Hydrogenated Olive Oil Caprylyl Esters: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: June 27, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Hydrogenated Olive Oil Caprylyl Esters?

Hydrogenated Olive Oil Caprylyl Esters is a plant based ingredient created from olive oil that has been fully hydrogenated, then reacted with capryl alcohol, a short chain alcohol often sourced from coconut or palm. The hydrogenation step turns the liquid olive oil into a wax like solid, removing unsaturated bonds to make it more stable. The following esterification step links the fatty acids from the olive oil to capryl alcohol, giving a smooth, light feeling material that behaves a bit like synthetic emollients yet keeps a natural origin.

This ingredient entered the cosmetic scene in the early 2000s when brands were looking for silicone alternatives that could still give slip, gloss and a protective film. Olive oil was already loved for its skin compatibility, so chemists modified it to improve texture and shelf life, making it easy to place in modern formulas.

Manufacturing starts with food grade olive oil. It is hydrogenated under controlled pressure with a nickel catalyst until it becomes fully saturated. After purification it is blended with capryl alcohol and heated in the presence of an acid or enzyme catalyst to form the final esters. The result is a pale, almost odorless wax that melts quickly on skin.

You will find Hydrogenated Olive Oil Caprylyl Esters in moisturizers, anti-aging creams, body lotions, sunscreens, hair conditioners, styling balms, lipsticks and cleansing balms where it lends a soft, cushiony touch.

Hydrogenated Olive Oil Caprylyl Esters’s Cosmetic Benefits/Uses

Formulators value this ingredient for several performance perks

  • Emulsion stabilising – helps oil and water stay blended so creams keep a uniform texture and do not separate on the shelf or during use
  • Film forming – creates a light breathable film on skin or hair that locks in moisture, smooths rough spots and boosts the longevity of actives or pigments
  • Hair conditioning – coats the hair shaft to reduce frizz, improve combability and add a natural looking shine without a heavy greasy feel

Who Can Use Hydrogenated Olive Oil Caprylyl Esters

Because it is light and non-greasy most skin types can tolerate Hydrogenated Olive Oil Caprylyl Esters. Dry and normal skin often appreciate the soft film it leaves while sensitive skin tends to find it gentle thanks to the lack of fragrance and low risk of stinging. Very oily or acne-prone skin can still use it but may prefer lower levels in a formula as the protective layer could feel too rich if used in high amounts.

The material is made from olive oil and plant sourced capryl alcohol so it fits vegan and vegetarian lifestyles. No animal products or by-products are involved during standard manufacturing.

Current safety data shows no known concerns for women who are pregnant or breastfeeding when the ingredient is used in topical products. This is not medical advice and anyone expecting or nursing should check with a doctor before adding new skincare just to be on the safe side.

Hydrogenated Olive Oil Caprylyl Esters is not linked to photosensitivity. It will not make skin more prone to sunburn and can be paired with sunscreens without issue.

Potential Side Effects/Adverse Reactions

Reactions to any cosmetic ingredient can differ from person to person. The points below cover possible but uncommon side effects. When used at normal levels most people will not run into these problems as long as the finished product has been formulated correctly.

  • Mild skin irritation or redness in very sensitive individuals
  • Allergic contact dermatitis in users with an olive or fatty alcohol allergy
  • Clogged pores or breakouts if applied heavily on acne-prone skin
  • Build-up on hair shafts that may lead to limp or weighed-down strands with frequent use

If any discomfort or unusual reaction occurs stop using the product and consult a healthcare professional or dermatologist.

Comedogenic Rating

Rating: 2 / 5

Hydrogenated Olive Oil Caprylyl Esters has a low to moderate likelihood of clogging pores. The hydrogenation step removes much of the natural olive oil’s unsaturated content, giving a waxy ester structure that sits lighter on skin than raw oils. Still, its film forming nature can trap debris if a formula is very rich or if it is applied in thick layers, which is why it earns a 2 instead of a 0 or 1.

Most people prone to acne can use products containing this ingredient, especially when it appears lower on the ingredient list, but extremely oily or congestion-prone skin may prefer lighter textures.

Keep in mind that overall product design matters. A formula that balances these esters with lightweight humectants and non-occlusive emulsifiers will feel less heavy than one that pairs them with other waxes and butters.

Summary

Hydrogenated Olive Oil Caprylyl Esters serves as an emulsion stabiliser, a breathable film former and a lightweight hair conditioner. Its saturated olive-derived backbone lends structural support to creams so water and oil stay mixed, while the caprylyl side offers slip that leaves skin or hair smooth and subtly glossy. This dual nature lets it mimic silicones without the synthetic label.

The ingredient is moderately popular, appearing most often in clean beauty lines, hybrid skincare makeup and silicone-free hair products. It is not yet a household name but formulators appreciate its plant origin and versatility.

Current data shows it to be low risk for irritation or sensitisation when used as intended, though anyone trying a new product should still patch test to ensure personal compatibility.

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