Corn Starch/Maltodextrin Crosspolymer: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: June 24, 2025
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All information on this page is verified using publicly available nomenclature standards and reference materials from The Personal Care Products Council (PCPC) and the European Commission's CosIng database. Our analyses are based on technical data from these sources to ensure accuracy and reliability.

What Is Corn Starch/Maltodextrin Crosspolymer?

Corn Starch/Maltodextrin Crosspolymer is a plant-derived powder created from two familiar food ingredients: corn starch and maltodextrin. Chemists link these two carbohydrates together using citric acid, which acts like a natural glue and helps form a stable three-dimensional network. The end result is a smooth, free-flowing powder that performs differently from plain corn starch because the crosslinking makes it more resistant to heat, pH shifts and water.

Although the raw materials have long histories in cooking and pharmaceuticals, the crosslinked version first caught the eye of cosmetic formulators in the early 2000s. They were looking for more eco-friendly alternatives to synthetic film formers and found that this biodegradable, non-GMO option could match the performance of petrochemical counterparts while feeling lighter on the skin.

Manufacturing starts with purified corn starch and food-grade maltodextrin. These powders are blended with a small amount of citric acid, then heated under carefully controlled conditions. The heat drives a chemical reaction that bonds the starch and maltodextrin chains together. After cooling, the powder is washed, dried and milled to the desired particle size.

You will most often spot Corn Starch/Maltodextrin Crosspolymer in products that need to create a flexible film or a soft-focus finish. Typical uses include setting powders, mattifying primers, sheet masks, leave-on moisturizers, antiaging serums, sunscreen lotions and transfer-resistant foundations.

Corn Starch/Maltodextrin Crosspolymer’s Cosmetic Benefits/Uses

This ingredient brings one key function to a formula: it acts as a film former. When applied to skin it lays down an invisible, breathable layer that helps lock in moisture, smooth uneven texture and improve the staying power of makeup or active ingredients. The film also scatters light slightly, giving skin a blurred effect that can soften the look of fine lines and pores.

Who Can Use Corn Starch/Maltodextrin Crosspolymer

Because it is a lightweight plant-based film former with no added oils or fragrances, Corn Starch/Maltodextrin Crosspolymer is generally well tolerated by all skin types including oily, combination, dry and even sensitive skin. Its breathable film does not trap heat or moisture in the way some heavy occlusives do, so most acne-prone users also find it comfortable.

The raw materials are derived entirely from corn and plant sugars, and no animal derivatives are used during processing. This makes the ingredient suitable for both vegans and vegetarians. It is also commonly sourced from non-GMO corn, though you may wish to check individual brands for certification if that is important to you.

No data suggest any hormone-disrupting activity, so products containing Corn Starch/Maltodextrin Crosspolymer are considered safe for those who are pregnant or breastfeeding. That said this is not medical advice and anyone who is pregnant or nursing should run any skin care product past a qualified health professional before use, just to be on the safe side.

The ingredient is not known to cause photosensitivity, so it will not make skin more prone to sunburn. Normal UV protection practices still apply when using an SPF product.

Potential Side Effects/Adverse Reactions

Side effects and reactions to the topical application of Corn Starch/Maltodextrin Crosspolymer can vary from person to person. The points below list potential issues, yet they are unlikely for the average user when the ingredient is used at typical levels in a well-formulated product.

  • Mild skin irritation
  • Allergic contact dermatitis in individuals sensitive to corn derived ingredients
  • Transient dryness or tightness if applied to very dehydrated skin without a companion moisturizer
  • Rare clogged pores if the final formula contains other comedogenic ingredients

If any discomfort, redness or breakouts occur stop using the product and consult a dermatologist or healthcare provider.

Comedogenic Rating

Rating: 1/5 – Corn Starch/Maltodextrin Crosspolymer is a lightweight, water dispersible powder that sits on the surface of skin rather than sinking into pores, so it has a very low tendency to cause blockages. The crosslinked structure creates a breathable film that lets excess sebum escape, which further reduces clogging risk.

Because of this low rating it is generally considered suitable for people prone to acne or breakouts. As always overall pore friendliness depends on the rest of the formula and how the product is used.

If a product combines this polymer with heavy oils, waxes or high levels of certain silicones the finished item may feel more occlusive than the polymer alone. Checking the full ingredient list can give a clearer picture of real-world performance.

Summary

Corn Starch/Maltodextrin Crosspolymer is valued mainly as a plant based film former that locks in light moisture, boosts makeup wear time and gives skin a soft focus finish without heaviness. The citric acid crosslinks turn everyday food starches into a resilient, heat stable powder that forms an even, flexible layer once applied.

While not as famous as silicones or synthetic resins, it is gaining traction in clean beauty circles and in brands looking for biodegradable alternatives that still deliver professional results.

The safety profile is strong, with low irritation and allergy rates and minimal comedogenicity. Still, skin can be unpredictable so it is smart to perform a quick patch test whenever you try a new product containing this or any other unfamiliar ingredient.

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