C5-6 Alkane/Cycloalkane/Terpene Copolymer: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: June 24, 2025
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All information on this page is verified using publicly available nomenclature standards and reference materials from The Personal Care Products Council (PCPC) and the European Commission's CosIng database. Our analyses are based on technical data from these sources to ensure accuracy and reliability.

What Is C5-6 Alkane/Cycloalkane/Terpene Copolymer?

C5-6 Alkane/Cycloalkane/Terpene Copolymer is a man-made blend created by joining small hydrocarbon units from light petroleum cuts (C5-C6 alkanes and cycloalkanes) with terpene molecules that come from natural plant resins such as pine. Through a controlled chemical reaction called polymerization these pieces link together to form a flexible film-forming resin. The beauty industry began exploring these lightweight resins decades ago when the need for longer-lasting makeup and waterproof hair products grew. Over time refinements in purification and processing have made the copolymer clear odor-free and safe for skin contact.

To produce it manufacturers first isolate the C5-C6 fractions from petroleum refining and collect terpene feedstock from plant sources. After cleaning and filtering the raw materials they are blended in a reactor where heat and a catalyst trigger polymerization. Once the desired chain length is reached the mixture is cooled purified and milled into a smooth resin or liquid concentrate ready for use in cosmetic formulas.

You will most often spot C5-6 Alkane/Cycloalkane/Terpene Copolymer in long-wear foundations, waterproof mascaras, transfer-resistant lip colors, peel-off masks, sunscreens that claim better water resistance, setting sprays and hair gels or pomades that need extra hold.

C5-6 Alkane/Cycloalkane/Terpene Copolymer’s Cosmetic Benefits/Uses

This ingredient is prized for a single main role that makes many everyday products perform better.

As a film forming agent it creates an invisible flexible layer on skin hair or lashes. This thin film locks pigments in place, boosts water resistance, reduces smudging and helps active ingredients stay where they are applied for longer. The result is makeup that lasts through heat and humidity, sunscreens that cling during swimming, peel-off masks that remove neatly and hairstyling products that keep strands in shape without a stiff feel.

Who Can Use C5-6 Alkane/Cycloalkane/Terpene Copolymer

This lightweight film former is generally compatible with all skin types including dry, normal, combination and oily skin because it sits on the surface rather than sinking deep into pores. Those with very congestion-prone or sensitive skin might want to keep an eye on how their skin responds since any occlusive film can occasionally trap oil or sweat and trigger blemishes or redness in reactive individuals.

The copolymer is made from petroleum-derived hydrocarbons and plant terpenes, with no animal ingredients or by-products, so it is considered suitable for vegans and vegetarians as long as the rest of the formula aligns with their preferences.

No evidence links topical use of this ingredient to issues during pregnancy or breastfeeding. It is not absorbed in meaningful amounts and is regarded as chemically inert. This is not medical advice; anyone who is pregnant or nursing should review all skincare products with a healthcare professional to be sure they meet personal safety needs.

The copolymer does not make skin more sensitive to sunlight and has no known interactions with UV exposure. It also plays well with common actives like retinoids, vitamin C or acids, making it a flexible addition to most routines.

Potential Side Effects/Adverse Reactions

Reactions to C5-6 Alkane/Cycloalkane/Terpene Copolymer vary from person to person. The points below cover potential issues; most users will never experience them when the ingredient is used correctly in a well-formulated product.

  • Mild skin irritation – rare stinging or redness, usually in highly sensitive or compromised skin
  • Allergic contact dermatitis – uncommon rash or itching in people allergic to resin-type materials
  • Clogged pores or breakouts – possible in very oil-prone skin if heavy layers build up with other occlusives
  • Eye irritation – watery or itchy eyes if the ingredient flakes into the eye area from mascara or liner
  • Respiratory discomfort – slight throat or lung irritation when inhaled from aerosol hairsprays containing the copolymer

If any irritation, rash or other discomfort develops while using a product that contains this ingredient discontinue use and consult a healthcare professional if symptoms persist.

Comedogenic Rating

On the standard 0–5 scale C5-6 Alkane/Cycloalkane/Terpene Copolymer scores a 1. Its molecules are large and stay on the surface rather than slipping into pores so they rarely trigger true blockages. That said the thin film it leaves can trap existing oil and debris if layered with heavy creams or worn in hot humid conditions which is why it is not given a perfect zero. Overall this ingredient is usually fine for people who are prone to acne or breakouts, especially when used in lightweight formulas. Individual results still vary because the rest of the product and a person’s own oil production matter. One last point: most published comedogenic ratings are based on raw ingredients tested in isolation so finished products may perform better or worse depending on the full recipe.

Summary

C5-6 Alkane/Cycloalkane/Terpene Copolymer works as a film former, meaning it dries down into a clear flexible layer that anchors pigments, actives and styling agents where you put them. That film resists sweat, water and friction so makeup stays put, sunscreens cling longer during swimming and hair products keep a tidy hold without feeling crunchy. Because long wear and waterproof claims are big selling points, especially in color cosmetics, this copolymer shows up in a wide range of foundations, mascaras, lip colors and setting sprays, though it is still less talked about than older film formers like acrylates or PVP.

Safety studies and real-world use both point to a low irritation risk, negligible absorption and no phototoxicity, so most people can use it with confidence. As with any new product it is smart to perform a quick patch test to be sure your skin agrees with the full formula.

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