Glyceryl Undecylenate: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: June 27, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Glyceryl Undecylenate?

Glyceryl Undecylenate is an ester formed when glycerin, a naturally occurring humectant derived from plant oils, reacts with undecylenic acid, a fatty acid obtained from the cracking of castor oil. The result is a mild, oil-compatible ingredient that blends the skin-friendly nature of glycerin with the softly acidic character of undecylenic acid, creating a multifunctional molecule prized by formulators.

Interest in this ester began in the mid-20th century when chemists looked for gentler alternatives to harsh preservatives and stabilizers. Its ability to condition skin while also helping oil and water mix made it a natural fit for modern clean beauty trends. Today manufacturers typically craft Glyceryl Undecylenate through a controlled esterification process: glycerin and undecylenic acid are heated with a catalyst, water is removed, then the mixture is purified to obtain a clear, slightly viscous liquid.

You will spot this ingredient in a wide range of leave-on and rinse-off products. It shows up in lightweight facial moisturizers, rich body creams, soothing after-sun gels, sheet masks, scalp treatments and age-defying serums. Its versatility also makes it useful in natural deodorants, blemish-prone skin lotions and gentle baby care formulas.

Glyceryl Undecylenate’s Cosmetic Benefits/Uses

Thanks to its trio of functions Glyceryl Undecylenate offers several perks in one package

  • Skin conditioning: Softens and smooths the skin surface, helping it feel supple and hydrated without a greasy afterfeel
  • Emollient: Forms a light lipid film that reduces moisture loss, enhancing comfort for dry or sensitive skin types
  • Emulsifying: Helps oil and water phases stay blended, improving product stability and creating a pleasant, uniform texture

Who Can Use Glyceryl Undecylenate

This ester is considered suitable for most skin types. Dry and sensitive skin benefit from its softening film while normal and combination skin enjoy its light feel. Even oily or blemish-prone skin usually tolerates it because the molecule is small and non-greasy, though anyone who reacts easily to fatty acids should proceed with extra care.

The material is produced from plant glycerin and castor-derived undecylenic acid so it is generally acceptable for vegans and vegetarians as long as the finished formula contains no animal by-products.

No specific warnings have been issued for pregnancy or breastfeeding. The ingredient is classed as low risk when applied topically in cosmetic amounts, yet safety data during these life stages is limited. This is not medical advice and expectant or nursing mothers should show any skincare product to their doctor before use to be safe.

Glyceryl Undecylenate is not known to cause photosensitivity and does not increase the need for extra sun protection beyond daily SPF recommendations.

Potential Side Effects/Adverse Reactions

Side effects from topical Glyceryl Undecylenate can differ from one person to another. The points below list potential reactions but they are uncommon when the ingredient is used at the levels allowed in cosmetics.

  • Mild redness or stinging in very sensitive skin, especially on broken or freshly exfoliated areas
  • Contact dermatitis in individuals allergic to castor oil derivatives or fatty acids
  • Temporary clogged pores in users who are extremely prone to comedones
  • Eye irritation if the product accidentally gets into the eyes

If you experience any of the above stop using the product and consult a healthcare professional for guidance.

Comedogenic Rating

Rating: 1/5

Glyceryl Undecylenate is a lightweight ester that spreads easily and leaves only a thin film on the skin. Its glycerin backbone is water loving while the undecylenic acid segment is oil loving, so the molecule balances itself rather than building up in pores. Because it is less occlusive than heavier plant butters or waxes, it rarely blocks follicles, yet the fatty acid portion still carries a small chance of congestion in those who react to almost any lipid.

Most people prone to acne can use products containing Glyceryl Undecylenate without problems.

Final pore-clogging risk also depends on the full formula and how much of the ester is present. Levels in leave-on skincare typically sit well below those that could tip the scale toward breakouts.

Summary

Glyceryl Undecylenate is a multitasking ester that conditions skin, acts as a soft emollient and helps oils blend with water. The glycerin part attracts moisture while the fatty acid side forms a protective veil that slows water loss and stabilises emulsions, giving creams and lotions a smooth feel.

It is not as famous as hyaluronic acid or niacinamide, yet formulators in clean beauty and sensitive skin ranges appreciate its gentle profile and plant origin, so it appears steadily in niche products and a growing number of mainstream launches.

Safety data place it in the low risk category with only rare reports of irritation. As with any new ingredient it is wise to patch test a product before full use just to be on the safe side.

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