Caprylic/Capric Triglyceride Peg-4 Esters: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: June 24, 2025
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All information on this page is verified using The Personal Care Products Council's (PCPC) INCI database. Our ingredient analyses are based exclusively on PCPC's technical data to ensure accuracy and reliability.

What Is Caprylic/Capric Triglyceride Peg-4 Esters?

Caprylic/Capric Triglyceride Peg-4 Esters is a plant-derived ingredient made by joining medium chain triglycerides from coconut or palm kernel oil with a small amount of polyethylene glycol. The result is a lightweight molecule that mixes the softening feel of natural oils with the water-friendly nature of a mild surfactant. First explored in the late 1970s as chemists searched for gentler cleansers, it has since become a go-to helper in modern skin care because it does several jobs at once while feeling silky on the skin.

The process starts by splitting the original vegetable oil into caprylic and capric fatty acids, then reacting them with glycerin to rebuild a stable triglyceride. This oil is next combined with four units of ethylene oxide, giving the final ester its “Peg-4” tag and the ability to blend with water. The finished ingredient is a clear nearly odorless liquid.

You will spot Caprylic/Capric Triglyceride Peg-4 Esters in a wide range of products such as facial cleansers, micellar waters, makeup removers, lightweight moisturizers, sheet masks, baby washes and even some anti-aging serums where a non-greasy feel is key.

Caprylic/Capric Triglyceride Peg-4 Esters’s Cosmetic Benefits/Uses

This versatile ester earns its place on ingredient lists because it brings several perks at once

  • Skin Conditioning: Leaves skin feeling soft smooth and supple thanks to the cushioning effect of its fatty acid base
  • Emollient: Forms a light protective layer that helps reduce water loss without a heavy or sticky afterfeel making formulas more elegant
  • Cleansing: Loosens makeup dirt and excess oil then lifts them away when rinsed helping create gentle yet effective cleansers
  • Emulsifying: Helps oil and water stay blended improving the stability texture and shelf life of creams lotions gels and sprays

Who Can Use Caprylic/Capric Triglyceride Peg-4 Esters

This ingredient is gentle enough for nearly all skin types. Its light texture makes it a good match for oily and combination skin while the softening fatty acids offer comfort to dry or mature skin. Sensitive skin usually tolerates it well because it is non-fragrant and low in known irritants. Those with very acne-prone skin may want to keep an eye on how their complexion responds since any oil-derived material can occasionally contribute to clogged pores, though this ester is generally considered low risk in that regard.

Caprylic/Capric Triglyceride Peg-4 Esters comes from coconut or palm kernel oil and the polyethylene glycol used in production is petroleum-based rather than animal-derived, so products featuring it are typically suitable for both vegans and vegetarians. Always check the full ingredient list for other additives if you follow a strict plant-only routine.

No specific warnings exist for women who are pregnant or breastfeeding; the ingredient is widely viewed as safe for topical use. This is not medical advice and anyone who is expecting or nursing should run any skincare routine past a qualified healthcare provider to be on the safe side.

The ester does not increase photosensitivity and can be used day or night without raising the skin’s sensitivity to sunlight. It also plays well with most other common skincare ingredients so formulating conflicts are rare.

Potential Side Effects/Adverse Reactions

Reactions can vary from person to person. The issues below are possible but unlikely for most users when the ingredient is properly formulated and used as directed.

  • Mild irritation or redness
  • Temporary stinging on broken or highly sensitised skin
  • Contact dermatitis in individuals with a specific polyethylene glycol allergy
  • Pore congestion in those extremely prone to comedones

If you notice any of the effects above stop using the product and consult a healthcare professional for guidance.

Comedogenic Rating

Rating: 1/5 (low)

The medium chain triglycerides absorb quickly and the PEG segment adds water solubility, so the molecule is unlikely to linger on the skin long enough to block pores.

Suitable for acne prone skin? Generally yes though individual experiences can differ.

Remember the overall formula matters: heavier oils or waxes paired with this ester can still raise the pore clogging risk.

Summary

Caprylic/Capric Triglyceride Peg-4 Esters softens, smooths, lifts away dirt and holds oil with water by pairing lightweight fatty acids with a small water loving PEG tail. This combination lets it condition skin, act as a silky emollient, aid in gentle cleansing and stabilise emulsions.

Its quiet versatility keeps it on the ingredient lists of many cleansers, micellar waters, light lotions and makeup removers though it rarely gets star billing.

Decades of use and safety reviews show it is low risk for irritation or sensitivity at typical levels. Even so it is wise to patch test any new product that contains it to make sure it suits your skin.

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