Acrylates/Methacryloyl Propyltrimethoxysilane Crosspolymer: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: June 23, 2025
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All information on this page is verified using publicly available nomenclature standards and reference materials from The Personal Care Products Council (PCPC) and the European Commission's CosIng database. Our analyses are based on technical data from these sources to ensure accuracy and reliability.

What Is Acrylates/Methacryloyl Propyltrimethoxysilane Crosspolymer?

Acrylates/Methacryloyl Propyltrimethoxysilane Crosspolymer is a synthetic polymer made by linking acrylic or methacrylic acid units with Methacryloyl Propyltrimethoxysilane, then crosslinking the chain with a small connector called 1,4-butanediol dimethacrylate. The silane part gives the final material a light silicone-like touch while the acrylic backbone keeps it flexible. The ingredient does not come from a natural plant or animal source; it is produced in a controlled lab setting where the raw monomers are blended, triggered to react and then purified into a fine powder.

Polymers like this started showing up in cosmetics in the late 1990s when chemists looked for new ways to form soft, breathable films on skin without the tacky feel older resins left behind. The added silane groups helped the film resist water and improve wear time so makeup and skin care stayed put longer.

During manufacture, the monomers are mixed in a solvent, exposed to heat or a small amount of initiator to spark the reaction, then crosslinked to lock the network in place. The resulting gel is dried and milled into uniform particles. Because the process happens inside closed reactors, the end product is free of unreacted monomers by the time it reaches formulators.

Today you will most often find Acrylates/Methacryloyl Propyltrimethoxysilane Crosspolymer in long-wear foundations, BB creams, tinted moisturizers, sunscreens, primers, setting sprays, peel-off masks and hair styling products where a light, flexible film is needed to hold pigments or active ingredients on the surface.

Acrylates/Methacryloyl Propyltrimethoxysilane Crosspolymer’s Cosmetic Benefits/Uses

This ingredient serves one key purpose in a formula which brings several practical benefits.

Film forming: Once the product is applied the polymer lays down an invisible, flexible layer that helps pigments, UV filters or skin care actives stay where you put them. This film improves water resistance, extends wear time, reduces smudging and gives skin a smooth feel without heaviness.

Who Can Use Acrylates/Methacryloyl Propyltrimethoxysilane Crosspolymer

This film former is considered suitable for most skin types including normal, oily, combination and dry because it sits on top of the skin rather than soaking in. Sensitive or compromised skin can usually tolerate it as well since it is chemically inert, though people with a known allergy to acrylates should be cautious. The ingredient is non animal derived and produced entirely in a lab, so it is appropriate for vegans and vegetarians.

No specific warnings exist for pregnant or breastfeeding women, yet out of an abundance of caution they should show any product containing this polymer to their doctor before regular use. Acrylates/Methacryloyl Propyltrimethoxysilane Crosspolymer does not absorb UV light so it does not cause photosensitivity. It is fragrance free and has no known interactions with common actives like vitamin C, retinoids or hydroxy acids.

Potential Side Effects/Adverse Reactions

Responses to topical Acrylates/Methacryloyl Propyltrimethoxysilane Crosspolymer can differ from person to person. The points below outline possible but uncommon reactions when the ingredient is used at normal cosmetic levels and formulated correctly.

Skin redness or mild irritation in individuals who are allergic to acrylic resins

Transient tightness or dryness if the formula contains high levels of alcohol and the film reduces skin breathability

Eye stinging if the powder or finished product gets into the eyes before it sets

If you notice any of the reactions above discontinue use and consult a healthcare professional.

Comedogenic Rating

Rating: 1 out of 5. Acrylates/Methacryloyl Propyltrimethoxysilane Crosspolymer is a large, non-oily molecule that creates a breathable film on the surface instead of seeping into pores. Because it is not greasy and does not feed surface bacteria it is very unlikely to clog pores, yet any film former can theoretically trap existing sebum or debris in rare cases, so it does not earn a perfect zero.

Suitable for acne-prone or easily congested skin in most situations.

No noteworthy interactions with common acne treatments such as benzoyl peroxide or salicylic acid have been reported.

Summary

Acrylates/Methacryloyl Propyltrimethoxysilane Crosspolymer is primarily a film former that locks pigments, UV filters and active ingredients onto skin or hair. Its hybrid acrylic-silane structure lets it form a flexible, water-resistant layer that boosts wear time, improves spread and gives a smooth afterfeel.

The polymer sits comfortably in modern long wear foundations, tinted sunscreens, primers and setting sprays, though it is not as famous as classic silicones or carbomers because it is usually one of many helpers in a formula rather than the star ingredient.

Safety profiles from industry and independent panels rate it as low risk with minimal irritation potential. Still, skin is personal, so do a small patch test when you try a new product containing this polymer to make sure it suits you.

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