Dimethicone Peg/Ppg-7/4 Phosphate: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: June 27, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Dimethicone Peg/Ppg-7/4 Phosphate?

Dimethicone Peg/Ppg-7/4 Phosphate is a silicone-based ingredient created by reacting dimethicone with phosphoric acid along with an average of seven units of ethylene oxide and four units of propylene oxide. The result is a partially esterified molecule that blends the silky feel of silicones with the water-friendly nature of polyethylene glycol and polypropylene glycol. Because of this mixed structure it can sit at the boundary between oil and water, helping the two phases cooperate in a single formula.

Silicones began gaining traction in cosmetics in the 1950s for their velvety glide and protective feel. Chemists later enhanced them by attaching PEG or PPG chains, making the molecules more versatile. Adding a phosphate group was the next step, introduced in the 1990s to improve stability and mild cleansing action without sacrificing the signature smooth touch.

The manufacturing process starts with medical-grade dimethicone that is first reacted with ethylene oxide and propylene oxide in controlled conditions to graft on the PEG and PPG portions. This intermediate is then treated with phosphoric acid to create a partial ester. Careful purification removes by-products, leaving a clear, low-odor liquid.

You will usually find Dimethicone Peg/Ppg-7/4 Phosphate in lightweight moisturizers, facial cleansers, micellar waters, makeup removers, conditioning shampoos, hair masks and leave-in styling creams. Its ability to emulsify, cleanse and leave a soft finish makes it popular in daily skin care and hair care formulas that aim for a fresh non-greasy feel.

Dimethicone Peg/Ppg-7/4 Phosphate’s Cosmetic Benefits/Uses

This multi-tasking ingredient supports several technical roles in a formula that translate into user-friendly benefits

  • Cleansing: Its phosphate group allows it to latch onto excess oil and impurities while its silicone backbone keeps it gentle. This leads to effective yet mild removal of dirt and makeup without leaving skin tight or hair stripped.
  • Emulsifying: By bridging water and oil phases it helps create stable, homogenous emulsions. This keeps creams from separating, enhances spreadability and ensures the active ingredients are delivered evenly with each use.

Who Can Use Dimethicone Peg/Ppg-7/4 Phosphate

Most skin types tolerate this ingredient well, including oily, combination, normal and mildly dry skin thanks to its light texture and gentle cleansing profile. Very dry or compromised skin might feel it does not deliver enough long-lasting moisture on its own, so pairing it with richer emollients can help.

The compound is manufactured entirely from synthetic sources so it is suitable for vegetarians and vegans who avoid animal-derived ingredients.

Current safety data show no known risks for pregnant or breastfeeding women when the ingredient is used topically at the concentrations found in cosmetics. This is not medical advice; anyone who is expecting or nursing should discuss any skincare product with a qualified physician before use just to be safe.

Dimethicone Peg/Ppg-7/4 Phosphate is not known to cause photosensitivity and does not increase vulnerability to sunburn. Standard sun protection habits should still be followed when spending time outdoors.

Potential Side Effects/Adverse Reactions

Responses to topical Dimethicone Peg/Ppg-7/4 Phosphate vary from person to person. The points below outline potential side effects yet most users will not experience them when the ingredient is formulated and used correctly.

  • Mild transient stinging or redness in very sensitive skin
  • Rare contact dermatitis for individuals with a silicone or PEG sensitivity
  • Eye irritation if the product accidentally enters the eyes
  • Build-up on hair leading to a weighed-down feel if rinsing is inadequate

If any discomfort, persistent redness or other adverse reaction occurs stop using the product and seek advice from a healthcare professional.

Comedogenic Rating

Rating: 1 / 5

Dimethicone Peg/Ppg-7/4 Phosphate earns a low score because its large silicone backbone stays mainly on the surface and the attached PEG / PPG chains let it rinse away more easily than traditional dimethicone. This reduces the chance of it clogging pores. Most people who are prone to acne or breakouts should find it compatible with their routine.

As with any film-forming agent build-up can happen if the rest of the formula contains heavy oils or if cleansing is inadequate so overall product design and good washing habits still matter.

Summary

Dimethicone Peg/Ppg-7/4 Phosphate acts as a mild cleanser that lifts oils, an emulsifier that keeps water and oil blended and a slip agent that leaves skin and hair feeling silky. It pulls off this trio of tasks by combining a smooth silicone skeleton with water-loving PEG / PPG chains and a phosphate group that boosts cleansing power.

While not as famous as plain dimethicone this hybrid silicone shows up in modern lightweight cleansers, micellar waters and leave-in hair products where formulators want both a soft touch and easy rinse-off.

Current research and cosmetic panel reviews rate it as low risk for irritation or sensitization when used at typical percentages. Still skin can be unpredictable so it is wise to patch test any new product that features this ingredient before applying it widely.

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