Amp-Acrylates/Dimethylaminoethylmethacrylate Copolymer: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: June 23, 2025
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All information on this page is verified using The Personal Care Products Council's (PCPC) INCI database. Our ingredient analyses are based exclusively on PCPC's technical data to ensure accuracy and reliability.

What Is Amp-Acrylates/Dimethylaminoethylmethacrylate Copolymer?

Amp-Acrylates/Dimethylaminoethylmethacrylate Copolymer is a synthetic ingredient created by linking together small units of dimethylaminoethyl methacrylate with acrylic or methacrylic acid units that have been neutralized by 2-methyl-2-amino-1-propanol. The result is a large, flexible molecule that dissolves in water and forms clear films when it dries. First explored in the late 1970s as part of the search for better hair-setting agents, this copolymer quickly gained traction with formulators because it offered strong hold without a stiff or flaky finish.

Production begins with petroleum-derived monomers that are purified then mixed in precise ratios. Through a controlled polymerization process, these small molecules join into long chains. Adjusting factors like temperature, pH and reaction time lets chemists dial in the exact viscosity and performance traits needed for different cosmetic applications. The finished copolymer is usually supplied as a clear, slightly viscous liquid or as a dry powder ready to be blended into water-based formulas.

Today you will spot Amp-Acrylates/Dimethylaminoethylmethacrylate Copolymer in a wide range of hair styling products including mousses, gels, sprays and defining creams. It also shows up in some brow gels, mascara bases, peel-off masks and long-wear makeup where a flexible film is useful for staying power.

Amp-Acrylates/Dimethylaminoethylmethacrylate Copolymer’s Cosmetic Benefits/Uses

This ingredient earns its place in formulas by delivering two main performance perks:

  • Film forming: When the product dries the copolymer creates an invisible mesh that clings to hair or skin. This film locks in style, improves water resistance, enhances shine and helps prevent flaking in color cosmetics
  • Hair fixing: The polymer’s positive charge interacts with the natural negative charge on hair fibers, giving reliable hold and shape memory. Styles stay in place longer yet can still be brushed out without heavy buildup

Who Can Use Amp-Acrylates/Dimethylaminoethylmethacrylate Copolymer?

The copolymer is considered suitable for most skin types including oily, combination, dry and even sensitive skin because it stays on the surface and forms a light breathable film rather than sinking into deeper layers. People with very reactive skin may still want to watch for any sign of redness or tightness since any film former can occasionally trap sweat or bacteria.

Hair products that rely on this polymer work well on fine, thick, curly or straight hair thanks to its flexible hold. It rinses out with regular shampoo so it is unlikely to weigh strands down when used as directed.

Because the ingredient is fully synthetic and made from petroleum sourced monomers it contains no animal derived materials, so it is generally accepted by both vegans and vegetarians. Final confirmation depends on the overall formulation and the brand’s animal testing policy.

No specific warnings exist for pregnant or breastfeeding women and the polymer’s large molecular size limits any chance of absorption through the skin. This is not medical advice and anyone who is expecting or nursing should still show the full ingredient list of a product to their doctor to be safe.

Amp-Acrylates/Dimethylaminoethylmethacrylate Copolymer is not known to cause photosensitivity and does not break down into sun reactive by-products, so it can be worn during the day without raising the risk of sunburn.

Potential Side Effects/Adverse Reactions

Responses to topical use of Amp-Acrylates/Dimethylaminoethylmethacrylate Copolymer can differ from person to person. The effects listed below are only potential issues and most users will not notice any problems when the ingredient is formulated and used correctly.

  • Mild skin or scalp irritation such as redness or itching
  • Eye stinging if the wet product drips into the eyes
  • Build up on hair strands leading to dullness if not washed out regularly
  • Allergic contact dermatitis in people who are already allergic to methacrylate type materials

If you notice any unwanted reaction stop using the product and consult a healthcare professional or dermatologist.

Comedogenic Rating

Rating: 0–1. Amp-Acrylates/Dimethylaminoethylmethacrylate Copolymer is a large water-soluble polymer that does not melt into skin lipids or clog pores. It sits on the surface, forms a breathable film and is typically used at low concentrations. Because it is not oily or waxy the chance of it blocking follicles is minimal.

Suitable for acne-prone and breakout-prone skin.

Formulas that combine this polymer with heavy oils, silicones or butters could still pose a clogging risk, so always judge the whole ingredient list rather than one component.

Summary

Amp-Acrylates/Dimethylaminoethylmethacrylate Copolymer is valued for two main jobs: it forms a clear flexible film and it provides reliable hair hold by bonding lightly to the hair cuticle. These abilities come from its large charged polymer chains that line up on the surface then lock together as water evaporates, giving staying power without stiffness.

The ingredient is a staple in mousses, gels and long-wear makeup though it is not as headline-grabbing as trendy plant extracts. Formulators like it because it is predictable, cost-effective and works across many product textures.

Overall safety reports are favorable with low irritation or sensitization rates. Still, every skin is different so do a quick patch test when trying a new product that features this polymer to make sure it suits you.

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