Dipentaerythrityl Hexa C5-9 Acid Esters: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: June 27, 2025
Share:
Inside this article:

We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Dipentaerythrityl Hexa C5-9 Acid Esters?

Dipentaerythrityl Hexa C5-9 Acid Esters is a group of synthetic ingredients made by reacting dipentaerythritol, a multi-functional alcohol, with a blend of short chain carboxylic acids that have five to nine carbon atoms. The result is a clear, oil-like liquid made up of six ester bonds, giving it a lightweight silky feel that spreads easily on skin and hair.

The ingredient emerged in the late twentieth century when formulators looked for alternatives to heavier natural oils that could deliver smooth application without leaving a greasy residue. By adjusting the ratio of C5 to C9 acids, chemists fine-tune viscosity and melting point to suit different product types.

Manufacturing begins with plant-derived or petrochemical feedstocks that are purified, then esterified in a controlled reactor at high temperature. After the reaction is complete the mixture is filtered, vacuum-stripped to remove excess acids and finally quality-checked for purity and stability.

Its slip, lightweight cushion and ability to dissolve other ingredients make it popular in leave-in hair serums, conditioning masks, moisturizing creams, anti-aging lotions, lightweight sunscreens, deodorant sticks and color cosmetics such as lipsticks and foundations.

Dipentaerythrityl Hexa C5-9 Acid Esters’s Cosmetic Benefits/Uses

This multitasking ester brings several formulating advantages:

  • Hair conditioning – coats the hair shaft to reduce friction enhance shine and improve combability without weighing strands down
  • Plasticiser – softens solid formulas like sticks pencils and pressed powders helping them glide smoothly and resist cracking
  • Skin conditioning – forms a light emollient layer that smooths rough patches boosts suppleness and leaves a soft non-greasy afterfeel
Who Can Use Dipentaerythrityl Hexa C5-9 Acid Esters

This ester is generally friendly to all skin types, including oily, combination, normal and dry. Its light texture does not clog pores and its smooth finish can help soothe dry patches without adding heaviness. Sensitive or reactive skin usually tolerates it well because it is non-fragrant and has low irritation potential. Those with very acne-prone skin may still prefer to monitor how their skin responds since any emollient can be a concern for some individuals.

The ingredient is synthetic and contains no animal-derived material so it is suitable for vegans and vegetarians. It is also not typically tested on animals when sourced from cruelty-free suppliers, though final product policies will vary by brand.

No specific warnings exist for use during pregnancy or while breastfeeding. The molecule does not penetrate deeply and has no known hormonal activity. Still, this is not medical advice and anyone who is pregnant or nursing should review all personal care products with a healthcare professional to be extra cautious.

Dipentaerythrityl Hexa C5-9 Acid Esters does not cause photosensitivity. It can even improve the feel of sunscreens by reducing greasiness, but it does not add any sun protection on its own.

Potential Side Effects/Adverse Reactions

Side effects from topical use can vary person to person. The points below list potential reactions that are unlikely for most users when the ingredient is formulated and used correctly.

  • Mild skin irritation – a small number of people may notice redness or a stinging sensation, usually due to individual sensitivity
  • Contact dermatitis – rare allergic response leading to itching or rash, more likely in those with multiple existing allergies
  • Eye irritation – if a product containing the ester accidentally gets into the eyes it can cause temporary tearing or discomfort
  • Acne flare-up – very oily or acne-prone skin might experience clogged pores if the rest of the formula is also rich in emollients

If you notice any of these effects stop using the product and consult a medical professional if symptoms persist or worsen.

Comedogenic Rating

Rating: 1/5. Dipentaerythrityl Hexa C5-9 Acid Esters is a lightweight ester that spreads thinly and evaporates slowly without leaving a thick residue that can trap dead skin cells inside pores. Its molecular structure is bulky and branched which keeps it sitting mostly on the surface and makes it less likely to harden inside follicles. For these reasons formulators and cosmetic safety databases consider it very low on the pore-clogging scale.

Suitable for acne-prone or breakout-prone skin, especially in well balanced formulas that do not rely heavily on multiple heavy oils.

Real-world reactions can still differ based on the overall product, the concentration used and what other occlusive ingredients are present.

Summary

Dipentaerythrityl Hexa C5-9 Acid Esters works as a hair and skin conditioner plus a plasticiser. Its six ester bonds give it a silky slip that smooths rough cuticles on hair, softens skin and helps solid sticks glide without crumbling. Because it is clear, odorless and stable, formulators add it to everything from leave-in serums and sunscreens to lipsticks and pressed powders.

The ingredient is moderately popular: not as famous as plant oils or silicones yet valued in professional labs for its light feel and versatility. It blends easily with other emollients, cuts down greasiness and boosts consumer sensory appeal.

Safety reviews rate it as low risk with minimal irritation or sensitisation potential. Still, skin is personal so it is smart to patch test any new product that lists Dipentaerythrityl Hexa C5-9 Acid Esters near the top of the ingredient list just to be safe.

Was this article helpful?
More from Glooshi:
ADVERTISEMENT
Get all our top headlines in beauty.
Delivered right to your inbox each week. Zero spam, all goodness, opt-out at anytime.
This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.
Get the latest beauty news, top product recommendations & brand-exclusive discount codes direct to your inbox.
Send good feedback:

All feedback is greatly appreciated, anonymous, and will be used to improve the quality of our articles.

This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.
Send bad feedback:

All feedback is greatly appreciated, anonymous, and will be used to improve the quality of our articles.

This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.
Search