Butyl Methacrylate/Acryloyloxy Pg Methacrylate Copolymer: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: June 23, 2025
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All information on this page is verified using The Personal Care Products Council's (PCPC) INCI database. Our ingredient analyses are based exclusively on PCPC's technical data to ensure accuracy and reliability.

What Is Butyl Methacrylate/Acryloyloxy Pg Methacrylate Copolymer?

Butyl Methacrylate/Acryloyloxy Pg Methacrylate Copolymer is a man-made polymer created by linking two small building blocks: butyl methacrylate and acryloyloxy propyl methacrylate. Chemists start with liquid monomers, mix them with a tiny amount of peroxide-based starter, then allow the mixture to harden into long repeating chains. The result is a clear, flexible film-forming powder or fluid that blends easily with many cosmetic bases.

This type of acrylic chemistry has been around since the middle of the twentieth century when laboratories looked for lightweight alternatives to natural resins. As makeup trends moved toward longer wear and water resistance, formulators turned to these polymers for their strong yet comfortable finish. Over the years suppliers refined the process to remove residual monomers, making the ingredient milder and ready for everyday beauty products.

Today you will find Butyl Methacrylate/Acryloyloxy Pg Methacrylate Copolymer in a wide range of items: long-lasting foundations, smudge-proof mascaras, liquid eyeliners, transfer-resistant lip colors, setting sprays, peel-off face masks and certain hair-styling gels. Its ability to form a thin breathable layer on skin or hair makes it especially useful in products that promise durability without a heavy feel.

Butyl Methacrylate/Acryloyloxy Pg Methacrylate Copolymer’s Cosmetic Benefits/Uses

In beauty formulas this ingredient serves one key purpose that delivers several practical perks.

Film forming: Once the product dries the polymer creates a smooth invisible film that locks pigments in place resists sweat and humidity reduces flaking and helps active ingredients stay on the skin or hair longer. The film flexes with facial movement so makeup looks fresh and comfortable throughout the day while also adding a light glossy finish if desired.

Who Can Use Butyl Methacrylate/Acryloyloxy Pg Methacrylate Copolymer

This film former is generally well tolerated by all skin types including oily dry combination and normal because it sets as a lightweight breathable layer rather than an occlusive seal. People with very sensitive or reactive skin should still pay attention to how their skin feels since acrylic polymers can occasionally trigger redness or itch in that group.

Because the ingredient is fully synthetic and contains no animal by-products it fits the needs of vegans and vegetarians. Its production relies on petrochemical feedstocks not animal sources.

No published data link the polymer to problems during pregnancy or breastfeeding. It is not known to penetrate deeply or reach the bloodstream in meaningful amounts but this is not medical advice and anyone who is pregnant or nursing should run every skincare or makeup item past a doctor just to be on the safe side.

The ingredient does not make skin more sensitive to sunlight so extra sun precautions beyond daily SPF are not required solely because of its presence. It can however be paired with sunscreens without affecting their performance.

Potential Side Effects/Adverse Reactions

Responses to topical Butyl Methacrylate/Acryloyloxy Pg Methacrylate Copolymer vary from person to person. The effects listed below are only potential issues and are unlikely for most users when the ingredient is formulated and used correctly.

  • Mild skin irritation such as temporary redness itching or a slight burning sensation
  • Eye stinging or watering if a product containing the polymer accidentally gets into the eyes
  • Contact allergy manifested by swelling redness or small bumps in individuals already sensitized to acrylic compounds
  • Build up on hair shaft leading to dullness or product residue when used in styling gels without regular cleansing
  • Acne flare ups in rare cases where heavy multi-layered makeup traps oil and debris

If you experience any negative reaction discontinue use and consult a healthcare professional or dermatologist for guidance.

Comedogenic Rating

Rating: 1/5

This acrylic polymer sits on top of the skin as a breathable film and its large molecular size keeps it from slipping into pores, so it earns a very low score. While the film can trap oil if layered with heavy makeup or not removed properly, the ingredient itself does not clog pores in standard leave-on concentrations.

Overall it is considered suitable for acne-prone or breakout-prone skin, provided normal cleansing habits are followed.

If you use multiple long-wear products containing similar film formers, periodic deep cleansing can help prevent any surface buildup.

Summary

Butyl Methacrylate/Acryloyloxy Pg Methacrylate Copolymer is a versatile film former that locks color in place resists moisture and extends wear time without creating a stiff or heavy feel. It does this by drying into a flexible mesh that hugs pigments and active ingredients yet allows skin or hair to move naturally.

You will mainly see it in long-lasting foundations, mascaras, eyeliners, liquid lipsticks, setting sprays and some peel-off masks. While not a household name it is a behind-the-scenes favorite among formulators who need staying power and a smooth finish.

Safety profiles show it is generally gentle, vegan friendly and unlikely to clog pores. As with any new cosmetic ingredient it is wise to patch test a fresh product to be sure your skin agrees with the full formula.

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