Bismaleate: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: June 23, 2025
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All information on this page is verified using The Personal Care Products Council's (PCPC) INCI database. Our ingredient analyses are based exclusively on PCPC's technical data to ensure accuracy and reliability.

What Is Bismaleate?

Bismaleate, also listed on ingredient labels as Bis-(1-Methylheptyl)-2-Butenedioate or Diisooctyl Maleate, is a lab crafted compound that belongs to the family of maleate esters. It forms when maleic acid is reacted with branched chain alcohols, creating a clear oily liquid with a light feel and low scent. First explored by the plastics industry for its flexibility boosting talents in the 1960s, chemists soon noticed that the same softening action could be useful in beauty formulas. Modern production relies on controlled esterification, a process that joins the acid and alcohol parts under heat then purifies the result so it meets cosmetic grade standards.

Today you can spot Bismaleate in a variety of leave-on and rinse-off products. It appears in hair masks, conditioners and styling creams where it helps strands feel smoother. It is also blended into lightweight facial oils, body lotions and certain color cosmetics to improve slip and spreadability.

Bismaleate’s Cosmetic Benefits/Uses

Formulators turn to Bismaleate because it brings several practical benefits to a product:

  • Hair conditioning: Forms a thin, flexible layer around each strand so hair feels softer, looks shinier and is easier to detangle
  • Plasticiser: Adds pliability to film-forming ingredients such as styling polymers and mascara bases preventing cracking or flaking through the day
  • Emollient: Provides a silk-like glide on skin reducing rough texture and improving overall comfort without a greasy afterfeel
  • Solvent: Helps dissolve fragrance oils, UV filters and other actives ensuring a smooth uniform mix that stays stable over time

Who Can Use Bismaleate

Bismaleate is generally considered suitable for all skin types. Its lightweight emollient nature means it will not leave a heavy residue on oily skin while still providing softness for dry or mature skin. Sensitive skin usually tolerates it well because it is free from common fragrance allergens and has a low likelihood of provoking stinging or redness. At present there are no known skin types that should actively avoid it, though anyone with a history of reacting to ester-based ingredients may wish to exercise extra caution.

The compound is produced synthetically from maleic acid and branched chain alcohols, neither of which come from animal sources. Because no animal-derived materials are required and it is compatible with cruelty-free production standards, products using Bismaleate can be formulated to meet vegan and vegetarian preferences. Always check the final product label to confirm that the entire formula meets your ethical needs.

Current safety assessments have not flagged Bismaleate as a hazard for pregnant or breastfeeding women when used topically in cosmetic concentrations. That said this information is educational only and not medical advice. Anyone who is expecting or nursing should run any skin or hair care product past their doctor to be on the safe side.

Bismaleate is not known to cause photosensitivity. It does not absorb UV light nor make skin more prone to sunburn so it can be worn during the day without extra sun-related precautions beyond your usual SPF.

Potential Side Effects/Adverse Reactions

Responses to topical Bismaleate depend on the individual. The issues listed below are uncommon but worth noting. Assuming the ingredient has been used correctly by the manufacturer most people will not experience any of these effects.

  • Mild skin irritation such as transient redness or itching, more likely on freshly shaved or broken skin
  • Contact dermatitis in those with a specific allergy to maleate esters or other formulation components
  • Eye irritation if a hair or skin product accidentally gets into the eyes
  • Scalp build-up or weighed-down hair when very high levels are used in leave-in styling products

If you notice persistent discomfort rash or swelling while using Bismaleate or a product containing it stop use immediately and consult a healthcare professional.

Comedogenic Rating

Rating: 1 / 5

Bismaleate is a lightweight ester with a quick-spreading feel that does not create a heavy occlusive film on skin. It sits on the surface just long enough to soften then evaporates or is washed away, leaving little residue to clog pores. There are no published reports linking it to acne flare-ups and its structure resembles other emollients ranked low on the comedogenic scale, which is why it earns a score of 1.

Most people prone to acne or breakouts should find Bismaleate acceptable in leave-on or rinse-off products, although overall formula design and personal skin sensitivity will always play a role.

The final pore-clogging potential of any product depends on the full ingredient mix, texture and how often it is applied so consider the whole formula rather than judging by a single component.

Summary

Bismaleate pulls double duty in cosmetics. As a hair conditioner and plasticiser it wraps strands in a flexible coating that boosts shine, softness and staying power in styling polymers. On skin it acts as a silky emollient, smoothing rough patches and helping lotions glide without greasiness. Its mild solvent ability also keeps fragrances UV filters and colorants evenly dispersed for a stable finished product.

While not a household name like jojoba oil or glycerin it has carved out a quiet niche in hair masks, lightweight facial oils and certain long-wear makeup where a non-sticky feel is prized. Formulators appreciate its versatility and low irritation profile so its presence has been growing slowly but steadily.

Current safety reviews show Bismaleate to be low risk for topical use with very rare reports of irritation or allergy. As with any new skin or hair care item do a small patch test before full application to make sure the complete formula agrees with you.

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