Dicaprolactone Ethoxyacrylate/1,4-Butanediol/Ipdi Copolymer: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: June 27, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Dicaprolactone Ethoxyacrylate/1,4-Butanediol/Ipdi Copolymer?

Dicaprolactone Ethoxyacrylate/1,4-Butanediol/IPDI Copolymer is a man-made ingredient created by linking three smaller building blocks: dicaprolactone ethoxyacrylate, 1,4-butanediol and isophorone diisocyanate (often shortened to IPDI). When these units join together they form a large chain-like molecule called a copolymer that acts as a film-forming binder on the skin.

The raw materials come from the petrochemical industry, which supplies many cosmetic ingredients. Over time chemists learned that combining these three components produces a stable, flexible film that helps hold other ingredients together. As a result the copolymer gained popularity in the late 1990s when brands began seeking lightweight alternatives to heavier waxes and gums.

Manufacturing starts with controlled reactions of the three monomers under heat and safe catalysts. The process is carefully timed so the resulting polymer has the right length and thickness for cosmetic use. After purification the finished copolymer is a clear or slightly hazy liquid that dissolves well in common cosmetic oils and some solvents.

You will typically find Dicaprolactone Ethoxyacrylate/1,4-Butanediol/IPDI Copolymer in products where a smooth flexible film is useful, such as facial masks, long-wear foundation, waterproof mascara, anti-aging serums, sunscreens, hair styling creams and transfer-resistant lip color.

Dicaprolactone Ethoxyacrylate/1,4-Butanediol/Ipdi Copolymer’s Cosmetic Benefits/Uses

This ingredient is valued mainly for one key function that affects both the feel and performance of many formulas.

Binding: As a binder the copolymer forms an even film that holds pigments, powders and other actives in place. This boosts wear time, water resistance and overall stability so makeup lasts longer without flaking and skincare acts stay where they are meant to deliver benefits.

Who Can Use Dicaprolactone Ethoxyacrylate/1,4-Butanediol/Ipdi Copolymer

This lightweight film former is generally well tolerated by all skin types, including oily, dry, combination and normal skin. Sensitive or highly reactive skin can usually use it too because it sits on the surface rather than penetrating deeply, though anyone with a known sensitivity to acrylic polymers should proceed carefully.

The material is fully synthetic and contains no animal by-products, making it acceptable for both vegetarians and vegans.

No specific warnings exist for pregnant or breastfeeding women, and the ingredient does not appear on common restriction lists. Still, this is not medical advice so anyone who is pregnant or nursing should show the full product label to a healthcare professional before use.

Dicaprolactone Ethoxyacrylate/1,4-Butanediol/IPDI Copolymer does not cause photosensitivity and will not make skin more prone to sunburn. It can actually boost the water resistance of sunscreens, helping the SPF stay in place longer.

Potential Side Effects/Adverse Reactions

Individual reactions to topical Dicaprolactone Ethoxyacrylate/1,4-Butanediol/IPDI Copolymer vary from person to person. The effects below are possible yet unlikely for most users when the ingredient is properly formulated and used as directed.

  • Mild skin irritation
  • Redness or itching linked to an acrylic allergy
  • Eye stinging if the product migrates into the eyes
  • Temporary clogged pores in those who are highly acne-prone

If any of these effects occur discontinue use and seek medical guidance if symptoms persist or worsen.

Comedogenic Rating

Rating: 1 / 5

This copolymer is a large surface-sitting molecule that lacks oily or waxy chains, so on its own it is very unlikely to block pores. The thin breathable film it forms can occasionally trap sebum in users who are extremely acne prone, which is why it is given a cautious 1 instead of a perfect 0.

Overall it is considered suitable for people who are prone to breakouts, especially when the rest of the formula is light and non-greasy.

Keep in mind that a product’s full recipe, application method and cleansing habits all influence real-world comedogenicity.

Summary

Dicaprolactone Ethoxyacrylate/1,4-Butanediol/IPDI Copolymer is mainly used as a binder and film former that locks pigments, powders and active ingredients in place for longer wear and better water resistance. It does this by creating a flexible network on the skin or hair that moves with facial expressions yet keeps everything underneath from smudging or fading.

While not a household name it has carved out a steady niche in long-wear makeup, waterproof mascara, transfer-resistant lip color and modern sunscreens that need dependable staying power without a heavy feel.

Safety data and real-world use show it to be low risk for irritation or clogged pores in most people. As with any new cosmetic ingredient it is smart to perform a small patch test when trying a fresh product to confirm personal compatibility.

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