Hydroxypropyl Dimethicone Behenate: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: June 27, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Hydroxypropyl Dimethicone Behenate?

Hydroxypropyl Dimethicone Behenate is a specialty silicone created by joining hydroxypropyl dimethicone, a lightweight water-friendly silicone, with behenic acid, a long-chain fatty acid most often taken from moringa or rapeseed oil. The result is a hybrid molecule that blends the silky glide of silicones with the soft, cushiony feel of natural oils.

Silicone chemistry took off in the 1950s when beauty brands began looking for ingredients that could smooth the skin without feeling greasy. Over time scientists learned that attaching fatty acids to silicones could improve spreadability and staying power. Hydroxypropyl Dimethicone Behenate emerged from this line of research and entered cosmetic formulas in the late 1990s as a way to add long-lasting softness.

Manufacturing starts by heating hydroxypropyl dimethicone with behenic acid in the presence of a catalyst. As the two react, water is removed and an ester bond forms, locking the fatty acid onto the silicone backbone. The finished material is then purified, cooled, and milled into a pourable fluid or soft wax that dissolves easily into oils and emulsions.

You will most often spot Hydroxypropyl Dimethicone Behenate in moisturizers, primers, foundations, pressed powders, lipsticks, sunscreens, leave-on hair conditioners, and sheet or cream masks. Formulators choose it when they want a product to feel velvety, resist rubbing off, and leave skin or hair with a subtle protective film.

Hydroxypropyl Dimethicone Behenate’s Cosmetic Benefits/Uses

This ingredient is prized for the way it conditions and pampers the skin.

As a skin-conditioning agent Hydroxypropyl Dimethicone Behenate forms a breathable layer that traps moisture, smooths rough texture, and reduces the look of fine lines. It also improves slip, making creams and makeup glide on more evenly while helping pigments stay put throughout the day.

Who Can Use Hydroxypropyl Dimethicone Behenate

Most skin types, including dry, normal and combination, tend to tolerate Hydroxypropyl Dimethicone Behenate well thanks to its lightweight cushioning feel. Oily or acne-prone skin can also benefit because the molecule is non-greasy and helps pigments sit smoothly without adding extra oil, though those who are highly clog-prone may prefer to monitor how their skin responds since any occlusive film has the potential to trap excess sebum. Sensitive skin generally handles this ingredient without trouble because silicones are inert and the fatty acid chain is mild, yet individuals with a history of silicone or fatty acid sensitivities should proceed with caution.

The behenic acid used to create this ingredient is almost always sourced from plant oils like moringa or rapeseed, and the silicone backbone is synthetic, so Hydroxypropyl Dimethicone Behenate is suitable for vegans and vegetarians as long as the finished product is certified cruelty-free.

No data suggests that topical use poses a risk to pregnant or breastfeeding women. Still, this is not medical advice and anyone who is expecting or nursing should check with a healthcare professional before adding new skincare to their routine.

The ingredient does not increase photosensitivity and there are no known concerns related to sun exposure. It can be worn day or night under sunscreen without special precautions.

Potential Side Effects/Adverse Reactions

Reactions to Hydroxypropyl Dimethicone Behenate vary from person to person. The issues listed below are only potential side effects and are unlikely for the average user when the ingredient is properly formulated.

  • Mild irritation – rare stinging or redness, usually in very sensitive skin
  • Contact dermatitis – an allergic response to the silicone or residual catalysts, presenting as rash or itching
  • Clogged pores – possible in those extremely prone to comedones due to the light occlusive film
  • Product buildup – a heavy or coated feel if layered with multiple silicone-rich items, which may dull skin or hair until washed off

If any discomfort, rash or breakout develops stop using the product and seek advice from a healthcare professional.

Comedogenic Rating

Rating: 1/5

Hydroxypropyl Dimethicone Behenate is a large silicone-fatty acid ester that sits on the surface of skin rather than sinking deeply into pores. Its size and inert nature mean it is unlikely to clog follicles in most people, yet the light occlusive film it creates can, in rare cases, trap existing sebum if skin is already very congestion-prone. Overall it is considered low risk for breakouts and is generally suitable for acne-prone users.

Because it is often blended with other silicones and oils, the comedogenic impact of the final product will depend on the full formula, application amount and cleansing habits.

Summary

Hydroxypropyl Dimethicone Behenate conditions skin by forming a breathable, velvety layer that locks in moisture, smooths texture and improves the glide and wear of makeup or skincare. Its hybrid silicone-fatty structure delivers the slip of dimethicone with the cushioned feel of natural oils, making it popular in primers, foundations, moisturizers and lip products, though it remains more of a supporting actor than a headline ingredient.

Current safety data shows a low likelihood of irritation or systemic harm when used topically, and regulatory bodies allow it without concentration limits. As with any new cosmetic it is wise to patch test first to be sure your individual skin agrees with the formula.

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