Bis-(Phenoxyacryloyloxypropanol) Hdi: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: June 23, 2025
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All information on this page is verified using The Personal Care Products Council's (PCPC) INCI database. Our ingredient analyses are based exclusively on PCPC's technical data to ensure accuracy and reliability.

What Is Bis-(Phenoxyacryloyloxypropanol) Hdi?

Bis-(Phenoxyacryloyloxypropanol) Hdi is a lab made molecule created by linking 2-hydroxy-3-phenoxypropyl acrylate with 1,6-hexamethylene diisocyanate. The result is a sturdy, chain-like compound that helps other ingredients stick together once a product dries on the skin or hair. It has no plant or animal source and is produced entirely through controlled chemical reactions, which allows for steady quality from batch to batch.

The ingredient first showed up in nail coatings where a tough yet flexible film was needed. As formulating science moved forward, chemists noticed its binding power could improve wear time and texture in many leave-on products. Today it appears in a range of cosmetics, from long-lasting foundations to peel-off masks.

Manufacturing starts with purified monomers placed in a sealed reactor. Under heat and gentle stirring the acrylate groups join with the diisocyanate groups, forming the final polymer. Extra steps remove leftover reactants so the finished powder or viscous liquid is safe for skin contact.

You will most often spot Bis-(Phenoxyacryloyloxypropanol) Hdi in color cosmetics like nail polish, liquid lipstick and foundation. It also turns up in peel-off face masks, waterproof sunscreens, hair styling gels and certain high-shine topcoats where long wear and a smooth finish are key selling points.

Bis-(Phenoxyacryloyloxypropanol) Hdi’s Cosmetic Benefits/Uses

In formulas this ingredient serves one main purpose that brings several practical advantages.

As a binding agent it helps the other ingredients form a uniform film over skin, nails or hair. This improves adhesion so makeup or treatment products stay in place longer, resist smudging and feel smoother to the touch. It can also boost water and transfer resistance which is why it is popular in long-wear cosmetics.

Who Can Use Bis-(Phenoxyacryloyloxypropanol) Hdi

This binder is generally considered suitable for all skin types. Oily and combination skin often appreciate its lightweight film that keeps makeup in place without adding greasiness while dry skin benefits from the smooth finish it leaves behind. Most people with sensitive skin also tolerate it since it is non-reactive and used at low levels though anyone with a known acrylic allergy may want to steer clear.

Because the molecule is fully synthetic and contains no ingredients sourced from animals it is appropriate for vegans and vegetarians. Production does not involve animal testing in regions that follow cruelty-free regulations however policies can vary by country so checking the brand’s stance is wise if this is a priority.

Current data does not flag Bis-(Phenoxyacryloyloxypropanol) Hdi as a concern for women who are pregnant or breastfeeding. It remains on the skin surface and is unlikely to reach the bloodstream in meaningful amounts. This is not medical advice and anyone who is pregnant or nursing should review any new cosmetic product with a qualified healthcare provider to be safe.

The ingredient is not known to make skin more sensitive to sunlight so it will not raise your risk of sunburn. As always daily sunscreen is still recommended for overall skin health.

No other special usage limitations are noted beyond basic good-sense hygiene such as keeping containers closed and avoiding contact with broken skin.

Potential Side Effects/Adverse Reactions

Reactions to topical Bis-(Phenoxyacryloyloxypropanol) Hdi differ from person to person. The points below list potential side effects even though most users will not notice any problems when the ingredient is used correctly in a finished product.

  • Mild skin irritation such as redness or itching in people who have an acrylic sensitivity
  • Contact dermatitis presenting as small bumps or a rash usually after repeated exposure
  • Eye irritation if the wet product accidentally gets into the eyes before it sets
  • Respiratory discomfort from inhaling aerosol or dust during professional application of spray or powdered formulas

If irritation or any other unexpected reaction occurs stop using the product immediately and seek advice from a healthcare professional.

Comedogenic Rating

Rating: 0 / 5

Bis-(Phenoxyacryloyloxypropanol) Hdi is a large, inert polymer that stays on the skin surface and is used at low concentrations, giving it virtually no ability to block pores. It does not contain fatty acids or oils that typically raise comedogenicity, and it forms a breathable film that is removed with normal cleansing. For these reasons it earns a solid zero on the comedogenic scale.

Because it is non-comedogenic it is generally suitable for people who are prone to acne or frequent breakouts.

No additional concerns related to clogging pores have been noted in the available cosmetic safety literature.

Summary

Bis-(Phenoxyacryloyloxypropanol) Hdi is mainly a binder and film former. It links other ingredients together, creating a smooth, flexible coat that helps makeup, sunscreen and nail products stick better, last longer and resist water or smudging. Its synthetic origin lets manufacturers control purity and performance from batch to batch.

The ingredient enjoys steady but niche popularity, showing up most often in long-wear cosmetics rather than everyday lotions or cleansers. Brands focused on extended wear time appreciate the reliable hold it provides.

Current research and cosmetic use data classify it as low risk for irritation or sensitization for most users. While problems are rare, skin reactions can never be ruled out so it is always wise to patch test any new product that contains this binder before full application.

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