Acrylates/T-Butylacrylamide Copolymer: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: June 23, 2025
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All information on this page is verified using The Personal Care Products Council's (PCPC) INCI database. Our ingredient analyses are based exclusively on PCPC's technical data to ensure accuracy and reliability.

What Is Acrylates/T-Butylacrylamide Copolymer?

Acrylates/T-Butylacrylamide Copolymer is a man-made polymer created by linking together tert-butyl acrylamide with acrylic or methacrylic acid units. The result is a lightweight flexible plastic-like material that can be dissolved or dispersed in water or alcohol. First explored by chemists in the 1960s as they searched for new styling resins, it quickly found a place in hair sprays and has since spread to many other beauty formulas.

Manufacturing begins with liquid monomers that are blended in large reactors. When heat or a small amount of catalyst is added, the monomers join into long chains in a controlled process called free-radical polymerization. The finished mixture is filtered, neutralized and dried into a fine powder or delivered as an aqueous dispersion that formulators can drop straight into their batches.

Because the polymer forms a clear flexible film once the water or alcohol evaporates, you will often see it in hair sprays, styling gels, mascara, brow gels, waterproof eyeliners, long-wear foundations, peel-off face masks and certain sunscreens. Its ability to lock a style or coat the skin without feeling stiff makes it a versatile workhorse in modern cosmetics.

Acrylates/T-Butylacrylamide Copolymer’s Cosmetic Benefits/Uses

In beauty products this ingredient serves two key roles that improve both performance and user experience.

  • Film forming – Once applied it dries into an invisible flexible layer that helps makeup last longer, shields skin from smudging and adds water resistance to products like mascara or sunscreen
  • Hair fixing – The polymer wraps each strand in a thin coat that holds styles in place, fights frizz and provides touchable hold without flaking

Who Can Use Acrylates/T-Butylacrylamide Copolymer

This ingredient is generally considered suitable for every skin type from oily to dry because it forms a breathable light film that lets moisture escape instead of trapping it beneath a heavy layer. Very sensitive or eczema-prone skin could react to any film former so those users may prefer to proceed with extra care.

Acrylates/T-Butylacrylamide Copolymer is a fully synthetic resin made from petrochemical feedstocks. No animal-derived substances are involved in its production which makes it acceptable for vegans and vegetarians.

The polymer molecules are large and stay on the surface of skin and hair so they are not expected to enter the bloodstream. Current safety assessments find no reproductive toxicity which means products containing it are normally viewed as safe during pregnancy or while breastfeeding. This is not medical advice and pregnant or nursing individuals should clear any cosmetic routine with their doctor first just to be sure.

The ingredient is not known to increase photosensitivity and it plays well with everyday actives like vitamin C or niacinamide. It can be paired with chemical or mineral sunscreens without breaking them down.

Potential Side Effects/Adverse Reactions

Reactions to topical Acrylates/T-Butylacrylamide Copolymer differ from person to person. The list below covers potential issues yet most people will not run into them when the ingredient is used at the levels found in finished cosmetics.

  • Mild skin irritation or redness especially on compromised or freshly exfoliated skin
  • Contact dermatitis in individuals allergic to acrylate type resins or trace residual monomers
  • Eye irritation if styling sprays or mascaras containing the polymer flake or drip into the eye
  • Scalp build up and dullness when heavy styling products are layered without thorough cleansing
  • Dry or stiff feeling hair if high hold formulas are overapplied

If any of these issues occur stop using the product and speak with a healthcare professional or dermatologist for guidance.

Comedogenic Rating

Rating: 0. Acrylates/T-Butylacrylamide Copolymer sits on the surface as a large, water-compatible film that is too bulky to slip into pores or mix with skin oils, so it is considered non-comedogenic. This makes it a low-risk choice for people prone to acne or breakouts. Only in rare cases where thick layers of styling products or long-wear makeup are left on overnight could residue trap dirt and indirectly invite blemishes, so thorough cleansing at the end of the day is advisable.

Summary

Acrylates/T-Butylacrylamide Copolymer works as a film former and hair fixative. It dries into a clear flexible mesh that locks makeup in place, adds water resistance to mascara and sunscreen and coats hair strands for lasting hold without visible flakes. While not a headline-grabbing ingredient, it appears in countless hair sprays, brow gels, foundation primers and peel-off masks, quietly powering the long-wear claims shoppers expect.

Safety reviews find it non-irritating for most users, non-comedogenic and suitable during pregnancy when used as directed. As with any cosmetic ingredient personal sensitivity can vary, so patch testing a new product before full-face or full-scalp use is always a smart move.

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