C12-17 Alkyl Ketene Dimer: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: June 24, 2025
Share:
Inside this article:

All information on this page is verified using publicly available nomenclature standards and reference materials from The Personal Care Products Council (PCPC) and the European Commission's CosIng database. Our analyses are based on technical data from these sources to ensure accuracy and reliability.

What Is C12-17 Alkyl Ketene Dimer?

C12-17 Alkyl Ketene Dimer is a wax-like compound made from long chain fatty acids that usually come from animal tallow or plant oils. Chemists hydrogenate these fatty acids to make them more stable then link two of the chains together in a ring-forming step that creates a “dimer.” The result is a molecule with both oily and reactive parts, which makes it good at clinging to hair or skin and changing surface feel.

The ingredient first showed up in the paper industry in the 1950s because it helped paper repel water. Formulators later noticed that the same water-resisting film could smooth hair fibers and lock moisture into skin. By the early 2000s specialty raw-material suppliers had refined the grade to meet cosmetic purity standards and it started appearing in personal care launches.

Today C12-17 Alkyl Ketene Dimer is most common in rinse-off and leave-on hair conditioners, styling creams, anti-frizz serums, waxes and pomades. Skin care brands use it in moisturizers, primers, sunscreens and color cosmetics where a silky feel and longer wear are important.

C12-17 Alkyl Ketene Dimer’s Cosmetic Benefits/Uses

Formulators reach for this ingredient because it offers several useful roles in one easy-to-handle powder or pellet.

  • Hair conditioning: Coats the hair shaft to smooth rough cuticles, which boosts softness, shine and manageability while helping reduce breakage during combing
  • Hair fixing: Adds light hold so styles keep their shape, yet stays flexible and touchable rather than stiff or crunchy
  • Skin conditioning: Forms a thin occlusive film that slows water loss, leaving skin feeling supple and protected against environmental drying
  • Surface modifier: Improves spreadability and slip in creams and sticks, helps pigments lay down evenly, enhances water resistance and can fine-tune a product’s final texture from glossy to velvety

Who Can Use C12-17 Alkyl Ketene Dimer

This waxy film former works for most skin types, especially normal and dry skin that benefits from extra moisture sealing. Oily or acne-prone complexions may find it a bit heavy if used in high amounts because the coating layer can trap sebum and sweat. On hair it suits straight, wavy and curly textures that need frizz control or light hold.

Traditional grades start with animal tallow so strict vegans and many vegetarians may wish to avoid it. Some suppliers now offer plant-based versions made from coconut or palm fatty acids so checking a brand’s sourcing claim is key for plant-only users.

No studies show the ingredient entering the bloodstream in meaningful amounts so it is generally viewed as safe for people who are pregnant or breastfeeding. This is not medical advice and expectant or nursing parents should still clear any new product with their doctor to be safe.

C12-17 Alkyl Ketene Dimer is not known to cause photosensitivity and has no reported issues with sun exposure.

Potential Side Effects/Adverse Reactions

Reactions to topical C12-17 Alkyl Ketene Dimer differ from person to person. The effects listed below are only potential outcomes and most users will not notice any problems when the ingredient is used at normal cosmetic levels.

  • Clogged pores or acne flare-ups in very oily skin when the formula is rich in the dimer
  • Mild scalp buildup or greasiness if a heavy hair product is not washed out fully
  • Rare allergic contact dermatitis marked by redness itching or small bumps
  • Folliculitis on body areas where thick occlusive films trap sweat and bacteria
  • Minor eye irritation if raw powder becomes airborne during DIY handling

If any irritation or unusual reaction occurs stop using the product and seek advice from a healthcare professional.

Comedogenic Rating

Rating: 2 / 5

C12-17 Alkyl Ketene Dimer sits in the low-to-moderate range because its large waxy molecules stay on the surface rather than sinking deeply into pores yet the occlusive film can trap existing oil and debris if skin is already very oily. Most people will not break out at typical use levels but those who are highly acne-prone may notice congestion when the ingredient appears high on an ingredient list or in rich balms.

Suitable for acne-prone users in lightweight formulas, best avoided in heavy creams or thick pomades if breakouts are a recurring issue. High rinse-off formulas like conditioners present even lower risk.

Formulas combining this dimer with high percentages of other waxes or butter-type emollients can raise the effective comedogenicity, so texture matters as much as the ingredient itself.

Summary

C12-17 Alkyl Ketene Dimer conditions hair, offers light style hold, seals moisture on skin and tweaks the surface feel of creams and sticks. It does this by forming a thin uniform film that smooths cuticles, locks in water and improves slip and water resistance.

The ingredient is a quiet workhorse rather than a headline act, appearing in specialty hair products, some long-wear cosmetics and a handful of moisturizers but not in every drugstore aisle.

Safety reviews and practical use show it is well tolerated for most skin and hair types with only rare allergy or pore-clogging concerns. As with any new cosmetic it is smart to patch test first so you can see how your own skin reacts before committing to full use.

Was this article helpful?
More from Glooshi:
ADVERTISEMENT
Get all our top headlines in beauty.
Delivered right to your inbox each week. Zero spam, all goodness, opt-out at anytime.
This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.
Get the latest beauty news, top product recommendations & brand-exclusive discount codes direct to your inbox.
Send good feedback:

All feedback is greatly appreciated, anonymous, and will be used to improve the quality of our articles.

This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.
Send bad feedback:

All feedback is greatly appreciated, anonymous, and will be used to improve the quality of our articles.

This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.
Search