Acrylates/Octylacrylamide/Diphenyl Amodimethicone Copolymer: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: June 23, 2025
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All information on this page is verified using The Personal Care Products Council's (PCPC) INCI database. Our ingredient analyses are based exclusively on PCPC's technical data to ensure accuracy and reliability.

What Is Acrylates/Octylacrylamide/Diphenyl Amodimethicone Copolymer?

Acrylates/Octylacrylamide/Diphenyl Amodimethicone Copolymer is a man-made blend of three key parts: octylacrylamide, diphenyl amodimethicone and small acrylic or methacrylic units. When these parts join together they create a lightweight film-forming material that works well on hair. The idea of mixing silicone pieces like diphenyl amodimethicone with acrylics took shape in the late 1990s as chemists looked for styling agents that could give hold yet keep hair soft. Today most production starts with liquid acrylic monomers and silicone fluids that are combined in large reactors, heated and then cooled to form a smooth milky polymer solution. Because it is water-resistant yet flexible this ingredient shows up in many everyday products such as styling gels, hair sprays, leave-in conditioners, waxes and creams aimed at frizz control or heat protection.

Acrylates/Octylacrylamide/Diphenyl Amodimethicone Copolymer’s Cosmetic Benefits/Uses

This ingredient earns its place in formulas because it can improve both how hair looks and how it behaves.

  • Hair Conditioning: Forms a thin coating that smooths the cuticle so strands feel softer, look shinier and detangle more easily. The silicone part adds slip which helps reduce breakage during brushing
  • Hair Fixing: Creates a flexible film that holds a style in place without making hair stiff or crunchy. The acrylic part lends staying power while resisting humidity so curls, waves or updos last longer

Who Can Use Acrylates/Octylacrylamide/Diphenyl Amodimethicone Copolymer

This copolymer is generally friendly to all skin and hair types. Because it sits on the surface and does not sink deeply into skin, it rarely triggers dryness or excess oil, making it fine for normal, dry, oily and combination skin. Sensitive skin types can usually handle it too, though they should stay alert for any irritation simply because every person is different. No specific skin type is considered unsuitable.

The ingredient is fully synthetic and contains no animal by-products, so it is suitable for both vegans and vegetarians. Cruelty-free status depends on the end brand’s testing policy rather than the ingredient itself.

Current safety data show no issues for women who are pregnant or breastfeeding when the ingredient is used topically in rinse-off or leave-on hair products. This is not medical advice; anyone who is expecting, nursing or under medical care should show the full product list to a qualified health professional before use just to be safe.

Acrylates/Octylacrylamide/Diphenyl Amodimethicone Copolymer does not make skin more prone to sunburn, so it is not considered photosensitising. It also plays well with common styling aids like proteins, humectants and most silicones, so formulators can blend it without worrying about unexpected reactions.

Potential Side Effects/Adverse Reactions

Responses to topical use of Acrylates/Octylacrylamide/Diphenyl Amodimethicone Copolymer vary from person to person. The points below list potential side effects, but most users will not run into these issues when the ingredient is used at normal levels in properly made products.

  • Mild scalp or skin irritation such as redness or itching
  • Build-up on hair leading to a heavy feel or reduced volume
  • Allergic contact dermatitis in people already allergic to acrylate compounds
  • Eye discomfort if the product accidentally gets into the eyes

If you notice any of these effects stop using the product and speak with a healthcare professional or dermatologist.

Comedogenic Rating

Rating: 1 / 5
The molecule is bulky, sits on the surface and is mostly water-repellent silicone and acrylic segments that do not mix with skin oils, so it is unlikely to block pores. It can, however, trap sweat or sebum if layered with heavy butters or waxes which is why it is given a low but not zero score. Suitable for acne-prone or breakout-prone users in most cases.

Summary

Acrylates/Octylacrylamide/Diphenyl Amodimethicone Copolymer works as a dual-action styling helper: the acrylic side provides flexible hold that resists humidity while the silicone side smooths the cuticle for softness and shine. That mix explains its steady presence in sprays, creams and serums found on drugstore and salon shelves alike, though it is not as famous as classic styling polymers like PVP.

Current research and marketplace use rate it as safe for topical application with only rare irritation or build-up issues reported. As with any new cosmetic ingredient it is smart to do a quick patch test before fully committing to a product that contains it, just to be safe.

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