no animal-derived substances or processing aids, making it appropriate for vegans and vegetarians.

No specific warnings exist for pregnant or breastfeeding women when it comes to topical use of this ingredient at the levels found in finished cosmetics. That said this information is not medical advice and anyone who is pregnant or nursing should review all personal care products with a healthcare professional to be on the safe side.

Because the molecule includes a UV-absorbing unit it does not cause photosensitivity; if anything it adds a modest boost of protection against sun damage. Users should still rely on dedicated broad-spectrum sunscreen for full coverage.

Potential Side Effects/Adverse Reactions

Responses to topical Va/Crotonates/Methacryloxybenzophenone-1 Copolymer vary from person to person. The points below list potential reactions that are uncommon and should not represent the average experience when the ingredient is used correctly in a well-formulated product.

  • Mild skin irritation
  • Allergic contact dermatitis in individuals sensitized to acrylate or vinyl resins
  • Eye stinging if the product migrates into the eyes before it sets
  • Scalp or hair buildup leading to dullness if not shampooed out regularly
  • Temporary respiratory discomfort if aerosolized sprays are inhaled in a poorly ventilated space

If any discomfort occurs discontinue use and seek advice from a qualified healthcare professional.

Comedogenic Rating

Rating: 1/5

Va/Crotonates/Methacryloxybenzophenone-1 Copolymer is a large, water-dispersible polymer that sits on top of skin rather than sinking into pores. It contains no oily emollients or waxes that typically trigger blockages, so the likelihood of it clogging pores is low. The small chance of buildup comes from the thin film it forms, especially if layered with heavy creams or not cleansed off properly, which is why it earns a cautious 1 instead of a perfect 0.

Overall this ingredient is considered suitable for acne-prone or breakout-prone skin types.

Those who use very occlusive routines or who do not wash off styling products at night may notice a higher chance of congestion, but this is uncommon.

Summary

Va/Crotonates/Methacryloxybenzophenone-1 Copolymer works as a film former, hair fixer and UV absorber. Its vinyl acetate and crotonic acid units let it dry quickly into a clear flexible layer that locks makeup or hair style in place, while the methacryloxybenzophenone segment soaks up some UV rays to help preserve color and protect skin or hair from light exposure.

You will spot this polymer most often in hair sprays, gels and long-wear cosmetics rather than everyday moisturizers, giving it a moderate but not superstar level of popularity compared with better-known fixatives like PVP or acrylates.

Safety data show it is well tolerated by most users with only rare irritation or allergy reports. As with any new product it is wise to patch test first so you can catch any personal sensitivities early and enjoy the hold and protection this ingredient provides.

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