Butyl Acrylate/Ethylhexyl Methacrylate Copolymer: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: June 23, 2025
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All information on this page is verified using publicly available nomenclature standards and reference materials from The Personal Care Products Council (PCPC) and the European Commission's CosIng database. Our analyses are based on technical data from these sources to ensure accuracy and reliability.

What Is Butyl Acrylate/Ethylhexyl Methacrylate Copolymer?

Butyl Acrylate/Ethylhexyl Methacrylate Copolymer is a man-made polymer created by linking together two small building blocks: butyl acrylate and ethylhexyl methacrylate. Both of these starting materials belong to the acrylic family, known for forming flexible, clear films once they set. The copolymer was first explored in the late 1970s when chemists searched for lightweight alternatives to heavy hair-setting resins of that era. Today it is produced through a controlled process called free-radical polymerization, where the two monomers are mixed, heated and reacted in the presence of an initiator until they fuse into long repeating chains. Manufacturers can tweak temperature, time and the ratio of each monomer to fine-tune the final texture and hold strength.

This ingredient appears in a wide range of personal-care products. It is common in hair sprays, styling gels, mousses, brow setters and mascaras because it forms a flexible film that locks styles in place without making strands feel stiff or crunchy. Skin care formulators also use it in peel-off masks and certain long-wear makeup products such as liquid foundations and eyeliners, where its film helps the product stay put, resist water and maintain a smooth finish throughout the day.

Butyl Acrylate/Ethylhexyl Methacrylate Copolymer’s Cosmetic Benefits/Uses

This copolymer brings two main benefits to beauty formulas

  • Film Forming – Once the product dries the polymer creates a thin flexible layer over hair or skin. This film improves water resistance, boosts shine, helps pigments stay even and prevents smudging so makeup and hair styles last longer
  • Hair Fixing – In styling products the film provides light to medium hold that keeps hair in place yet allows natural movement. It helps tame frizz, maintain curls or add structure to updos without weighing hair down

Who Can Use Butyl Acrylate/Ethylhexyl Methacrylate Copolymer

This polymer is considered friendly for most skin and hair types, including oily, dry and combination skin. It sits on the surface forming a breathable film and is not known to clog pores, so acne-prone users usually tolerate it well. Those with very sensitive or allergy-prone skin should still review the full formula because other ingredients, fragrances or preservatives may be the real irritants.

The material is synthetic and made entirely from petrochemical feedstocks, not animal-derived sources, so products that rely on it are generally suitable for vegans and vegetarians. As always, check for animal-based waxes or colorants elsewhere in the ingredient list if strict plant-based standards are important to you.

Current safety data show no specific risks for women who are pregnant or breastfeeding when the ingredient is used topically in cosmetics. That said this is not medical advice and anyone who is expecting or nursing should run any skincare or haircare products past a qualified healthcare professional just to be on the safe side.

Unlike some acids or retinoids the copolymer does not make skin more sensitive to sunlight, so added sun protection is not needed solely because it is present. Normal daily sunscreen habits are still encouraged for overall skin health.

Potential Side Effects/Adverse Reactions

Reactions to topical Butyl Acrylate/Ethylhexyl Methacrylate Copolymer vary from person to person. The points below outline potential side effects only. When the ingredient is used at appropriate levels most people will not notice any problems.

  • Mild skin redness or irritation in very sensitive individuals
  • Transient itching or stinging where the product is applied
  • Rare allergic contact dermatitis if a person has a specific acrylic allergy
  • Flaking or buildup on hair with heavy use or inadequate cleansing

If any of these issues occur stop using the product and consult a healthcare professional or dermatologist for guidance.

Comedogenic Rating

Comedogenic rating: 1 out of 5

The molecule is large and stays on the surface so it is unlikely to lodge inside pores. It lacks heavy oils or waxes that normally spark congestion and any residual monomers are present at trace levels set by safety guidelines.

This low score means it is generally fine for acne-prone or breakout-prone skin.

Very thick layering combined with poor cleansing could trap sweat and grime under the film so washing it off at day’s end is still wise.

Summary

Butyl Acrylate/Ethylhexyl Methacrylate Copolymer works as a film former and hair fixative, drying into a flexible layer that locks in pigment, shine and style. Interlinked polymer chains give makeup staying power and hair products light to medium hold without crunch.

It is not a headline ingredient yet you will spot it in many sprays, gels, mascaras and long-wear foundations because it delivers reliable performance at a friendly cost.

Overall safety data are solid with low risk of irritation or pore issues when used as intended. Still, skin can be unpredictable so it is smart to patch test any new product containing this copolymer before full use.

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