Ampd-Acrylates/Diacetoneacrylamide Copolymer: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: June 23, 2025
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All information on this page is verified using The Personal Care Products Council's (PCPC) INCI database. Our ingredient analyses are based exclusively on PCPC's technical data to ensure accuracy and reliability.

What Is Ampd-Acrylates/Diacetoneacrylamide Copolymer?

Ampd-Acrylates/Diacetoneacrylamide Copolymer is a large, mesh-like molecule made from linking two main building blocks: diacetoneacrylamide and a neutralized form of acrylic or methacrylic acid called aminomethyl propanediol (AMPD) salt. When these small units join together they create a flexible film that can sit on skin or hair.

The idea of using acrylic-based polymers in beauty care started in the 1960s when chemists searched for lightweight alternatives to natural gums. Over time they blended different monomers to get better hold, shine and durability. Adding diacetoneacrylamide made the film tougher while AMPD helped it stay water-friendly, which is why this specific copolymer gained popularity in styling products during the 1990s.

Manufacturing begins with liquid monomers placed in a reactor. Heat or light starts the reaction that links them into long chains. The finished polymer is filtered, dried into powder or kept as a thick gel, then shipped to formulators who blend it with water and other ingredients.

You will most often spot Ampd-Acrylates/Diacetoneacrylamide Copolymer in hair gels, mousses, styling sprays, pomades and edge tamers. It also shows up in some brow gels, waterproof mascaras and long-wear foundations where a thin, flexible film helps color stay put.

Ampd-Acrylates/Diacetoneacrylamide Copolymer’s Cosmetic Benefits/Uses

This ingredient pulls its weight in formulas by delivering the following actions:

  • Film forming: Creates an invisible layer that locks pigments and other actives in place, boosts water resistance and gives a smooth, even finish on skin or hair.
  • Hair fixing: Provides hold so hairstyles keep their shape, fights frizz and adds a light shine without making strands stiff or sticky.

Who Can Use Ampd-Acrylates/Diacetoneacrylamide Copolymer

This ingredient plays well with nearly every skin type. Its large molecule sits on the surface rather than soaking in, so even oily and acne-prone skins usually tolerate it without added congestion while dry or mature skins appreciate the flexible, non-tight film it forms. Highly sensitive complexions may notice a slight tight feel if the formula has a high polymer load, but outright irritation is rare.

Ampd-Acrylates/Diacetoneacrylamide Copolymer is fully synthetic and contains no animal-derived materials, making it suitable for vegans and vegetarians. It is also gluten-free and fragrance-free by nature, though finished products may add other components.

Because the polymer stays on top of skin and is not absorbed in meaningful amounts, it is generally viewed as safe for use during pregnancy and breastfeeding. That said, this information is not medical advice and anyone who is pregnant or nursing should run any new cosmetic product past a doctor to be safe.

The ingredient does not increase photosensitivity, so there is no special sun-care protocol beyond the usual daily sunscreen recommendation. It is also non-reactive with common actives like retinoids or acids, meaning it can be layered without worry.

Potential Side Effects/Adverse Reactions

Reactions to topical Ampd-Acrylates/Diacetoneacrylamide Copolymer differ from person to person. The issues listed below are only potential outcomes and are unlikely for most users when the ingredient is correctly formulated.

  • Mild skin redness or itching if the overall formula is drying or contains aggressive solvents
  • Contact dermatitis in individuals allergic to acrylic polymers
  • Eye irritation if styling sprays or mascaras are accidentally rubbed into the eyes
  • Flaking or dull buildup on hair with very frequent use or inadequate cleansing

If any of these effects occur stop using the product and seek advice from a healthcare professional

Comedogenic Rating

Rating: 1 / 5

Ampd-Acrylates/Diacetoneacrylamide Copolymer is a very large molecule that stays on the surface of skin rather than sliding into pores. It has no oily or waxy part of its own and is used at low levels, so it rarely traps sebum or dead cells the way heavier ingredients can. Because of that the risk of clogged pores is minimal but not absolutely zero, which is why it scores a cautious 1 instead of 0.

Those who are prone to acne or breakouts can generally use products containing this polymer without trouble.

Keep in mind overall formula matters; if the product also contains rich oils or butters the final pore-clogging potential could be higher, while light gels or sprays stay low.

Summary

Ampd-Acrylates/Diacetoneacrylamide Copolymer earns its spot in cosmetics as a film former and hair fixer. It strings together acrylic and diacetoneacrylamide units into a network that dries into a thin, flexible veil on skin or hair. That veil locks makeup pigments in place, boosts water resistance, tames frizz and sets styles without crunch.

You will mostly meet this polymer in hair gels, mousses and long wear makeup. It is not a trend ingredient splashed across ads every season, but formulators appreciate its dependable hold so it quietly shows up in many mainstream products.

Safety profiles rate it as low risk for irritation, allergy or pore blockage, and it is vegan friendly and non photo-sensitizing. As with any new cosmetic, patch test first to be extra safe then enjoy the hold and stay-put power it provides.

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