Cetearyl Ethylhexyldimonium Methosulfate: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: June 24, 2025
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All information on this page is verified using The Personal Care Products Council's (PCPC) INCI database. Our ingredient analyses are based exclusively on PCPC's technical data to ensure accuracy and reliability.

What Is Cetearyl Ethylhexyldimonium Methosulfate?

Cetearyl Ethylhexyldimonium Methosulfate is a conditioning agent made by linking a fatty alcohol blend, usually derived from coconut or palm oil, with a small amount of quaternized ammonium salt. This pairing creates a molecule that clings lightly to the surface of hair, giving it softness and slip without a greasy feel. The ingredient first appeared in salon products in the late 1990s when formulators were searching for alternatives to older, heavier quats that left buildup. Today it is produced through a straightforward two-step process: the natural fatty alcohols are first purified then reacted with ethylhexyl dimethyl amine and finally neutralized with a mild sulfate to form a stable, water-dispersible powder or flake.

You will most often find Cetearyl Ethylhexyldimonium Methosulfate in rinse-off and leave-in conditioners, hair masks, co-washes, anti-frizz creams and curl-defining treatments. Its light touch makes it popular in products aimed at fine or oily hair where weightless conditioning is a must.

Cetearyl Ethylhexyldimonium Methosulfate’s Cosmetic Benefits/Uses

Its main role is hair conditioning. By attaching to the hair cuticle, it smooths raised scales, reduces friction during combing and helps hair look shinier and feel softer. Because the molecule is partially derived from natural fatty alcohols, it also adds a subtle moisturizing feel that improves manageability without flattening volume.

Who Can Use Cetearyl Ethylhexyldimonium Methosulfate

This ingredient is considered gentle enough for all scalp and hair types, including those prone to oiliness or sensitivity, because it stays mostly on the hair shaft and rinses away cleanly. It is not known to clog pores on the scalp so users with easily irritated skin can generally tolerate it well.

Cetearyl Ethylhexyldimonium Methosulfate is typically sourced from plant based fatty alcohols such as coconut or palm oil, and the processing agents are synthetic, meaning no animal components are involved. For that reason most finished products using it are suitable for vegans and vegetarians, although strict users should still look for proper vegan certification on the label.

The ingredient has no documented hormonal or systemic activity so it is widely regarded as safe for people who are pregnant or breastfeeding. This is not medical advice and anyone expecting or nursing should have their doctor review any personal care product before use.

It does not increase photosensitivity, and there are no special sun precautions tied to its use. Color treated hair, chemically relaxed hair and natural textures alike can benefit from it because it adds slip without stripping dye molecules or interfering with salon treatments.

Potential Side Effects/Adverse Reactions

Side effects and reactions to the topical application of Cetearyl Ethylhexyldimonium Methosulfate can vary from person to person. The list below covers potential issues, though most users will not experience any of them when the ingredient is formulated and used correctly.

  • Mild scalp redness or itching in people with very sensitive skin
  • Allergic contact dermatitis in rare cases of individual hypersensitivity
  • Eye irritation if the product accidentally drips into the eyes before rinsing
  • Product buildup that can leave hair feeling heavy if used in excess without clarifying shampoos

If any of these effects occur stop using the product and consult a healthcare professional or licensed dermatologist.

Comedogenic Rating

Rating: 1 / 5. Cetearyl Ethylhexyldimonium Methosulfate is largely water dispersible and designed to stay on the hair shaft rather than the skin, which keeps pore-clogging potential very low. Its fatty alcohol portion is lightweight and the quaternized end carries a positive charge that discourages deep penetration into follicles. In leave-on products that touch the hairline it is generally considered safe for acne-prone users, though very oily skin types may still prefer to keep heavy conditioners off the face.

Summary

Cetearyl Ethylhexyldimonium Methosulfate is a light, plant-derived conditioning agent that smooths the cuticle, reduces friction, adds softness and helps hair look shinier. It works by using its positive charge to bond to the negatively charged hair surface, while its fatty alcohol backbone provides a touch of moisture without weight.

Although it is not as famous as ingredients like dimethicone or behentrimonium chloride, formulators reach for it when they need slip and softness that will not flatten fine strands, so you will spot it in many modern conditioners, co-washes and curl creams.

Safety reviews place it in the low-risk category for skin and overall health. Most users tolerate it well but as with any new cosmetic ingredient it is smart to do a quick patch test when trying a product that features it.

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