Acrylamidopropyltrimonium Chloride/Acrylamide Copolymer: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: June 23, 2025
Share:
Inside this article:

All information on this page is verified using publicly available nomenclature standards and reference materials from The Personal Care Products Council (PCPC) and the European Commission's CosIng database. Our analyses are based on technical data from these sources to ensure accuracy and reliability.

What Is Acrylamidopropyltrimonium Chloride/Acrylamide Copolymer?

Acrylamidopropyltrimonium Chloride/Acrylamide Copolymer is a man-made polymer created by linking units of acrylamide with a quaternary ammonium salt known as acrylamidopropyltrimonium chloride. The result is a water-soluble chain that carries a gentle positive charge, which helps it cling to hair or skin. The ingredient traces its cosmetic use back to the late 1980s when formulators looked for safer alternatives to high-hold resins that could feel stiff or flaky. By adjusting the ratio of the two building blocks, manufacturers learned to fine-tune how much grip or smoothness the polymer provides.

Production starts with two liquid monomers. Under controlled heat and the presence of an initiator, they react and form long repeating chains. The finished polymer is then filtered, purified and dried or kept as a viscous solution ready for blending into products.

You will most often see this copolymer in rinse-off and leave-on hair care such as shampoos, conditioners, mousses, gels and sprays. It can also pop up in styling creams, anti-frizz serums and temporary color rinses. A few skincare formulas like toners or peel-off masks use it for its light film-forming feel.

Acrylamidopropyltrimonium Chloride/Acrylamide Copolymer’s Cosmetic Benefits/Uses

This ingredient plays more than one role in beauty formulas, making it a versatile pick for product developers.

  • Antistatic: The polymer’s positive charge neutralizes the static electricity that builds on hair strands, helping reduce flyaways and frizz so hair looks smoother and is easier to style.
  • Film Forming: It creates a thin flexible layer on the surface of hair or skin that locks in moisture, boosts shine and improves the product’s staying power without a heavy feel.
  • Hair Fixing: By forming a gentle bond around each strand it provides hold and shape, allowing styles to last longer while still being easy to brush out.

Who Can Use Acrylamidopropyltrimonium Chloride/Acrylamide Copolymer

This polymer is considered gentle enough for all skin and hair types including dry, oily, combination and sensitive skin. Because it is water soluble and does not clog pores it rarely triggers breakouts, though people with extremely reactive skin should still watch for any signs of irritation caused by the overall formula, not the polymer itself.

The ingredient is produced entirely from synthetic sources so it is suitable for vegans and vegetarians. No animal by-products are required during manufacturing, though cruelty-free shoppers should verify that the finished product has not been tested on animals.

Current safety data shows no issues for pregnant or breastfeeding women when the polymer is used topically and in normal cosmetic concentrations. The molecule is large and stays on the surface of hair or skin so systemic absorption is minimal. This is not medical advice and anyone who is pregnant or nursing should consult a healthcare professional before adding a new cosmetic product to their routine, just to be safe.

Acrylamidopropyltrimonium Chloride/Acrylamide Copolymer does not increase photosensitivity and has no known interaction with sun exposure. It is color safe, plays well with most other common cosmetic ingredients and rinses out easily with regular shampoo or cleanser.

Potential Side Effects/Adverse Reactions

Side effects or reactions to topical Acrylamidopropyltrimonium Chloride/Acrylamide Copolymer can vary from person to person. The points below cover potential issues only. When the ingredient is used at the low levels found in finished products most users experience none of these effects.

  • Mild skin or scalp irritation – redening, itching or a tingling sensation can occur in highly sensitive individuals
  • Allergic contact dermatitis – rare cases of redness, swelling or small bumps due to an allergy to the polymer or to trace monomer residues
  • Eye irritation – stinging or watery eyes if the product accidentally gets into the eye area before it dries or is rinsed away
  • Product buildup – with very frequent use hair may feel weighed down or appear dull until clarified with a deeper cleanse

If you notice any of the reactions listed above stop using the product and seek advice from a healthcare professional if symptoms persist or worsen.

Comedogenic Rating

Rating: 0/5

Acrylamidopropyltrimonium Chloride/Acrylamide Copolymer is water soluble and forms a lightweight film that sits on the surface rather than sinking into pores. It does not contain heavy oils or waxes that could trap sebum or dead skin. For these reasons it is considered non-comedogenic.

Suitable for acne-prone or breakout-prone skin.

Because it rinses off easily with regular cleansing it is unlikely to build up on skin or hair, which further lowers the risk of clogged pores.

Summary

Acrylamidopropyltrimonium Chloride/Acrylamide Copolymer is a synthetic polymer that smooths static, forms a flexible film and gives light to medium hold in hair products. Its positive charge helps it bind to hair or skin so it can tame flyaways, lock in moisture and keep styles in place while still washing out with water.

It shows up in many shampoos, conditioners, gels and sprays though it is less well known to shoppers than buzzier ingredients like silicones or proteins. Formulators value it for its reliable performance and gentle feel.

Current research finds the ingredient safe for topical use at the levels seen in cosmetics with very low risk of irritation or pore clogging. As with any new product it is wise to run a quick patch test to make sure your skin or scalp agrees with the full formula.

Was this article helpful?
More from Glooshi:
ADVERTISEMENT
Get all our top headlines in beauty.
Delivered right to your inbox each week. Zero spam, all goodness, opt-out at anytime.
This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.
Get the latest beauty news, top product recommendations & brand-exclusive discount codes direct to your inbox.
Send good feedback:

All feedback is greatly appreciated, anonymous, and will be used to improve the quality of our articles.

This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.
Send bad feedback:

All feedback is greatly appreciated, anonymous, and will be used to improve the quality of our articles.

This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.
Search