Dimethicone Peg-7 Octyldodecyl Citrate: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: June 27, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Dimethicone Peg-7 Octyldodecyl Citrate?

Dimethicone Peg-7 Octyldodecyl Citrate is a hybrid ingredient made by joining three well known cosmetic building blocks: citric acid, a silky alcohol called octyldodecanol, and Peg-7 dimethicone, a lightweight silicone. When chemists combine them they create a mixed ester that brings together the smooth glide of silicone, the softness of a fatty alcohol, and the mild acidity of citrus-derived citric acid. The result is a clear to slightly hazy liquid that feels velvety on skin.

This blend appeared in the late 1990s as brands searched for silicone alternatives that could also improve skin feel and boost moisture. By bonding dimethicone with a plant-based alcohol and a food grade acid suppliers offered formulators a stable ingredient that spreads easily without feeling greasy.

Production starts with purified citric acid sourced from fermented sugar. Manufacturers react it with octyldodecanol under controlled heat to form octyldodecyl citrate. Peg-7 dimethicone is then added in a second step, creating the final mixed ester. Every batch is filtered and quality checked to make sure it is colorless, odorless, and low in impurities.

You will spot Dimethicone Peg-7 Octyldodecyl Citrate in lightweight moisturizers, anti-aging serums, sheet masks, BB creams, hair leave-ins, and makeup primers. Brands favor it when they want a silky after-feel without the heavy slip of traditional silicones.

Dimethicone Peg-7 Octyldodecyl Citrate’s Cosmetic Benefits/Uses

This multitasker improves both the feel and performance of many skin and hair formulas.

  • Skin conditioning – forms a soft, flexible film that helps skin hold water, leaving it smoother and more supple
  • Emollient – fills in tiny gaps on the skin surface so it feels softer and looks more even while reducing rough texture

Who Can Use Dimethicone Peg-7 Octyldodecyl Citrate

This silky ester suits most skin types including dry, normal and combination because it adds light moisture without heaviness. Sensitive skin usually tolerates it well since it is non reactive and free of common irritants. Very oily or congestion-prone complexions may prefer it in rinse-off or lightweight formulas rather than rich creams, as any occlusive film can sometimes trap excess sebum.

The ingredient is produced from plant-derived citric acid and octyldodecanol plus lab-made silicone so it contains no animal material, making it appropriate for vegans and vegetarians. Always verify that the finished product is also cruelty free if that is a concern.

No data links Dimethicone Peg-7 Octyldodecyl Citrate to hormonal effects or systemic absorption, so it is generally viewed as safe for those who are pregnant or breastfeeding. This is not medical advice; expectant or nursing mothers should show any skincare routine to their physician before use, just to be cautious.

The ester does not increase photosensitivity so it will not make skin more prone to sunburn. It is stable across a broad pH range and plays nicely with exfoliating acids, retinoids and vitamin C, giving formulators flexibility without risking degradation.

Potential Side Effects/Adverse Reactions

Reactions to topical Dimethicone Peg-7 Octyldodecyl Citrate vary from person to person. The points below list potential side effects but they are uncommon when the ingredient is used correctly in well formulated products.

  • Mild redness or stinging in people with a compromised skin barrier
  • Contact irritation if an individual is allergic to any component of the ester
  • Temporary clogged pores or breakouts in very acne-prone skin when used in heavy leave-on products
  • Product buildup on hair or scalp leading to dullness if not washed out regularly

If you notice irritation, breakouts or any other unwanted change stop using the product and seek advice from a healthcare professional or dermatologist.

Comedogenic Rating

Rating: 1 / 5

This mixed ester contains a light silicone backbone that sits on top of skin rather than sinking into pores. Its PEG side chains keep the molecule water dispersible which helps it rinse away, while the octyldodecyl citrate part is less greasy than pure fatty alcohols. Taken together these traits make it low risk for pore clogging, earning it a 1.

Suitable for most acne-prone users, though extremely oily skin might still prefer it in lightweight or rinse-off products.

Real-world comedogenicity also depends on how much of the ester is used and what other ingredients share the formula, so always judge the finished product as a whole.

Summary

Dimethicone Peg-7 Octyldodecyl Citrate works as a skin conditioner and emollient, forming a thin breathable film that locks in water, smooths rough patches and gives products a silky glide. Its hybrid structure lets it spread like traditional silicone while feeling lighter thanks to the citric ester segment.

It is not yet a household name but formulators lean on it when they need a modern alternative to heavier silicones, so you will spot it in many new serums primers and hair treatments.

Current safety data show low irritation potential and minimal risk of sensitisation, making it generally safe for daily use. Still, every skin is different so patch testing any new product is a smart precaution.

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