Bis-Stearyl Peg/Ppg-8/6 Smdi/Peg-400 Copolymer: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: June 23, 2025
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All information on this page is verified using The Personal Care Products Council's (PCPC) INCI database. Our ingredient analyses are based exclusively on PCPC's technical data to ensure accuracy and reliability.

What Is Bis-Stearyl Peg/Ppg-8/6 Smdi/Peg-400 Copolymer?

Bis-Stearyl Peg/Ppg-8/6 Smdi/Peg-400 Copolymer is a lab-crafted polymer that blends fatty alcohol chains sourced from stearic acid with short units of polyethylene glycol, polypropylene glycol and a diisocyanate linker. The result is a large, flexible molecule that behaves a bit like a liquid plastic, able to swell in oils or water and lend body to a formula. It entered the cosmetic scene in the early 2000s when formulators began searching for silicone-free ways to give creams and hair products a richer feel without leaving a heavy film. To make it, the individual building blocks are reacted under controlled heat and pressure so they join end-to-end, then the finished polymer is purified and dried into a soft wax or flake. You will usually spot this ingredient in moisturizers, sunscreens, cream cleansers, makeup primers, foundation, styling balms and rinse-off hair masks.

Bis-Stearyl Peg/Ppg-8/6 Smdi/Peg-400 Copolymer’s Cosmetic Benefits/Uses

This polymer’s main job in a formula is to control viscosity, meaning it tweaks how thick or runny the product feels. By dissolving or swelling at different rates in oils and water it can turn a watery lotion into a silky cream, keep a rich balm from melting in the jar, help pigments stay evenly suspended and stop a shampoo from pouring out too fast. The payoff for you is a product that spreads smoothly, stays stable over time and feels pleasantly cushiony on skin or hair.

Who Can Use Bis-Stearyl Peg/Ppg-8/6 Smdi/Peg-400 Copolymer

This polymer is considered skin friendly for most skin types, including dry, normal and combination. Oily or acne prone users usually tolerate it well too since it does not add noticeable grease, though extremely sensitive or reactive skin may prefer to avoid complex synthetic polymers in general because of their larger molecular size and the trace impurities that can linger after manufacturing.

The ingredient is manufactured from plant derived stearic acid and petrochemical based glycols, so no animal sourced materials are involved. That makes it acceptable for vegans and vegetarians.

Current safety data shows no reproductive toxicity, so products containing this polymer are generally viewed as safe for pregnant or breastfeeding women. This is not medical advice; anyone who is expecting or nursing should still confirm product choices with a healthcare professional.

Bis-Stearyl Peg/Ppg-8/6 Smdi/Peg-400 Copolymer is not known to cause photosensitivity and it does not interact with UV light. It is also fragrance free and carries no natural allergen markers like limonene or linalool, which further lowers its irritation risk.

Potential Side Effects/Adverse Reactions

Side effects from topical use of Bis-Stearyl Peg/Ppg-8/6 Smdi/Peg-400 Copolymer vary from person to person. The points below outline uncommon but possible reactions. When used in a properly formulated product most people notice no issues.

  • Mild skin irritation
  • Temporary redness on very sensitive skin
  • Eye stinging if the product accidentally gets into the eyes
  • Contact dermatitis in rare cases of polymer or glycol allergy

If any of these reactions occur discontinue use and seek medical advice if symptoms persist or worsen.

Comedogenic Rating

Rating: 1/5. Bis-Stearyl Peg/Ppg-8/6 Smdi/Peg-400 Copolymer is a bulky wax-like polymer that sits on the surface rather than soaking into pores and it contains no heavy oils that typically trigger clogs. While it can add a slight occlusive feel in richer formulas its large molecular size and balanced oil-to-water affinity mean it is very unlikely to block follicles.

Suitable for acne-prone or breakout-prone skin in most cases.

Formulas that pair this polymer with high levels of butters or waxes may feel heavier so overall product composition still matters.

Summary

Bis-Stearyl Peg/Ppg-8/6 Smdi/Peg-400 Copolymer is mainly used to control viscosity, giving lotions and creams a silky body that stays stable during shelf life. By swelling in both oil and water phases it thickens, suspends pigments and prevents separation so textures feel plush yet not greasy.

It is a niche but steadily growing ingredient found in modern silicone-free moisturizers, makeup primers and hair masks where formulators want a cushiony glide without using silicones.

Current safety assessments show it to be low risk for irritation, allergy or comedogenicity for most users. Still, whenever trying a new product containing this polymer it is wise to do a small patch test to be confident it agrees with your skin.

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