Dimethicone Peg-7 Undecylenate: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: June 27, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Dimethicone Peg-7 Undecylenate?

Dimethicone PEG-7 Undecylenate is a hybrid ingredient that blends silicone technology with a plant-derived fatty acid. Chemically, it is the partial ester of PEG-7 dimethicone, a water-dispersible silicone, and undecylenic acid, an oil derived from castor or other vegetable oils. The union of these two parts gives the molecule a dual personality: the silicone end loves oils while the PEG and fatty acid end mixes well with water. This balance makes it valuable when formulating products that need to feel light yet still spread smoothly.

Silicones entered cosmetics in the 1950s for their silky glide, and chemists soon looked for ways to make them more versatile. By the late 1990s PEG-modified silicones such as Dimethicone PEG-7 Undecylenate emerged, answering the need for ingredients that could self-emulsify and rinse off cleanly. Manufacturing involves reacting PEG-7 dimethicone with undecylenic acid under controlled heat and catalysts until part of the silicone becomes esterified. The result is a clear to slightly hazy fluid that is easy to incorporate into both water-based and oil-based systems.

You will meet this ingredient in lightweight moisturizers, leave-in hair serums, clarifying shampoos, micellar cleansers, facial masks, after-sun lotions and many anti-aging creams where a non-greasy feel is crucial.

Dimethicone Peg-7 Undecylenate’s Cosmetic Benefits/Uses

This multitasking agent earns its place on an ingredient list by addressing several formulation needs at once:

  • Hair Conditioning – forms a thin protective film that smooths the cuticle, reduces frizz and adds a soft touch without weighing hair down
  • Skin Conditioning – leaves a breathable layer that improves slip, softens rough patches and imparts a silky after-feel ideal for quick-absorbing lotions
  • Cleansing – the molecule’s dual affinity helps lift away excess oil and impurities, allowing them to rinse off easily for a fresh finish
  • Emulsifying – acts as a bridge between water and oil phases, stabilizing lotions and creams while keeping textures light and non-sticky

Who Can Use Dimethicone Peg-7 Undecylenate

Thanks to its light, non occlusive film Dimethicone PEG-7 Undecylenate suits almost every skin type. Oily, combination and normal skin often appreciate the silky slip without extra shine, while dry or mature skin benefits from the protective layer that slows water loss. Highly sensitive or reactive skin usually tolerates it because the molecule is too large to penetrate deeply and has a low irritation profile. Those with extremely clog-prone skin may want to monitor how their complexion responds, as any film-forming ingredient can occasionally trap debris if cleansing is inadequate.

The raw materials come from silicone chemistry and plant sourced undecylenic acid, so the ingredient itself is free from animal by-products. This makes it acceptable for vegans and vegetarians, provided the finished product and company meet cruelty-free standards.

Current safety data show no specific risks for women who are pregnant or breastfeeding since the compound stays on the surface and is not readily absorbed. This information is not medical advice and anyone expecting or nursing should clear all skincare choices with a healthcare professional to be safe.

Dimethicone PEG-7 Undecylenate is not known to make skin more sensitive to sunlight and does not interfere with common actives like vitamin C, niacinamide or retinol.

Potential Side Effects/Adverse Reactions

Responses to any cosmetic ingredient differ from person to person. The points below represent potential side effects seen in rare cases. When a product is well formulated most users will not notice any of these issues.

  • Mild skin irritation – a temporary sensation of stinging or warmth, usually subsides once the product is removed
  • Contact dermatitis – redness, itching or small bumps in individuals allergic to silicones or PEG derivatives
  • Acne-like breakouts – in very clog-prone skin a residue can, on occasion, contribute to blocked pores
  • Eye irritation – watering or discomfort if the ingredient accidentally gets into the eyes

If any of these reactions occur stop using the product and consult a qualified medical professional.

Comedogenic Rating

Rating: 1/5

Dimethicone PEG-7 Undecylenate earns a very low score because its silicone backbone forms a lightweight breathable film that does not sink into pores. The PEG and fatty acid portions make the molecule water dispersible so it tends to rinse off cleanly rather than build up. While any film former can theoretically trap debris if cleansing is poor, real-world reports of clogged pores with this ingredient are scarce.

Most people who are prone to acne or breakouts can use products containing Dimethicone PEG-7 Undecylenate without issues, though individual experiences can vary.

Keep in mind that comedogenic ratings are only guidelines. Formula complexity, concentration and personal skin chemistry all influence how a finished product behaves.

Summary

Dimethicone PEG-7 Undecylenate conditions hair, softens skin, helps cleanse and stabilises water-oil blends. It does this by pairing a silky silicone segment that loves oils with a PEG-fatty acid segment that mixes with water, giving chemists a flexible tool for lightweight textures that rinse away without residue.

The ingredient is quietly popular in leave-in conditioners, micellar cleansers and fast-absorbing lotions, though it is less of a household name than plain dimethicone.

Current data show it is safe for almost all skin types with a low risk of irritation or pore clogging. As with any new product it is wise to perform a quick patch test first just to be safe.

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