Ferric Chloride: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: June 27, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Ferric Chloride?

Ferric chloride, also known as iron trichloride, is a salt formed when iron reacts with chlorine. In its pure state it appears as dark brown crystals that dissolve readily in water to create a yellow-brown solution. The compound is typically produced on an industrial scale by treating scrap iron with dry chlorine gas or by oxidizing ferrous chloride. Although ferric chloride has long been used in water treatment and metal etching, cosmetic chemists recognized its value as an astringent in the mid-20th century and began incorporating it into skin care formulas that call for rapid tightening or toning effects. Today you will most often see ferric chloride in rinse-off masks, clarifying toners, post-shave lotions, scalp treatments and occasional spot treatments aimed at minimizing the look of enlarged pores.

Ferric Chloride’s Cosmetic Benefits/Uses

Ferric chloride serves as an astringent, meaning it helps tighten skin temporarily by causing proteins on the surface to contract. This quick contraction can reduce the appearance of pores, curb excess oil and leave skin feeling smoother and firmer after use.

Who Can Use Ferric Chloride

Ferric chloride is generally best for normal to oily skin because its astringent action helps cut down surface oil and gives a tightening feel. Dry or easily irritated skin may find it too stripping since the salt can remove lipids that keep those skin types comfortable. Sensitive complexions should also proceed with caution for the same reason: the fast contracting effect can sometimes trigger stinging.

The ingredient is mineral based and contains no animal derived components so it is suitable for both vegetarians and vegans. It is also cruelty free when sourced from reputable suppliers because its manufacture does not require animal testing.

No data suggest that ferric chloride poses a specific risk to pregnant or breastfeeding women when used topically in rinse-off or leave-on concentrations found in cosmetics. That said this is not medical advice and anyone who is pregnant or nursing should discuss any new skincare product with a qualified healthcare provider first.

Ferric chloride does not increase photosensitivity so there is no special need to avoid sun exposure beyond normal daily sun protection practices. People using exfoliating acids or retinoids alongside an astringent toner containing ferric chloride may wish to alternate use to avoid compounding dryness.

Potential Side Effects/Adverse Reactions

Reactions to topical ferric chloride vary from person to person. The effects below are only potential outcomes and are unlikely for most users when the ingredient has been properly formulated and used as directed.

  • Transient stinging or burning on application
  • Temporary redness or flushing
  • Excessive dryness or tightness with repeated use
  • Mild skin irritation in sensitive individuals
  • Rare localized discoloration if left on very porous skin for extended periods

If you notice persistent discomfort or visible irritation stop using the product and consult a healthcare professional

Comedogenic Rating

Rating: 0/5
Ferric chloride is a water-soluble inorganic salt that does not leave an oily or waxy residue on skin, so it has virtually no potential to block pores. Because it works by contracting surface proteins instead of forming a film, it is considered non-comedogenic. For that reason the ingredient is generally suitable for people who are prone to acne or frequent breakouts. Since its action is tightening rather than coating, build-up that could trap sebum or bacteria is unlikely.

One point to note: formulas that pair ferric chloride with heavier emollients could alter the overall pore-clogging risk, but the salt itself remains non-comedogenic.

Summary

Ferric chloride acts mainly as an astringent, delivering quick tightening, oil-reducing and pore-minimizing effects by causing surface proteins to contract. It is not a headline ingredient in most modern skincare lines, yet it still appears in select toners, masks and aftershaves where an immediate firm feel is desired.

Topically applied in cosmetic strengths, ferric chloride is considered safe for the vast majority of users though overuse can lead to dryness or irritation. As with any new skincare product it is smart to do a patch test first to be sure your skin tolerates the formula.

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