Brassicyl Valinate Esylate: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: June 23, 2025
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All information on this page is verified using publicly available nomenclature standards and reference materials from The Personal Care Products Council (PCPC) and the European Commission's CosIng database. Our analyses are based on technical data from these sources to ensure accuracy and reliability.

What Is Brassicyl Valinate Esylate?

Brassicyl Valinate Esylate is a plant-derived ingredient created by joining L-valine, an amino acid, with long-chain fatty alcohols that come from brassica oilseeds such as rapeseed. The result is then paired with ethanesulfonic acid to form a gentle salt. This combination gives the molecule both water-loving and oil-loving parts, letting it sit comfortably at the point where oil and water meet.

The ingredient was first explored in the early 2010s when formulators looked for greener alternatives to silicone-based conditioners. By tapping into renewable brassica crops and amino acids, chemists crafted an efficient yet biodegradable compound that soon found favor in eco-focused skin and hair care lines.

Production starts with fermenting sugars to obtain L-valine. Separately, brassica fatty alcohols are made by refining and hydrogenating natural seed oils. These two pieces are esterified together, then neutralized with ethanesulfonic acid. The final powder or liquid is filtered and dried to cosmetic-grade purity.

You will usually see Brassicyl Valinate Esylate in lightweight moisturizers, leave-in hair conditioners, curl creams, anti-aging serums and sheet masks. Because it can stabilize emulsions while softening skin and hair, it is popular in both rinse-off and leave-on formulas intended for daily use.

Brassicyl Valinate Esylate’s Cosmetic Benefits/Uses

This multitasking ingredient earns its spot on an ingredient list by offering several practical benefits:

  • Emulsion stabilising – helps oil and water stay blended so lotions do not separate, giving products a smooth consistent feel from the first pump to the last
  • Hair conditioning – deposits a light film on strands that boosts softness, reduces static and makes detangling easier without weighing hair down
  • Skin conditioning – leaves a silky finish on the skin surface improving suppleness and short-term hydration
  • Emollient – adds slip and cushions the formula so it glides on effortlessly and leaves a non-greasy softness

Who Can Use Brassicyl Valinate Esylate

Thanks to its balanced oil-and-water nature, Brassicyl Valinate Esylate is generally suitable for all skin types including dry, normal, combination and oily. Its lightweight emollient feel means it rarely clogs pores on oily or acne-prone skin while still delivering softness to dry complexions. Sensitive skin also tends to tolerate the ingredient because it is free of common irritants like fragrances or essential oils.

The compound is produced entirely from plant sources (brassica seed oils, fermented sugars and mineral-derived ethanesulfonic acid) with no animal derivatives or by-products, making it appropriate for vegans and vegetarians.

Current data does not flag any issues for women who are pregnant or breastfeeding when products containing Brassicyl Valinate Esylate are used as directed. This is not medical advice and anyone who is pregnant or nursing should consult a healthcare professional before introducing new skincare or haircare products.

The ingredient does not absorb UV light or trigger increased sun sensitivity, so it is not considered photosensitising. It also plays well with most other cosmetic ingredients, including acids, retinoids and sunscreens.

Potential Side Effects/Adverse Reactions

Side effects from topical use of Brassicyl Valinate Esylate vary between individuals. The points below list potential reactions yet most consumers will not encounter them when the ingredient is properly formulated and used as intended.

  • Mild skin irritation such as transient redness or itching in very sensitive users
  • Allergic contact dermatitis in those already allergic to brassica-derived compounds
  • Eye irritation if the product accidentally enters the eyes
  • Build-up or slight limpness on extremely fine hair when used in high-concentration leave-in conditioners

If any of these reactions occur discontinue use immediately and seek advice from a qualified healthcare professional.

Comedogenic Rating

Rating: 1 out of 5

Brassicyl Valinate Esylate is largely non-occlusive and has a balanced water-loving and oil-loving structure that tends to sit on the surface without blocking pores. It is also used at modest levels, typically under 3 percent, which further limits its ability to trap sebum or dead skin cells. For these reasons it earns a low score of 1.

That makes it generally suitable for people who are prone to acne or breakouts.

Because the ingredient is usually paired with lightweight oils or water-based formulas and is sometimes rinsed off in hair products, the real-world risk of pore congestion is minimal.

Summary

Brassicyl Valinate Esylate works as an emulsion stabiliser, hair conditioner, skin conditioner and emollient. Its amino acid half attracts water while its brassica-derived fatty chain mingles with oils, letting it hold oil and water together in a stable blend. On skin and hair the molecule lays down an invisible film that smooths texture, adds softness and reduces moisture loss without a greasy feel.

The ingredient enjoys growing popularity in eco friendly lines that want silicone-like slip from plant sources, though it is still less common than long-established emollients such as caprylic/capric triglyceride.

Safety data show a low rate of irritation or sensitisation so most users tolerate it well. As with any new cosmetic, perform a small patch test when first trying products that contain Brassicyl Valinate Esylate to confirm personal compatibility.

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