Acrylates/Diethylaminoethyl Methacrylate/Ethylhexyl Acrylate Copolymer: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: June 23, 2025
Share:
Inside this article:

All information on this page is verified using The Personal Care Products Council's (PCPC) INCI database. Our ingredient analyses are based exclusively on PCPC's technical data to ensure accuracy and reliability.

What Is Acrylates/Diethylaminoethyl Methacrylate/Ethylhexyl Acrylate Copolymer?

Acrylates/Diethylaminoethyl Methacrylate/Ethylhexyl Acrylate Copolymer is a synthetic polymer created by linking together three key building blocks: diethylaminoethyl methacrylate, ethylhexyl acrylate and small amounts of acrylic or methacrylic acids or their simplest esters. When these monomers are mixed and triggered by heat or a catalyst, they join in a process called free radical polymerization, forming long chains that behave very differently from the liquid ingredients they started as. Because the raw materials are produced in controlled factory settings, the final copolymer is consistent in quality and purity.

Acrylic copolymers first appeared in cosmetics in the 1950s in hair sprays that needed a flexible yet durable film. Chemists soon recognized that adjusting the monomer mix could fine-tune qualities like softness, clarity and water resistance, which opened the door to skin care, color cosmetics and sun care formulas. Today manufacturers often supply the copolymer as a water-based dispersion or a ready-to-use solution that blends smoothly into standard cosmetic production lines.

You will most often find this ingredient in products that need a lightweight coating to boost wear time or create a smooth finish. Common examples include long-wear foundations, eyeliners, mascaras, lip glosses, primers, peel-off face masks, sunscreens and leave-in hair stylers.

Acrylates/Diethylaminoethyl Methacrylate/Ethylhexyl Acrylate Copolymer’s Cosmetic Benefits/Uses

The copolymer’s main job in a formula is to form a thin, continuous film once the product is applied to skin or hair. This film locks active ingredients in place, improves water and rub resistance, enhances shine and helps pigments stay true for longer wear. Because the film is flexible rather than brittle, it feels comfortable, avoids flaking and allows skin to move naturally.

Who Can Use Acrylates/Diethylaminoethyl Methacrylate/Ethylhexyl Acrylate Copolymer

This film former is generally considered suitable for all skin types including oily, combination, normal and dry because it sits on the surface rather than sinking deeply into pores and it has no known effects on sebum production. Sensitive skin usually tolerates it as well since the polymer is chemically stable and non reactive, though anyone with a history of acrylic allergies should proceed with caution.

The ingredient is synthetic and contains no animal derived materials so it is appropriate for vegans and vegetarians. It is also not tested on animals in regions that forbid such practices, though shoppers may still want to check the finished brand’s cruelty free policy.

Current safety assessments do not flag the copolymer as a concern for pregnant or breastfeeding women when used in normal cosmetic concentrations. That said this is not medical advice and anyone who is expecting or nursing should run any product past a qualified healthcare professional to be on the safe side.

The polymer does not make skin more sensitive to sunlight and has no photosensitizing properties. It can even boost the water resistance of sunscreens which indirectly helps with sun protection. Because it forms a breathable film it can be layered with most other active ingredients without issue.

Potential Side Effects/Adverse Reactions

Reactions to topical Acrylates/Diethylaminoethyl Methacrylate/Ethylhexyl Acrylate Copolymer vary from person to person. The following is a list of potential side effects that could occur even though most users will not experience them when the ingredient is used correctly in a well formulated product.

  • Mild skin irritation such as redness stinging or itching
  • Allergic contact dermatitis in individuals sensitive to acrylic compounds
  • Eye irritation if the product accidentally gets into the eyes
  • Temporary pore blockage or surface buildup when very heavy layers are applied repeatedly without proper cleansing

If any of the above reactions occur stop using the product and consult a medical professional for advice.

Comedogenic Rating

Rating: 1 out of 5. Acrylates/Diethylaminoethyl Methacrylate/Ethylhexyl Acrylate Copolymer is a large water-friendly polymer that sits on the surface rather than melting into oil glands, so it is very unlikely to clog pores. It does not add extra oils or waxes and it forms a breathable film that is washed away with normal cleansing. Because of this low tendency to block follicles it is generally suitable for people who are prone to acne or breakouts. In rare cases buildup can occur if heavy layers are left on for days without proper removal, so regular cleansing is still important.

Summary

Acrylates/Diethylaminoethyl Methacrylate/Ethylhexyl Acrylate Copolymer is mainly used as a film former. After you apply a product the polymer dries into a thin flexible layer that locks pigments and actives in place, boosts water and rub resistance and adds a smooth even finish. This ability makes it popular in long wear makeup, sunscreens and styling products, though it is not as well known to shoppers because it usually appears low on the ingredient list.

Current safety reviews find the copolymer non irritating for most users, non comedogenic and free of major health concerns at the levels used in cosmetics. Still, skin can be unpredictable so it is wise to patch test any new product that contains it before full use.

Was this article helpful?
More from Glooshi:
ADVERTISEMENT
Get all our top headlines in beauty.
Delivered right to your inbox each week. Zero spam, all goodness, opt-out at anytime.
This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.
Get the latest beauty news, top product recommendations & brand-exclusive discount codes direct to your inbox.
Send good feedback:

All feedback is greatly appreciated, anonymous, and will be used to improve the quality of our articles.

This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.
Send bad feedback:

All feedback is greatly appreciated, anonymous, and will be used to improve the quality of our articles.

This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.
Search