Glycol Dioleate: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: June 27, 2025
Share:
Inside this article:

We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Glycol Dioleate?

Glycol dioleate is an ester created when ethylene glycol reacts with two molecules of oleic acid, a fatty acid that occurs naturally in many plant oils such as olive, sunflower and soybean oil. The result is a waxy liquid that feels silky to the touch. Cosmetic chemists first turned to this ingredient in the 1970s as they searched for gentle alternatives to harsh thickeners and softening agents. Today it is produced in large batches through a simple heating process called esterification, where ethylene glycol and purified oleic acid are mixed with a food grade catalyst, then washed and filtered until the final product is neutral and skin friendly. You can spot glycol dioleate in a wide range of personal care items including shampoos, creamy body washes, bath oils, moisturizers, facial masks, hair conditioners, shaving creams and anti aging serums because it helps them feel richer and more cushioned on the skin.

Glycol Dioleate’s Cosmetic Benefits/Uses

This multitasking ingredient is valued for several roles in a formula

  • Skin conditioning – it forms a light, breathable film that smooths rough patches so skin and hair feel softer and more supple
  • Emollient – its fatty structure fills in microscopic gaps on the skin surface, locking in moisture and giving products a luxurious glide
  • Viscosity controlling – it thickens watery formulas, turning them into creamy washes or lotions that stay put during use and dispense more evenly from a bottle or pump

Who Can Use Glycol Dioleate

Glycol dioleate is generally well tolerated by most skin types. Dry, normal and combination skin tend to appreciate its smoothing and moisture-locking feel. Sensitive skin typically handles it without trouble because it is non-reactive and free of common allergens. Very oily or acne-prone skin may want to keep usage moderate since richer fatty esters can occasionally feel too heavy and contribute to congestion.

The ingredient is sourced from plant-derived oleic acid and synthetic ethylene glycol, so it contains no animal matter and is suitable for vegans and vegetarians.

Current safety reviews show no specific risks for pregnant or breastfeeding women when glycol dioleate is used in rinse-off or leave-on products. This is not medical advice and anyone who is pregnant or nursing should ask a healthcare professional before adding new skincare items, just to be safe.

Glycol dioleate does not increase photosensitivity, so normal sun precautions apply. It also has no known interactions with common actives like retinol or vitamin C, letting it fit easily into multi-step routines.

Potential Side Effects/Adverse Reactions

Responses to any cosmetic ingredient can differ person to person. The points below outline potential side effects but they are uncommon when glycol dioleate is used at normal cosmetic levels and formulated by a reputable brand.

  • Mild skin irritation – rare stinging, redness or itching on very reactive skin
  • Contact allergy – exceptionally uncommon sensitization that may result in rash or swelling
  • Breakouts – possible clogged pores or pimples on individuals already prone to acne, especially with heavy leave-on products
  • Eye irritation – temporary watering or stinging if a product accidentally gets into the eyes

If any troublesome reaction occurs stop using the product and seek medical advice if the issue does not quickly subside.

Comedogenic Rating

Rating: 2 out of 5

Glycol dioleate contains oleic acid chains that lend a slightly rich, occlusive feel, so it can sit on the skin longer than lighter esters. Still, its molecular weight and typical low use levels reduce the chance of it fully blocking pores. Most people will not notice extra blemishes, but skin that is already very oily or acne prone could experience occasional congestion if the overall formula is heavy or left on for long periods.

This moderate score means the ingredient is usually fine for those with the odd breakout, yet may be less suitable for individuals with persistent acne.

Remember that a product’s real-world pore-clogging potential depends on the entire ingredient list, how often you apply it and how thoroughly you cleanse.

Summary

Glycol dioleate works as a skin conditioner, emollient and viscosity controller. Its fatty structure smooths and softens while forming a light film that locks in moisture. At the same time its waxy texture thickens watery bases so cleansers, lotions and masks feel creamier and spread more evenly.

Although it is not a headline ingredient, formulators reach for it often because it is affordable, plant linked and delivers a cushioned sensory feel that shoppers like.

Safety data show a very low risk of irritation, allergy or toxicity. Even so, skin can be unpredictable, so it is wise to patch test any new product containing glycol dioleate before full use.

Was this article helpful?
More from Glooshi:
ADVERTISEMENT
Get all our top headlines in beauty.
Delivered right to your inbox each week. Zero spam, all goodness, opt-out at anytime.
This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.
Get the latest beauty news, top product recommendations & brand-exclusive discount codes direct to your inbox.
Send good feedback:

All feedback is greatly appreciated, anonymous, and will be used to improve the quality of our articles.

This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.
Send bad feedback:

All feedback is greatly appreciated, anonymous, and will be used to improve the quality of our articles.

This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.
Search