Acrylates/Va Crosspolymer: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: June 23, 2025
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All information on this page is verified using The Personal Care Products Council's (PCPC) INCI database. Our ingredient analyses are based exclusively on PCPC's technical data to ensure accuracy and reliability.

What Is Acrylates/Va Crosspolymer?

Acrylates/VA Crosspolymer is a man-made ingredient created by linking vinyl acetate with acrylic or methacrylic acid units using a small amount of a three-armed connector called triallylisocyanurate. This crosslinking turns the material into a lightweight porous network rather than a straight chain, giving it special film-forming abilities. First developed for industrial coatings, the polymer quickly caught the eye of cosmetic chemists in the late 1980s when they noticed its smooth feel, clarity and flexible hold on skin and hair.

Production begins with vinyl acetate and acrylic acid derivatives dissolved in water or solvent. Under controlled heat and the presence of a catalyst, the monomers react while the crosslinker ties the chains together. Once polymerisation is complete, the slurry is neutralised, purified and dried into a fine white powder that disperses readily in water or alcohol.

Because it forms transparent, breathable films, Acrylates/VA Crosspolymer is now found in a wide range of leave-on and rinse-off products. These include facial masks, gels, setting sprays, hair styling creams, long-wear makeup, sunscreens, moisturisers and anti-aging serums where it helps the formula stay in place and resist smudging or flaking.

Acrylates/Va Crosspolymer’s Cosmetic Benefits/Uses

In skincare and haircare formulas this ingredient performs a single yet important role.

As a film forming agent it creates a thin flexible layer on the surface of skin or hair. This film locks active ingredients where they are needed, boosts water resistance, improves wear time of makeup and sunscreens, reduces transfer, tames flyaways and gives products a smooth even finish without a sticky feel.

Who Can Use Acrylates/Va Crosspolymer

This polymer suits nearly every skin type including dry, normal, combination, oily and even sensitive skin because it forms a breathable lightweight film that does not trap excessive oil or disrupt the skin barrier. Extremely reactive skin may prefer a patch test due to the small possibility of sensitivity to synthetic polymers but most users tolerate it well.

Acrylates/VA Crosspolymer is produced entirely from petroleum derived monomers and contains no animal sourced material so it is appropriate for vegetarians and vegans.

The molecule is large and stays on the skin surface rather than being absorbed so it is generally regarded as safe for pregnant or breastfeeding women. This is not medical advice and anyone who is expecting or nursing should confirm product choices with a qualified healthcare professional.

The ingredient does not induce photosensitivity and will not make skin more prone to sunburn. It can actually help keep sunscreen actives in place by improving water resistance.

Potential Side Effects/Adverse Reactions

Responses to topical Acrylates/VA Crosspolymer vary between individuals. The points below outline potential side effects yet they are unlikely for the average user when the ingredient is properly formulated and used as directed.

  • Mild skin irritation such as redness or itching in people sensitive to synthetic polymers
  • Allergic contact dermatitis in rare cases of true allergy to acrylate chemistry
  • Transient eye stinging or watering if the product accidentally gets into the eyes
  • Build up and dullness on hair shafts when heavy styling products are not washed out regularly
  • Pore congestion for very acne prone users if layered with heavy occlusive ingredients

If any unwanted reaction occurs discontinue use and seek advice from a healthcare professional or dermatologist.

Comedogenic Rating

Rating: 1/5 Acrylates/VA Crosspolymer sits on the surface and forms a breathable film that allows water vapor to pass through so it is unlikely to clog pores. It is oil free and does not add extra lipids that could trap dead skin cells yet very acne prone skin might notice issues if the polymer is layered with heavy oils or not cleansed off properly. Overall it is considered suitable for people who break out easily.

Because it rinses away with normal cleansing and is used at low levels the chance of it building up inside pores is low. Products that rely on it for water resistance may need a good double cleanse to avoid leftover residue.

Summary

Acrylates/VA Crosspolymer is used mainly as a film former. It links up into a flexible mesh on skin or hair that locks active ingredients in place boosts water resistance cuts transfer and delivers a smooth finish. This same network gives light hold in hair styling products and keeps makeup or sunscreen from sliding off during the day.

The polymer is quite popular in long wear cosmetics sun care sprays styling creams and peel off masks because it offers performance without a heavy feel. It is less talked about than trendy actives yet formulators rely on it for dependable staying power.

Safety profiles rate it as low risk since the large molecule does not penetrate living skin. Most users experience no irritation but as with any new product it is smart to patch test first to be sure your skin agrees with the formula.

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