Ammonium Styrene/Ma Copolymer: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: June 23, 2025
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All information on this page is verified using The Personal Care Products Council's (PCPC) INCI database. Our ingredient analyses are based exclusively on PCPC's technical data to ensure accuracy and reliability.

What Is Ammonium Styrene/Ma Copolymer?

Ammonium Styrene/Ma Copolymer is a synthetic ingredient created by reacting styrene, maleic anhydride and ammonia, which results in a water-friendly salt. Think of it as a plastic-like backbone with spots that love water, letting it sit comfortably in creams and lotions. First explored in the mid-20th century by the plastics industry, formulators soon noticed the copolymer’s knack for keeping oil and water blended, so it migrated into personal care labs. Production involves polymerizing styrene with maleic anhydride, neutralizing the mixture with ammonium hydroxide, then purifying and drying the final powder or granules. You will most often find it in facial masks, lightweight moisturizers, hair gels, sunscreens, leave-in conditioners and long-wear makeup where a stable, smooth texture is essential.

Ammonium Styrene/Ma Copolymer’s Cosmetic Benefits/Uses

This ingredient is prized for one main job in cosmetic formulas.

Emulsion stabilising: It helps oils, silicones and water stay evenly mixed throughout a product’s shelf life so your cream doesn’t split, the texture feels silky and every application delivers the same level of active ingredients.

Who Can Use Ammonium Styrene/Ma Copolymer

This polymer is gentle enough for most skin types including oily, dry and combination skin. Because it sits on the surface and does not sink deeply into pores it rarely clogs or causes breakouts, so acne-prone users usually tolerate it well.

The ingredient is made entirely from lab-made chemicals and contains no animal-derived matter, so it is suitable for vegans and vegetarians.

Current safety data shows no known risks for women who are pregnant or breastfeeding when the copolymer is used in normal cosmetic amounts. Still, this is not medical advice and anyone who is expecting or nursing should run any product past a doctor to be on the safe side.

Ammonium Styrene/Ma Copolymer does not increase sun sensitivity, and it has no known interactions with common skincare actives like retinoids or acids.

Potential Side Effects/Adverse Reactions

Side effects and reactions to the topical use of Ammonium Styrene/Ma Copolymer can vary from person to person. The points below list potential issues that could occur, but they are uncommon when the ingredient is used correctly in a finished product.

  • Mild skin irritation
  • Redness or itching for those with very sensitive skin
  • Eye stinging if the product is accidentally rubbed into the eyes
  • Build-up on hair that may feel tacky if used in high-hold styling gels

If you notice any of these reactions stop using the product and consult a healthcare professional or dermatologist.

Comedogenic Rating

Rating: 1/5

Ammonium Styrene/Ma Copolymer is a large, water-friendly polymer that stays on the skin surface and does not mix with sebum, so it has very little chance of blocking pores. Formulas usually include it at low levels purely to hold emulsions together which keeps the comedogenic risk minimal. This makes the ingredient generally suitable for people prone to acne or breakouts. As with any cosmetic, overall formulation and cleansing habits can influence how a product behaves on blemish-prone skin.

Summary

Ammonium Styrene/Ma Copolymer acts mainly as an emulsion stabilizer, using its water-loving salt groups to latch onto the watery phase while its styrene backbone anchors into oils. This dual nature forms an invisible web that stops oil and water from separating, keeping creams smooth, sunscreens even and hair gels consistent from first use to the last drop.

You will not see flashy marketing built around this polymer, yet it shows up quietly in many mainstream lotions, gels, sprays and long-wear makeup where reliability counts. Its safety profile is strong: the molecule is too large to penetrate skin, it is non-sensitizing for most users and it carries a very low comedogenic rating. Still, skin can be unpredictable so it is wise to patch test any new product that contains Ammonium Styrene/Ma Copolymer before adding it to your daily routine.

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