Acrylamide/Ethalkonium Chloride Acrylate Copolymer: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: June 23, 2025
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All information on this page is verified using The Personal Care Products Council's (PCPC) INCI database. Our ingredient analyses are based exclusively on PCPC's technical data to ensure accuracy and reliability.

What Is Acrylamide/Ethalkonium Chloride Acrylate Copolymer?

Acrylamide/Ethalkonium Chloride Acrylate Copolymer is a man-made polymer created by linking together two building blocks: acrylamide and an ethalkonium chloride acrylate unit. The first piece, acrylamide, forms a clear flexible backbone, while the ethalkonium chloride acrylate part adds a positive charge that helps the ingredient cling to hair or skin. Chemists first explored this combination in the late 1970s when the beauty industry was searching for lightweight film formers that could resist humidity and improve hair manageability. Over time the ingredient proved reliable, cost-effective and easy to blend, which helped it become a staple in styling products.

Production starts with a water-based reaction where acrylamide and the quaternary ammonium acrylate are mixed, activated by a catalyst then allowed to polymerize into long chains. The final gel-like mass is dried or kept in solution, filtered for purity and standardized for use in cosmetics. Because the process is water-friendly and the raw materials are widely available, large-scale manufacturing is straightforward and consistent.

You will most often find Acrylamide/Ethalkonium Chloride Acrylate Copolymer in hair gels, mousses, setting sprays, styling creams, leave-in conditioners, anti-frizz serums and sometimes in lightweight facial masks or primers that aim to create a smooth flexible film on the skin.

Acrylamide/Ethalkonium Chloride Acrylate Copolymer’s Cosmetic Benefits/Uses

In formulas this ingredient pulls triple duty, helping products look good, feel good and stay put:

  • Film forming – Creates an invisible flexible layer that locks style in place, fights humidity and boosts shine without flaking
  • Hair conditioning – Its positive charge is attracted to the negatively charged surface of hair, smoothing rough cuticles so strands feel softer and look less frizzy
  • Viscosity controlling – Thickens water-based formulas so gels, creams and sprays have the right texture and stay evenly mixed

Who Can Use Acrylamide/Ethalkonium Chloride Acrylate Copolymer

This polymer works for most skin and hair types including oily, dry, normal and combination because it sits on the surface and does not interfere with the skin’s natural balance. People with very sensitive or eczema-prone skin may want to be cautious since any cationic film former can occasionally cause mild irritation if left on for long periods.

The ingredient is fully synthetic and contains no animal-derived materials so it is suitable for vegans and vegetarians. Standard production does not involve animal testing in many regions though finished products may be tested where required by local law.

No studies have shown specific risks for those who are pregnant or breastfeeding. That said this is not medical advice and anyone who is expecting or nursing should review all personal care products with a qualified healthcare professional before use.

Acrylamide/Ethalkonium Chloride Acrylate Copolymer is not known to increase sun sensitivity. Normal daytime sun protection habits are still important but no extra precautions are needed because of this ingredient.

Potential Side Effects/Adverse Reactions

Responses to topical Acrylamide/Ethalkonium Chloride Acrylate Copolymer vary from person to person. The points below list potential but uncommon reactions. When the ingredient is used correctly in a well-formulated product most people experience none of these issues.

  • Skin irritation: mild redness itching or tightness, usually where the product forms a film
  • Contact allergy: rare sensitization leading to rash or swelling
  • Eye discomfort: stinging or watering if styling products run into the eyes
  • Product buildup: dullness or flaking on hair if excessive layers are not washed out regularly
  • Contaminant risk: very low chance of residual unreacted acrylamide if manufacturing controls are poor

If any adverse effect occurs stop using the product and seek medical advice.

Comedogenic Rating

Rating: 1

This ingredient forms a breathable water soluble layer that stays mostly on the surface so it rarely blocks pores. Its molecules are too large to seep into follicles and it contains no oils or fatty acids that typically trigger clogs. A trace risk of buildup keeps the score above zero, especially if thick leave-on products are not washed off over several days.

Overall it is considered safe for people who are prone to acne or breakouts.

No additional comedogenic concerns have been flagged in published studies or industry reports.

Summary

Acrylamide/Ethalkonium Chloride Acrylate Copolymer is prized for three core jobs: film forming, hair conditioning and viscosity control. It builds a clear flexible coating that locks styles in place, its positive charge smooths cuticles for softer looking hair and it thickens watery formulas so they feel substantial in the hand.

The polymer is fairly common in gels, mousses and sprays though it is less talked about than trendier plant based alternatives. Formulators keep choosing it because it is reliable, cost effective and easy to blend with other ingredients.

Safety reviews rate it as low risk with only occasional mild irritation in very sensitive users. As with any new personal care product it is wise to patch test before full use to make sure your skin or scalp agrees with the formula.

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