Bis-Hea Ppg-6 Glyceryl Ether/Smdi Copolymer: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: June 23, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Bis-Hea Ppg-6 Glyceryl Ether/Smdi Copolymer?

Bis-HEA PPG-6 Glyceryl Ether/SMDI Copolymer is a lab-made ingredient created by linking together PPG-6 glyceryl ether with a form of methylene diphenyl diisocyanate, then finishing the chain with 2-hydroxyethyl acrylate. The result is a large, flexible molecule that can adhere to other materials and hold them in place. The raw materials come from petrochemical or plant-derived propylene glycol and glycerin for the PPG-6 part, and industrial aromatic compounds for the diisocyanate portion. Chemists first explored this type of copolymer in the 1990s when formulators looked for lighter, more breathable film formers as alternatives to heavier resins. Production involves controlled polymerization in stainless steel reactors, followed by purification and testing to ensure a uniform molecular weight. You will most often spot this copolymer in long-wear foundations, mascaras, liquid lipsticks, spray primers, setting mists, hair styling creams and certain sheet mask essences where lasting adhesion is key.

Bis-Hea Ppg-6 Glyceryl Ether/Smdi Copolymer’s Cosmetic Benefits/Uses

This ingredient is prized for one main job in beauty formulas

Binding: It helps pigments, powders, oils and other actives stick together and stay evenly dispersed on skin or hair. By forming a lightweight, flexible film it boosts wear time, prevents color migration, reduces flaking and enhances water resistance without a heavy or sticky feel.

Who Can Use Bis-Hea Ppg-6 Glyceryl Ether/Smdi Copolymer

Because it forms a light breathable film rather than a heavy occlusive layer Bis-HEA PPG-6 Glyceryl Ether/SMDI Copolymer is generally well tolerated by all skin types including oily combination normal dry and even sensitive skin. Those with very acne-prone or reactive skin might want to monitor how their skin responds since any film former can in rare cases trap excess oil or exacerbate congestion.

The ingredient is made entirely from synthetic or plant-derived raw materials and contains no animal by-products so it is considered suitable for both vegans and vegetarians. As always double-check the finished formula for other non-vegan additives such as beeswax or carmine.

Current data show no special risks for pregnant or breastfeeding women when this copolymer is used topically. It is a large molecule that stays on the skin surface with minimal systemic absorption. This is not medical advice and expecting or nursing mothers should still review all products with their healthcare provider.

Bis-HEA PPG-6 Glyceryl Ether/SMDI Copolymer does not increase photosensitivity and will not make skin more prone to sunburn. Standard sun protection practices should still be followed.

Potential Side Effects/Adverse Reactions

Side effects and reactions to the topical application of Bis-HEA PPG-6 Glyceryl Ether/SMDI Copolymer can vary from person to person. The points below list potential issues only and most users will not experience them when the ingredient is properly formulated and used as directed.

  • Mild skin irritation – transient redness itching or dryness in very sensitive individuals
  • Contact dermatitis – rare allergic reaction to trace residual monomers or stabilizers in the finished product
  • Eye stinging – discomfort if a product containing the polymer accidentally gets into the eyes
  • Acne flare ups – possible worsening of breakouts in those extremely prone to clogged pores
  • Build up on hair shafts – dullness or heaviness after repeated use in hair products until clarified

If you experience any of these effects stop using the product and seek advice from a healthcare professional.

Comedogenic Rating

Rating: 1/5

Bis-HEA PPG-6 Glyceryl Ether/SMDI Copolymer sits on the skin surface, forms a breathable film and has no oily or waxy residues that typically clog pores. Its large molecular size limits the ability to seep into follicles, so the risk of blockage is low. Most finished formulas use it at modest levels which further reduces any chance of congestion.

Suitable for acne-prone or breakout-prone skin, though highly reactive individuals should still watch how their skin responds, especially if the product also contains richer emollients.

Keep in mind that heavy layering of multiple long-wear products containing this polymer could trap sebum and environmental debris over time, so thorough cleansing at the end of the day is important.

Summary

Bis-HEA PPG-6 Glyceryl Ether/SMDI Copolymer is mainly a binding agent. By creating a thin flexible film it keeps pigments, powders and actives evenly dispersed so makeup or hair products stay put, resist smudging and last longer without feeling heavy.

It is not the most famous ingredient on ingredient lists but formulators like it for long-wear foundations, mascaras and setting sprays where quiet workhorse performance matters more than buzz.

Current data show it is low irritation, non-sensitising and largely non-comedogenic. As with any new formula, do a quick patch test when you first try a product containing this copolymer to be sure your skin plays nicely with it.

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