Glycereth-20 Benzoate: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: June 27, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Glycereth-20 Benzoate?

Glycereth-20 Benzoate is a lab-made ester that joins benzoic acid with a glycerin base that has been linked to about 20 units of ethylene oxide. In simple terms it combines parts of a gentle fruit acid with a water-loving form of glycerin to create a clear liquid that mixes easily with water and oil.

The idea of blending glycerin and benzoic acid dates back to the mid-20th century, when chemists looked for ways to improve skin feel in lotions without using heavy oils. By adding ethylene oxide units they found they could make glycerin more flexible and less sticky. Over time this modified glycerin was paired with benzoic acid to boost stability and give extra skin benefits, leading to the ingredient now known as Glycereth-20 Benzoate.

Manufacturing starts with plant-derived glycerin. Through controlled reactions it is treated with ethylene oxide to attach roughly 20 repeating units. The resulting glycereth-20 then reacts with benzoic acid in the presence of heat and a catalyst. After purification the clear, low-odor liquid is ready for cosmetic use.

Thanks to its balanced mix of water and oil loving parts, Glycereth-20 Benzoate shows up in many formulas. You might find it in face and body moisturizers, sheet masks, gentle cleansers, lightweight serums, after-sun gels and anti-aging creams where a smooth, non-greasy finish is needed.

Glycereth-20 Benzoate’s Cosmetic Benefits/Uses

Formulators choose this ingredient for two main reasons

  • Skin conditioning: It helps water bind to the skin surface which can soften, smooth and protect against dryness. Its silky texture also improves spreadability so creams feel lighter
  • Solvent: It dissolves both oil and water soluble ingredients allowing actives, fragrances and colors to blend evenly which leads to stable products with no separation

Who Can Use Glycereth-20 Benzoate

The ingredient is generally well tolerated by most skin types including dry, oily, combination and normal skin because it is lightweight and non occlusive. Sensitive skin usually does fine as well since the molecule is mild and has a low chance of causing irritation, though anyone with a known allergy to benzoic acid derivatives should remain cautious.

Glycereth-20 Benzoate is synthesized from plant derived glycerin and benzoic acid that can come from either plant or synthetic sources. No animal by-products are needed in the process, so it is suitable for both vegans and vegetarians. If you follow a cruelty free lifestyle you can also feel comfortable, provided the finished product from a specific brand is certified as not tested on animals.

Current safety data do not flag the ingredient as problematic for women who are pregnant or breastfeeding when used in typical cosmetic concentrations. This is not medical advice and anyone expecting or nursing should show the full product ingredient list to a qualified healthcare provider before adding it to a routine.

The molecule is stable in sunlight and does not make skin more reactive to UV rays so it is not considered photosensitizing. It also plays nicely with common actives such as niacinamide, vitamin C and retinoids so there are no special layering rules to worry about.

Potential Side Effects/Adverse Reactions

Reactions to topical Glycereth-20 Benzoate can differ from person to person. The points below outline potential side effects but most users will not encounter them when the ingredient is used at standard cosmetic levels.

  • Mild redness or stinging in individuals with very reactive skin
  • Contact dermatitis in those allergic to benzoic acid or related preservatives
  • Eye irritation if the product accidentally gets into the eyes
  • Rare clogging or congestion on extremely acne-prone skin when used in heavy formulations

If any unwanted reaction occurs stop using the product and consult a healthcare professional or dermatologist for guidance.

Comedogenic Rating

Rating: 1/5. Glycereth-20 Benzoate is a light, water friendly ester that absorbs quickly and leaves little residue so it has a very low tendency to clog pores. Its structure is more humectant than oily which keeps it from forming the kind of thick film that traps sebum and debris. Most acne prone users should find it safe, but extremely sensitive or highly congested skin might want to monitor results.

Like all ingredients the final formula matters: if Glycereth-20 Benzoate is blended into a rich butter or wax heavy cream the overall product could still feel heavy. On its own, though, it ranks near the bottom of the pore-clogging scale.

Summary

Glycereth-20 Benzoate is mainly used to condition skin and to act as a solvent. Its humectant backbone pulls in water to keep the surface supple while the benzoate portion adds a light emollient slip. At the same time its balanced water and oil affinity lets it dissolve fragrance oils, pigments and active ingredients so formulas stay smooth and stable.

It is not the most talked about additive, yet it shows up quietly in a wide range of modern lotions, serums and cleansers because chemists appreciate its reliable performance and pleasant skin feel.

Current data show it is low risk for irritation or sensitization when used at cosmetic levels. Still, everyone’s skin is unique so it is smart to patch test any new product that lists Glycereth-20 Benzoate before making it part of a daily routine.

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