Broccoli Seed Oil Polyglyceryl-4 Esters: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: June 23, 2025
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All information on this page is verified using The Personal Care Products Council's (PCPC) INCI database. Our ingredient analyses are based exclusively on PCPC's technical data to ensure accuracy and reliability.

What Is Broccoli Seed Oil Polyglyceryl-4 Esters?

Broccoli Seed Oil Polyglyceryl-4 Esters comes from the seeds of Brassica oleracea italica, the same plant that gives us broccoli. Chemically it combines the nourishing fatty acids of broccoli seed oil with polyglycerin-4, a plant-derived chain of glycerin units. By linking the two through a process called transesterification, chemists create a new ingredient that carries the lightweight feel of broccoli seed oil and the water-loving nature of polyglycerin-4.

The idea of joining natural oils with polyglycerins grew in popularity in the early 2000s as formulators looked for eco-friendly alternatives to petrochemical emulsifiers. Broccoli seed oil stood out because its fatty acid profile is rich in erucic acid, giving a silky slip similar to silicone. When this oil is bonded to polyglycerin-4 it becomes easier to blend into water-based creams without extra surfactants.

Production starts by pressing broccoli seeds to obtain the pure oil. Separately glycerin molecules undergo a vegetable-based reaction to form polyglycerin-4. The two parts are then heated together with a mild catalyst, swapping parts of their structures until stable esters form. After purification the finished ingredient appears as a soft paste or liquid.

You will most often see Broccoli Seed Oil Polyglyceryl-4 Esters in moisturizers, light facial oils, leave-on hair masks, anti-aging serums, cleansing balms and makeup removers. Its dual oil-and-water affinity lets brands create creamy textures without synthetic emulsifiers.

Broccoli Seed Oil Polyglyceryl-4 Esters’s Cosmetic Benefits/Uses

This multitasking ingredient lends several helpful properties to beauty formulas

  • Emollient: Forms a thin, breathable layer on skin or hair that smooths rough spots, reduces moisture loss and leaves a soft, silky finish comparable to lightweight silicone
  • Cleansing: Loosens makeup and excess sebum while its oil-compatible part binds to grime and the polyglycerin part helps rinse it away without stripping natural moisture
  • Emulsifying: Bridges oil and water phases so creams stay stable, improving texture, spreadability and shelf life while allowing higher levels of natural oils in the formula

Who Can Use Broccoli Seed Oil Polyglyceryl-4 Esters

This ingredient suits most skin types including normal, dry, mature and even sensitive skin thanks to its lightweight texture and soothing fatty acids. Oily or acne-prone users generally tolerate it well because the polyglyceryl part keeps the oil from feeling heavy, though extremely blemish-prone skin may prefer to patch test products that feature high levels of it.

Because both broccoli seed oil and polyglycerin-4 come from plant sources it is suitable for vegans and vegetarians. No animal-derived materials are used in the creation or processing of the ingredient.

Current research finds no evidence that topical Broccoli Seed Oil Polyglyceryl-4 Esters poses a risk to women who are pregnant or breastfeeding. This statement is not medical advice and anyone expecting or nursing should confirm any skincare choice with a medical professional to be safe.

The ingredient does not make skin more sensitive to the sun so it is considered non-photosensitizing. It is also fragrance free and contains no known endocrine disruptors.

Potential Side Effects/Adverse Reactions

Reactions to Broccoli Seed Oil Polyglyceryl-4 Esters can vary from person to person. The points below list potential side effects, though most users will not experience them when the ingredient is used correctly in a finished product.

  • Mild redness or stinging in very sensitive skin
  • Allergic contact dermatitis in individuals allergic to Brassica family plants
  • Temporary clogged pores if applied in heavy layers on highly acne-prone skin
  • Eye irritation if the pure ingredient accidentally contacts the eyes before dilution in a finished formula

If you notice any of these issues stop using the product and consult a healthcare professional if symptoms persist.

Comedogenic Rating

Rating: 1 / 5

The erucic-rich broccoli seed portion has a naturally low pore-clogging profile and the attached polyglyceryl chain thins the texture and improves rinse-off, further lowering buildup risk. Because of this balanced structure the ester sits lightly on skin instead of solidifying inside follicles.

Most acne-prone users should find it suitable for daily use.

Real-world pore clogging also depends on the other ingredients in the formula and how heavily the product is layered.

Summary

Broccoli Seed Oil Polyglyceryl-4 Esters delivers three core benefits: it cushions skin as a silky emollient, lifts grime as a gentle cleansing agent and marries water with oils as a plant-based emulsifier. The oil side loves lipids while the polyglycerin side bonds with water so the molecule performs double duty wherever it is added.

Although big brands have not adopted it widely yet, it is popping up more often in niche moisturizers, cleansing balms and hair masks that spotlight eco credentials and a silicone-free feel.

Regulatory reviews rate it as safe for leave-on and rinse-off products with very low irritation potential. Still, try a small patch first to be extra sure your skin stays happy.

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