Chitosan Rice Branamide Hydroxypropyltrimonium Chloride: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: June 24, 2025
Share:
Inside this article:

We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Chitosan Rice Branamide Hydroxypropyltrimonium Chloride?

Chitosan Rice Branamide Hydroxypropyltrimonium Chloride is a specialized ingredient that blends the natural polymer chitosan, derived from the shells of crustaceans, with fatty acids taken from rice bran. These components are joined then quaternized with 3-chloro-2-hydroxypropyltrimethylammonium chloride, giving the final material a positive charge that helps it bind to hair and skin. Interest in chitosan began in the 1980s when formulators noticed its film-forming and conditioning abilities. To improve its compatibility with modern water-based products scientists reacted it with rice bran acids and a gentle quaternizing agent, creating a version that is easier to use and more effective in personal-care formulas.

Manufacturing starts with purified chitosan that is reacted with rice bran acid anhydride, producing an amide link. The resulting compound is then treated with the quaternizing agent in water, yielding a water-soluble powder or viscous fluid. Because the process is carried out in mild conditions it preserves many of the original benefits of both chitosan and rice bran while adding extra conditioning power.

You will often find this ingredient in shampoos, conditioners, leave-in sprays, hair masks, styling creams, face creams, body lotions and mild facial cleansers. Its ability to condition while also helping oil and water mix makes it popular in multi-benefit products such as lightweight moisturizers and anti-aging serums.

Chitosan Rice Branamide Hydroxypropyltrimonium Chloride’s Cosmetic Benefits/Uses

This versatile material offers several helpful functions in beauty products

  • Hair conditioning: Deposits a thin, flexible film on the hair shaft that smooths cuticles, reduces static and improves combability which can lead to softer, shinier strands
  • Skin conditioning: Forms a breathable layer on the skin surface that helps hold moisture, leaving skin feeling smoother and less dry
  • Emollient: Supplies a light, non-greasy softness that can replace or reduce heavier oils in a formula improving skin feel
  • Cleansing: Because of its mild positive charge it can lift away dirt and some negatively charged residues without stripping natural oils making cleansers gentler
  • Emulsifying: Stabilizes mixtures of oil and water allowing formulators to create creams and lotions that stay uniform over time

Who Can Use Chitosan Rice Branamide Hydroxypropyltrimonium Chloride

This conditioning agent is gentle enough for most skin types including normal, dry, combination and even mildly sensitive skin because it forms a lightweight film rather than penetrating deeply. Very oily or acne-prone skin may find heavy, leave-on products containing high amounts of the ingredient feel a little coating, although the material itself is not considered greasy.

Because the chitosan portion is typically sourced from shrimp or crab shells the ingredient is not suitable for vegans or strict vegetarians. A few suppliers offer non-animal chitosan made through fermentation of fungi, yet unless the label clearly states that origin consumers following a vegan lifestyle should assume the material comes from crustaceans.

Shellfish allergy is another point to keep in mind. Although the protein that usually triggers allergic reactions is largely removed during purification a person with a known shellfish allergy should approach products containing this ingredient with caution or seek medical advice first.

Pregnant or breastfeeding women can generally use cosmetics containing Chitosan Rice Branamide Hydroxypropyltrimonium Chloride because it stays on the surface of skin and hair and is not known to interfere with hormones. This is not medical advice and mothers-to-be should show any new personal care product to their doctor just to be safe.

The ingredient does not make skin more sensitive to sunlight and does not interact with UV filters so there is no extra need for sun avoidance beyond normal daily protection.

Potential Side Effects/Adverse Reactions

Reactions to topical Chitosan Rice Branamide Hydroxypropyltrimonium Chloride can vary from person to person. The following list covers potential side effects but they are uncommon when the ingredient is properly formulated and used as directed.

  • Mild skin redness or itching
  • Contact dermatitis in individuals highly sensitive to shellfish derivatives
  • Eye stinging if the product accidentally gets into the eyes
  • Hair feeling weighed down or looking dull when very high levels are used in leave-on products

If any discomfort, rash or other unexpected effect occurs discontinue use and consult a healthcare professional or pharmacist for guidance.

Comedogenic Rating

Rating: 1 / 5

Chitosan Rice Branamide Hydroxypropyltrimonium Chloride is highly water-soluble, light in texture and does not leave an oily residue that could block pores. Its primary action is to form a breathable film on skin and hair rather than sinking into follicles where breakouts start. Because it carries a positive charge it is more likely to rinse away easily, further lowering the risk of build-up. For these reasons it earns a low comedogenic score of 1.

Most people who are prone to acne or frequent breakouts should find this ingredient acceptable in both rinse-off and leave-on products, especially when it appears midway or lower on an ingredient list.

Very heavy formulations loaded with additional occlusive agents could still clog pores even if this polymer is not the main culprit so consider the overall formula when choosing a product.

Summary

Chitosan Rice Branamide Hydroxypropyltrimonium Chloride works as a hair and skin conditioner, mild cleanser, emollient and emulsifier. Its cationic (positively charged) nature helps it latch onto negatively charged hair and skin surfaces forming a thin uniform layer that smooths cuticles, reduces static and traps moisture. The rice bran segment adds fatty acid softness while the chitosan backbone supplies film-forming strength. In emulsions it positions itself between oil and water to keep creams stable and in cleansers its charge attracts dirt for gentler removal.

Although not as famous as silicone or hyaluronic acid, this ingredient is steadily gaining fans among formulators who want multi-function conditioning without heaviness. You will mainly spot it in premium haircare and lightweight skin lotions rather than in mass-market lines.

Overall safety data are reassuring. It stays on the surface, has low irritation potential and is used at modest levels. Shellfish allergy and vegan lifestyle concerns are the main caveats. As with any new cosmetic it is wise to patch test first to make sure your skin agrees with the full formula.

Was this article helpful?
More from Glooshi:
ADVERTISEMENT
Get all our top headlines in beauty.
Delivered right to your inbox each week. Zero spam, all goodness, opt-out at anytime.
This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.
Get the latest beauty news, top product recommendations & brand-exclusive discount codes direct to your inbox.
Send good feedback:

All feedback is greatly appreciated, anonymous, and will be used to improve the quality of our articles.

This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.
Send bad feedback:

All feedback is greatly appreciated, anonymous, and will be used to improve the quality of our articles.

This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.
Search