Cocoa Butter Polyglyceryl-6 Esters: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: June 24, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Cocoa Butter Polyglyceryl-6 Esters?

Cocoa Butter Polyglyceryl-6 Esters is a plant-derived ingredient created by joining rich cocoa butter with polyglycerin-6, a chain of six glycerin units. Cocoa butter comes from the seeds of the cacao tree, famous for giving us chocolate, while polyglycerin-6 is made by linking food-grade glycerin molecules together. When these two parts are blended through a process called transesterification, the result is a smooth, oil-like material that spreads easily on skin.

Chemists started exploring this kind of blend in the early 2000s as a way to keep the comforting feel of cocoa butter yet make it lighter and more skin-friendly. By attaching the polyglycerin portion, they gave traditional cocoa butter better water compatibility and a softer, non-greasy finish, helping formulators create modern textures consumers enjoy.

To make the ingredient, refined cocoa butter is mixed with polyglycerin-6 under controlled heat and pressure. The fatty acids of cocoa butter swap places with parts of the polyglycerin, forming new ester bonds. After purification, you get a pale, semi-fluid ingredient that is easier to work with than raw cocoa butter.

Brands use Cocoa Butter Polyglyceryl-6 Esters in a wide range of products. You will see it in everyday moisturizers, body lotions, lip balms, cleansing balms, baby care creams, after-sun gels and hair masks. It also shows up in deluxe anti-aging formulas where a velvety finish is key.

Cocoa Butter Polyglyceryl-6 Esters’s Cosmetic Benefits/Uses

In skin and hair care formulas this ingredient serves mainly one job, yet it is an important one.

Emollient: It fills in the tiny gaps on the skin surface, leaving it smoother softer and more flexible. Because it is lighter than raw cocoa butter it delivers that cushy feel without a greasy residue, helping creams and lotions glide on evenly and giving lips or hair a silky touch.

Who Can Use Cocoa Butter Polyglyceryl-6 Esters

This ingredient is considered compatible with most skin types. Dry and normal skin benefit from its cushioning moisture while combination and mildly oily skin usually tolerate its lighter feel better than raw cocoa butter. Very oily or highly acne-prone complexions might prefer leaner emollients although the polyglyceryl part makes clogging less likely than with pure butters. Anyone with a known cocoa allergy should steer clear.

Cocoa Butter Polyglyceryl-6 Esters is fully plant based because both cocoa butter and polyglycerin originate from vegetable sources so it fits vegan and vegetarian lifestyles.

Current safety data show no specific risks for women who are pregnant or breastfeeding when the ingredient is used topically. This is not medical advice and expecting or nursing mothers should ask their doctor before adding any new skincare product just to be sure.

The ingredient does not increase sensitivity to sunlight and carries no special UV warnings. It is fragrance free by itself which can be a plus for reactive or eczema-prone skin.

Potential Side Effects/Adverse Reactions

Reactions to Cocoa Butter Polyglyceryl-6 Esters differ from person to person. The points below are only potential issues and are not what the average user should expect when the ingredient is used correctly in a finished formula.

  • Allergic contact dermatitis – rare itching or redness in people sensitive to cocoa proteins
  • Mild pore congestion – possible small bumps on very oily or acne-prone skin if the overall formula is rich
  • Scalp heaviness – a weighed-down feel when used in leave-on hair products for fine hair types
  • Eye irritation – stinging if an emulsion containing the ingredient accidentally gets into the eyes

If any irritation or unexpected reaction occurs stop use immediately and seek advice from a healthcare professional or dermatologist.

Comedogenic Rating

Rating: 2 / 5 – the cocoa butter part is naturally rich in fatty acids that can sit in pores, but attaching it to water-loving polyglycerin makes the molecule more spreadable and less likely to build up. Most users with normal or dry skin will have no problems, yet those who clog easily might notice occasional bumps if the overall formula is very heavy.

Overall it can be suitable for acne-prone skin when used in light emulsions or rinse-off products, though very oily complexions may still prefer leaner options.

Formulators often mix it with quick-absorbing oils or humectants to further cut any clogging risk, so the finished product matters just as much as the raw ingredient.

Summary

Cocoa Butter Polyglyceryl-6 Esters acts mainly as an emollient. It slips into tiny surface gaps to smooth and soften, while the polyglycerin side keeps the texture light and helps the butter blend with water-based ingredients. This gives creams and balms a silky, non-greasy finish that feels comforting yet modern.

The ingredient is growing in popularity because it offers the familiar richness of cocoa butter without the weight that can turn shoppers away. You will spot it more often in mid- to high-end moisturizers, lip care and baby products as brands look for plant-based feel-improvers.

Safety data and real-world use both show a very low risk of irritation or long-term issues. Still, skin is personal, so it is smart to patch test any new product that lists Cocoa Butter Polyglyceryl-6 Esters before diving into full use.

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