Chitosan Formate: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: June 24, 2025
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All information on this page is verified using The Personal Care Products Council's (PCPC) INCI database. Our ingredient analyses are based exclusively on PCPC's technical data to ensure accuracy and reliability.

What Is Chitosan Formate?

Chitosan formate is a salt made from chitosan, a natural polymer sourced mainly from the shells of shrimp, crab and other crustaceans. When chitosan reacts with formic acid it forms chitosan formate, a water-compatible powder that dissolves into a clear solution. Chitosan itself has been studied since the 1960s for uses ranging from agriculture to wound dressings, and cosmetic chemists began exploring it in the late 1980s because of its gentle feel and film-forming ability. The process starts with chitin, the hard material that gives shells their structure. Manufacturers clean and grind the shells, remove minerals and proteins, then treat the chitin with an alkaline solution to convert it to chitosan. Finally, the chitosan is neutralized with formic acid to create chitosan formate, filtered, and dried.

Because it forms an invisible, breathable layer on skin or hair, chitosan formate shows up in many rinse-off and leave-on products. You may find it in sheet masks, peel-off masks, anti-aging serums, lightweight moisturizers, makeup primers, hair styling gels, and setting sprays where it helps hold style while keeping a natural feel.

Chitosan Formate’s Cosmetic Benefits/Uses

Chitosan formate is prized for one main reason in personal care formulas.

Film forming: Once applied it dries into a flexible film that locks in moisture, smooths surface texture, boosts the staying power of active ingredients, and provides light hold in hair products without stiffness.

Who Can Use Chitosan Formate

Because it forms a light breathable film, chitosan formate generally suits normal, oily, combination and even sensitive skin that can tolerate a mild acid salt. Very dry skin may prefer richer film formers with added emollients since chitosan formate itself is not highly moisturizing on its own.

The ingredient is derived from crustacean shells so it is not appropriate for vegans or strict vegetarians. While some labs are experimenting with fungal or plant sources of chitosan, products that list chitosan formate almost always come from seafood waste streams.

Current safety data indicates no specific risks for pregnant or breastfeeding women when the ingredient is used topically in cosmetic amounts. Nonetheless this is not medical advice and anyone who is pregnant or nursing should review any skincare or haircare routine with a qualified healthcare provider.

Chitosan formate does not raise the skin’s sensitivity to sunlight so it is not linked to photosensitivity. People with shellfish allergies, however, should check labels carefully and proceed with caution because trace proteins could remain after processing.

Potential Side Effects/Adverse Reactions

Responses to topical chitosan formate differ from person to person. The issues below are possible yet uncommon, assuming the formula has been correctly crafted and preserved.

  • Mild skin irritation – transient redness stinging or itching, usually in very sensitive skin
  • Allergic reaction – rare but more likely in individuals with known shellfish allergies
  • Tight feeling or slight dryness – the film can reduce surface flexibility on very dry skin or overprocessed hair
  • Product buildup on hair – repeated use in styling products may create a filmy residue that dulls shine until washed out

If any of these effects occur discontinue use and consult a healthcare professional if symptoms persist or worsen.

Comedogenic Rating

Rating: 1 / 5

Chitosan formate is water soluble and creates a breathable film rather than an oily layer, so it is very unlikely to clog pores. Its light film can in rare cases trap excess sebum if applied in thick layers or combined with heavy creams, which is why it is given a low but not zero score.

Suitable for acne-prone skin, especially in lightweight formulas.

If you find that any water-based film former tends to build up on your skin, be sure to cleanse well at night to avoid possible pore congestion over time.

Summary

Chitosan formate works mainly as a film former. Once it dries it leaves a clear flexible layer that helps lock in moisture, smooths skin or hair and keeps active ingredients or styling agents in place. The ingredient is still somewhat niche compared with more common polymers like PVP or acrylates, but formulators who want a gentle marine-derived option are starting to use it more.

Current research and consumer reports show it is safe for topical use with only minimal risk of irritation or allergy outside of those sensitive to shellfish. As with any new cosmetic ingredient it is smart to do a quick patch test before adding a new product to your routine just to make sure your skin agrees with it.

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