Ammonium Acrylates Copolymer: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: June 23, 2025
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All information on this page is verified using The Personal Care Products Council's (PCPC) INCI database. Our ingredient analyses are based exclusively on PCPC's technical data to ensure accuracy and reliability.

What Is Ammonium Acrylates Copolymer?

Ammonium Acrylates Copolymer is a man-made ingredient created by linking together acrylic acid and methacrylic acid units, then neutralizing them with ammonia to form stable ammonium salts. The result is a flexible water-soluble polymer that behaves much like a transparent gel in formulas.

Chemists first explored acrylic polymers in the mid 1900s for use in paints and adhesives. Their ability to form clear thin films soon caught the attention of cosmetic makers looking for lightweight hold and smooth texture. Over time safety testing and refinements led to the specific grade now used in personal care.

The copolymer is produced in large stainless-steel reactors where the monomers are mixed with water, an initiator and controlled heat. As the reaction proceeds the small monomer molecules hook together into long chains. Once the desired thickness is reached the mixture is cooled, purified and dried or left as a liquid gel for easy blending.

You will most often find Ammonium Acrylates Copolymer in hair sprays, gels, mousses, leave-in conditioners, facial masks, serums, sunscreens, light lotions and long-wear makeup. Brands value its clear finish and versatility in both water-based and hydro-alcoholic systems.

Ammonium Acrylates Copolymer’s Cosmetic Benefits/Uses

Formulators rely on this polymer for several practical reasons that improve how a product looks, feels and performs.

  • Antistatic – helps reduce flyaways by preventing the buildup of static charge on hair or skin
  • Binding – keeps pigments, powders and other particles evenly dispersed so the formula stays uniform from first pump to last
  • Film Forming – creates a thin breathable layer that boosts shine, sets style and supports long-lasting wear without stickiness
  • Viscosity Controlling – adjusts thickness giving lotions a silky flow, gels a bouncy texture and sprays the right level of hold

Who Can Use Ammonium Acrylates Copolymer

This polymer is generally considered suitable for all skin and hair types including oily, dry, combination and mature skin because it is water soluble lightweight and non occlusive. People with extremely sensitive skin or a known allergy to acrylic ingredients should exercise caution as even trace residues could trigger redness or itching.

The ingredient is synthesized from petroleum derived monomers and neutralized with ammonia, with no animal sourced materials involved, so it is acceptable for vegans and vegetarians. As always cruelty free status depends on the brand’s overall testing policies rather than the raw material itself.

Current safety reviews show no reproductive toxicity and the large molecular size limits skin penetration, so products containing Ammonium Acrylates Copolymer are viewed as low risk for pregnant or breastfeeding women. This is not medical advice; anyone who is pregnant or nursing should discuss each product they plan to use with a qualified healthcare professional to be sure it meets their personal needs.

The polymer does not increase photosensitivity and can be worn in daytime formulas alongside sunscreen without special precautions. It is odorless, colorless and compatible with most other cosmetic ingredients, making adverse interactions unlikely.

Potential Side Effects/Adverse Reactions

Individual responses to topical Ammonium Acrylates Copolymer vary. The effects listed below are only potential outcomes and are uncommon when the ingredient is formulated correctly.

  • Mild skin irritation such as transient redness or stinging in very sensitive users
  • Allergic contact dermatitis in those already sensitized to acrylic compounds
  • Eye irritation if hair spray or similar products are accidentally misted into the eyes
  • Scalp or hair buildup that can feel stiff or flaky if the product is applied excessively and not washed out

If any discomfort or unexpected reaction occurs discontinue use and consult a healthcare professional or dermatologist for further guidance.

Comedogenic Rating

Rating: 0/5. Ammonium Acrylates Copolymer is a large water-soluble molecule that sits on the surface and rinses away easily so it does not clog pores or trap oil. Its lightweight film allows skin to breathe which keeps dead cells and sebum from building up in follicles. Because of this it is generally considered safe for people who are prone to acne or breakouts. In rare cases buildup can occur if very heavy layers are not cleansed off, but normal washing removes it without trouble.

Summary

Ammonium Acrylates Copolymer acts as an antistatic agent, binder, film former and viscosity controller. It reduces flyaways by neutralizing static, keeps pigments evenly suspended, forms a clear flexible film that adds shine and hold, and fine-tunes thickness so products feel silky not sticky. Its ability to do all of this without adding weight or haze makes it a handy multitasker in hair sprays, gels, light lotions and long-wear makeup.

The ingredient is moderately popular-you will spot it regularly in styling products and some skincare though it is not as ubiquitous as silicones or carbomers. It has a solid safety record with low irritation potential and virtually no risk of pore clogging. Still, skin is personal so when trying any new formula that contains it a quick patch test is a smart way to confirm compatibility.

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