Adipic Acid/Epoxypropyl Diethylenetriamine Copolymer: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: June 23, 2025
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All information on this page is verified using publicly available nomenclature standards and reference materials from The Personal Care Products Council (PCPC) and the European Commission's CosIng database. Our analyses are based on technical data from these sources to ensure accuracy and reliability.

What Is Adipic Acid/Epoxypropyl Diethylenetriamine Copolymer?

Adipic Acid/Epoxypropyl Diethylenetriamine Copolymer is a synthetic polymer created by combining adipic acid, diethylenetriamine and epoxypropyl groups. The result is a large, flexible molecule that can form thin films on skin or hair. First developed for industrial coatings, chemists soon noticed its ability to tame static and hold shapes which led to its introduction into hair styling products in the late twentieth century. Production starts with adipic acid derived from petrochemical feedstocks, which is reacted with diethylenetriamine. The intermediate blend is then treated with epoxypropyl chloride to extend the chain and give the final copolymer its film forming traits. After purification and drying the solid polymer is milled into a fine powder or supplied as an aqueous solution ready for cosmetic labs.

You will most often spot this ingredient in hairsprays, styling gels, mousses and leave in conditioners. It is also added to certain skin primers, long wear foundations and peel off face masks where a flexible film is desirable.

Adipic Acid/Epoxypropyl Diethylenetriamine Copolymer’s Cosmetic Benefits/Uses

This versatile polymer brings several performance perks to modern formulas

  • Antistatic – reduces electrical charge on hair strands so flyaways and frizz are less likely to appear, giving hair a smoother, more polished look
  • Film forming – creates a lightweight, breathable layer that helps lock in moisture, protect against humidity and improve the spreadability and wear time of makeup and skin care products
  • Hair fixing – provides hold and shape retention in styling products, allowing hairstyles to last longer without feeling stiff or sticky

Who Can Use Adipic Acid/Epoxypropyl Diethylenetriamine Copolymer

This polymer suits all skin and hair types including oily, dry and combination because it forms a breathable film that does not clog pores or trap excess oil. Extremely sensitive or eczema-prone users may want to monitor for irritation since any synthetic polymer can occasionally cause discomfort on compromised skin.

The ingredient is fully synthetic and contains no animal derivatives so it is acceptable for vegans and vegetarians.

No data suggest that the polymer can penetrate deeply or reach systemic circulation, therefore it is generally considered safe for pregnant or breastfeeding people. This is not medical advice; anyone who is pregnant or nursing should ask a doctor before adding new products to their routine.

The polymer does not make skin more reactive to sunlight and has no reported photosensitising effect. It can be paired with daytime products without extra sun precautions beyond a normal broad-spectrum sunscreen.

Potential Side Effects/Adverse Reactions

Responses to topical Adipic Acid/Epoxypropyl Diethylenetriamine Copolymer vary from person to person. The following outlines potential side effects which are uncommon when the ingredient is formulated correctly.

  • Mild skin irritation such as redness stinging or itching on very sensitive skin
  • Contact dermatitis in individuals allergic to amine-based polymers
  • Eye irritation if aerosol sprays or gels are used too close to the eye area
  • Scalp buildup leading to dullness or flakes if high-hold styling products are not washed out regularly
  • Respiratory discomfort when inhaled from aerosol hairsprays in poorly ventilated spaces

Discontinue use and consult a healthcare professional if any uncomfortable reaction occurs.

Comedogenic Rating

Rating: 1/5 (very low)

The copolymer molecules are large and sit on the surface rather than sinking into pores, plus they are not oily or waxy so they do not feed the bacteria that drive breakouts. For that reason the ingredient is considered unlikely to clog pores and is generally fine for acne-prone skin.

As with most film formers, buildup can occur if products are layered heavily without proper cleansing. A simple rinse-off cleanser at the end of the day keeps residue from accumulating and further reduces any pore-blocking risk.

Summary

Adipic Acid/Epoxypropyl Diethylenetriamine Copolymer acts as an antistatic agent, a flexible film former and a hair-fixing resin. Its long chain structure spreads into a thin mesh that smooths stray charges, locks style in place and shields hair or skin from humidity while staying lightweight.

It is a niche yet useful ingredient that shows up most often in hairsprays and gels, occasionally in long-wear makeup. You will not see it hyped on social media but formulators appreciate the reliable hold it delivers without stickiness.

Current safety data classifies the polymer as low risk with minimal irritation potential when used as directed. Still, every skin type is unique so performing a small patch test with any new product is the safest approach.

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