Ceteareth-4: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: June 24, 2025
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All information on this page is verified using The Personal Care Products Council's (PCPC) INCI database. Our ingredient analyses are based exclusively on PCPC's technical data to ensure accuracy and reliability.

What Is Ceteareth-4?

Ceteareth-4 is a synthetic ingredient made by attaching about four units of ethylene oxide to a blend of cetyl and stearyl (C16-C18) fatty alcohols that usually come from coconut or sustainably sourced palm oil. The result is a waxy solid that easily dissolves in water and oil, which is why it is so handy in cosmetics.

The roots of Ceteareth-4 go back to the 1940s when chemists looked for gentle surfactants that could replace harsher soaps in personal care. By fine-tuning the amount of ethylene oxide added to fatty alcohols, they learned how to create a family of ceteareth ingredients with different numbers after the hyphen. The lower the number the less water-loving it is, giving each grade its own sweet spot in formulas.

Manufacturing starts with purifying plant-derived cetyl and stearyl alcohols, then reacting them with ethylene oxide gas in a closed reactor at controlled temperature and pressure. The finished material is filtered, cooled, and formed into flakes or pellets ready for blending into cosmetic bases.

Because it balances oil and water so well, Ceteareth-4 shows up in many product types: face and body moisturizers, cleansing milks, makeup removers, hair conditioners, sunscreens, soothing masks and even quick-absorbing serums. Formulators pick it when they need light texture without a greasy feel.

Ceteareth-4’s Cosmetic Benefits/Uses

In formulas Ceteareth-4 plays two main roles that improve both performance and skin feel

  • Cleansing: Its surfactant nature lifts away dirt, excess oil and makeup so they rinse off easily. This makes cleansers and makeup removers more effective yet still gentle.
  • Emulsifying: It helps oil and water blend into a smooth stable lotion or cream. This keeps products from separating on the shelf, gives them a uniform texture and helps active ingredients spread evenly on the skin or hair.

Who Can Use Ceteareth-4

Ceteareth-4 is gentle enough for most skin types, including normal, dry, oily and combination skin. People with very sensitive or compromised skin should proceed with a little caution because any surfactant can sometimes disturb an already fragile barrier.

The ingredient is made from plant based cetyl and stearyl alcohols reacted with synthetic ethylene oxide, so it is typically suitable for vegans and vegetarians. Brands that use sustainable coconut or RSPO certified palm sources often highlight this on the label.

Current safety data shows no specific risks for pregnant or breastfeeding women when Ceteareth-4 is used in rinse off or leave on products. This is not medical advice and anyone who is pregnant or nursing should still confirm product choices with a healthcare professional.

Ceteareth-4 is not known to increase photosensitivity, so it does not make skin more prone to sunburn. It also has no effect on hair color treatments or common actives like retinol or vitamin C, making it easy to layer with other products.

Potential Side Effects/Adverse Reactions

Reactions to topical Ceteareth-4 vary from person to person. The points below list potential side effects, but most users will not notice any problems when the ingredient is formulated and used correctly.

  • Mild skin irritation such as redness or stinging, usually short lived
  • Contact dermatitis in individuals with a known sensitivity to ethoxylated ingredients
  • Eye irritation if the product accidentally gets into the eyes
  • Breakouts for some acne prone users because fatty alcohols can occasionally clog pores
  • Very rare allergic response triggered by trace impurities like 1,4-dioxane if the material is poorly purified

If any unwanted reaction occurs stop using the product and seek advice from a healthcare professional.

Comedogenic Rating

Rating: 2 / 5 (low to moderate)

Ceteareth-4 starts with fatty alcohols that could clog pores, yet the addition of ethylene oxide makes the molecule more water soluble and less likely to sit in follicles. Most studies and anecdotal reports point to a fairly low risk of triggering blackheads or pimples, but the possibility is not zero, especially in very occlusive creams. Overall it is usually fine for acne-prone skin when used in lightweight or rinse off formulas.

Comedogenicity also depends on concentration, the presence of heavier oils and whether the product stays on the skin. Rinse off cleansers containing Ceteareth-4 have almost no pore-clogging potential while rich night creams may pose a slightly higher risk.

Summary

Ceteareth-4 is a workhorse cleansing and emulsifying agent that lifts away grime and keeps oil and water blended into a smooth stable product. It does this by combining a fatty tail that loves oil with a short chain of ethylene oxide that loves water, letting it bridge both phases with ease.

The ingredient is popular in moisturizers, gentle cleansers, sunscreens, conditioners and masks because it delivers light texture, dependable stability and mild cleansing without a greasy afterfeel. It is not as trendy as botanical surfactants but formulators return to it again and again for its consistent performance and broad compatibility.

Current safety reviews find Ceteareth-4 non irritating for most users at typical use levels, and it carries a low comedogenic rating. As with any new cosmetic, patch test a small area first to make sure your skin agrees with the full formula.

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