Bis-Hea/Ethylhexyl Poly(1,4-Butanediol)-11/Ipdi Copolymer: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: June 23, 2025
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All information on this page is verified using The Personal Care Products Council's (PCPC) INCI database. Our ingredient analyses are based exclusively on PCPC's technical data to ensure accuracy and reliability.

What Is Bis-Hea/Ethylhexyl Poly(1,4-Butanediol)-11/Ipdi Copolymer?

Bis-HEA/Ethylhexyl Poly(1,4-Butanediol)-11/IPDI Copolymer is a lab-made polymer created by linking together 1,4-butanediol units and isophorone diisocyanate, then finishing the chain with 2-hydroxyethyl acrylate and 2-ethylhexanol. The result is a long, flexible molecule that behaves like a soft, clear resin once dissolved in the oily or watery parts of a formula. Because it is synthesized entirely in controlled factory conditions, it does not come from plants or animals, which helps keep its quality and performance consistent from batch to batch.

Polyurethane-type polymers like this one first gained attention in the 1990s as chemists looked for ways to improve the feel and stability of cosmetics without relying on heavier waxes. Over time, refinements in processing allowed manufacturers to tailor the polymer’s chain length and side groups, giving formulators more control over texture. The current version is produced through step-growth polymerization: 1,4-butanediol reacts with isophorone diisocyanate to build the backbone, after which the ends are “capped” with hydroxyethyl acrylate and ethylhexanol to lock in the structure and add extra slip.

You are most likely to see Bis-HEA/Ethylhexyl Poly(1,4-Butanediol)-11/IPDI Copolymer in lightweight lotions, silicone-free primers, sheet-mask essences, anti-aging serums and sprayable sunscreens where a silky, slightly cushiony feel is desirable but a thick cream is not. It can also show up in cream foundations and long-wear eye products that need to stay even over time.

Bis-Hea/Ethylhexyl Poly(1,4-Butanediol)-11/Ipdi Copolymer’s Cosmetic Benefits/Uses

The main role of this ingredient is straightforward yet important within a formula.

Viscosity controlling: It helps thicken or thin a product to the ideal flow, so a serum glides without dripping and a cream feels plush but not greasy. By fine-tuning viscosity, the polymer also keeps pigments, UV filters and actives evenly suspended, which improves stability, appearance and overall performance of the finished product.

Who Can Use Bis-Hea/Ethylhexyl Poly(1,4-Butanediol)-11/Ipdi Copolymer

This polymer is considered friendly for most skin types including oily, dry, combination and sensitive because it sits on the surface, adjusts texture and has no active biological effect of its own. Very reactive or allergy-prone skin may want to monitor how it feels, as with any new ingredient, but the vast majority tolerate it well.

Because the material is fully synthetic and contains no animal-derived substances it is suitable for vegans and vegetarians.

No data link the ingredient to hormonal activity or fetal risk, so products containing it are generally viewed as safe during pregnancy or while breastfeeding. That said this is not medical advice and anyone who is pregnant or nursing should run all skincare choices past a qualified healthcare provider to be on the safe side.

Bis-HEA/Ethylhexyl Poly(1,4-Butanediol)-11/IPDI Copolymer does not increase photosensitivity, so it will not make skin more prone to sunburn.

The polymer is fragrance-free and usually hypoallergenic, which can be helpful for users avoiding common irritants.

Potential Side Effects/Adverse Reactions

Responses to topical Bis-HEA/Ethylhexyl Poly(1,4-Butanediol)-11/IPDI Copolymer can vary from person to person. The points below outline potential issues, though they are unlikely for most users when the ingredient is properly formulated.

  • Mild transient irritation or redness in very sensitive skin
  • Contact dermatitis in individuals allergic to polyurethane-type materials or residual isocyanate traces
  • Stinging or watery eyes if a spray or serum migrates into the ocular area
  • Occasional acne flare when used in heavy, oil-rich formulas on clog-prone skin
  • Rare allergic reaction to trace monomers or solvents left from manufacturing

If any of these reactions occur stop using the product and consult a healthcare professional.

Comedogenic Rating

Rating: 1 / 5

This polymer forms a breathable film that sits on top of the skin and contains no heavy oils or waxes, so it is very unlikely to clog pores. A small amount of slip agents or residual solvents in a finished formula could bump the risk up slightly, which is why it is not rated a perfect zero.

Suitable for acne-prone or breakout-prone skin in most cases.

Keep in mind that the overall comedogenicity of a product depends on the full ingredient list and not on this polymer alone.

Summary

Bis-HEA/Ethylhexyl Poly(1,4-Butanediol)-11/IPDI Copolymer is mainly a viscosity controller that keeps lotions, serums and sprays at just the right thickness so they glide on smoothly and hold actives evenly in suspension. Its long flexible chain creates a light film that improves spreadability and stability without adding weight.

You will see it more often in modern lightweight formulas than in classic creams, so its popularity is growing but it is still something of a niche helper rather than a headline ingredient.

Current data show it is low risk for irritation, allergy or pore clogging, making it safe for most users and all skin types. As with any new cosmetic ingredient it is smart to patch test a product before full use, especially if your skin is sensitive.

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