Hydroxypropyl Dimethiconylpropyl Acrylates Copolymer: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: June 27, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Hydroxypropyl Dimethiconylpropyl Acrylates Copolymer?

Hydroxypropyl Dimethiconylpropyl Acrylates Copolymer is a lab-made ingredient created by linking two different building blocks: isobutyl methacrylate, which belongs to the acrylic family often used in clear plastics, and bis-hydroxypropyl dimethicone acrylate, a silicone-based unit known for its smooth feel. Together they form a flexible film-forming copolymer that blends the staying power of acrylics with the silky glide of silicones.

Cosmetic chemists began exploring silicone-acrylate hybrids in the late 1990s when long-wear makeup and water-resistant sunscreens gained popularity. The goal was to design a lightweight film former that could resist sweat and oil without feeling tight or heavy. After several iterations this copolymer emerged as a favorite thanks to its balance of comfort and durability.

The material is produced through a process called free radical polymerization. The two monomers are mixed in a reactor, triggered to join together, then purified and dried into a fine powder or viscous fluid. Because the starting materials are fully synthetic the final ingredient is consistent from batch to batch and free of animal derivatives.

You will most often spot Hydroxypropyl Dimethiconylpropyl Acrylates Copolymer in long-wear foundations, waterproof mascaras, liquid eyeliners, tinted sunscreens, primers, setting sprays, transfer-resistant lip colors, hair styling creams, lightweight conditioners and peel-off or rinse-off facial masks.

Hydroxypropyl Dimethiconylpropyl Acrylates Copolymer’s Cosmetic Benefits/Uses

This multifunctional copolymer contributes to formulas in several ways

  • Film forming: Creates a thin flexible layer on skin or hair that locks in pigments and active ingredients, boosts water and sweat resistance and helps makeup stay in place for longer hours
  • Cleansing: When used in rinse-off or micellar products it helps lift dirt and makeup from the surface so they can be washed away more easily, supporting a thorough yet gentle cleanse
  • Viscosity controlling: Helps thicken or stabilize a formula giving creams, gels or sprays the right texture so they spread evenly without dripping or feeling sticky

Who Can Use Hydroxypropyl Dimethiconylpropyl Acrylates Copolymer

This copolymer is generally suitable for all skin types including oily, combination, normal and dry. Its lightweight silicone-acrylate film sits on top of the skin without clogging pores or pulling away moisture so even sensitive or redness-prone complexions usually tolerate it well. Those with very reactive or allergy-prone skin should still keep an eye on new products because any synthetic film former can occasionally trap heat or perspiration and cause discomfort in rare cases.

The ingredient is fully synthetic and contains no animal-derived components so it fits vegan and vegetarian lifestyles. It is also commonly used in cruelty-free formulas because its production does not rely on animal testing under most regulatory frameworks.

Current safety assessments have not flagged any reproductive or developmental concerns for topical use which means most experts consider it acceptable during pregnancy and while breastfeeding. That said this is not medical advice and anyone who is pregnant or nursing should show the full ingredient list of any cosmetic product to their healthcare provider before adding it to a routine just to be safe.

Hydroxypropyl Dimethiconylpropyl Acrylates Copolymer does not make skin more sensitive to sunlight and will not interfere with SPF filters. As a non-reactive film former it also plays well with common actives such as vitamin C, niacinamide and retinoids.

Potential Side Effects/Adverse Reactions

Side effects from topical use can vary from person to person. The points below list potential reactions, though most users will not experience any of them when the ingredient is used correctly in a finished product

  • Mild skin irritation such as temporary redness or itching
  • Contact dermatitis in individuals allergic to acrylates or silicone derivatives
  • Eye stinging or watering if the product accidentally gets into the eyes
  • Scalp or hair buildup leading to a weighed-down feel when used in styling products without regular cleansing
  • Follicular occlusion in very acne-prone skin if layered heavily with other occlusives

If any discomfort, rash or other negative reaction occurs stop using the product and consult a healthcare professional for guidance.

Comedogenic Rating

Rating: 1/5 – Hydroxypropyl Dimethiconylpropyl Acrylates Copolymer is a large silicone-acrylate molecule that sits on the surface rather than sinking into pores so it rarely blocks them. Its flexible film allows some breathability and it does not carry oils or waxes that can feed breakouts. Heavy layering with other occlusive ingredients could still trap oil on very acne-prone skin but the copolymer itself is considered low risk.

Suitable for people who are prone to acne or breakouts as long as the overall formula is lightweight and removed thoroughly at the end of the day.

Because the ingredient rinses off with cleanser, proper cleansing habits further reduce any chance of pore congestion.

Summary

Hydroxypropyl Dimethiconylpropyl Acrylates Copolymer is a lab-made film former that keeps makeup, sunscreen or hair products in place, helps cleanse by lifting dirt during rinsing and tweaks texture so creams or sprays feel silky and stable. It does this by forming a thin flexible network on skin or hair that resists water and sweat while adding slip.

The copolymer shows up most in long-wear foundations, waterproof mascaras and primers so it is popular in performance formulas though you will not see it in every basic moisturizer. Safety reviews find it non-sensitizing and non-toxic for topical use, with very low comedogenic potential. As with any new ingredient it is wise to patch test a product first to be sure your skin agrees.

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